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Mechanisms responsible for two possible electrochemical reactions in Li$$_{1.2}$$Ni$$_{0.13}$$Mn$$_{0.54}$$Co$$_{0.13}$$O$$_{2}$$ used for lithium ion batteries

Konishi, Hiroaki*; Hirano, Tatsumi*; Takamatsu, Daiko*; Gunji, Akira*; Feng, X.*; Furutsuki, Sho*; Okumura, Takafumi*; Terada, Shohei*; Tamura, Kazuhisa  

Li$$_{1.2}$$Ni$$_{0.13}$$Mn$$_{0.54}$$Co$$_{0.13}$$O$$_{2}$$ is known as one of the cathode electrode material for Li ion batteries and its structure during charge and discharge process was investigated using electrochemical method and X-ray diffraction. It was found that in the charge process the structure changes in the order of Li$$_{2}$$MnO$$_{3}$$, LiNi$$_{0.33}$$Mn$$_{0.33}$$Co$$_{0.33}$$O$$_{2}$$, and Li$$_{2}$$MnO$$_{3}$$. On the other hand, in the discharge process, the structure changes in the order of Li$$_{2}$$MnO$$_{3}$$ and LiNi$$_{0.33}$$Mn$$_{0.33}$$Co$$_{0.33}$$O$$_{2}$$.

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Category:Chemistry, Inorganic & Nuclear

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