• help
  • PC | SP
  • JP | EN
          
Refine your search：     
Report No.
 - 
Clear All
Return to the previous page

Electronic structure of Li$$^{+}$$@C$$_{60}$$; Photoelectron spectroscopy of the Li$$^{+}$$@C$$_{60}$$[PF$$_{6}$$$$^{-}$$] salt and STM of the single Li$$^{+}$$@C$$_{60}$$ molecules on Cu(111)

Yamada, Yoichi*; Kuklin, A. V.*; Sato, Sho*; Esaka, Fumitaka  ; Sumi, Naoya*; Zhang, C.*; Sasaki, Masahiro*; Kwon, E.*; Kasama, Yasuhiko*; Avramov, P. V.*; Sakai, Seiji*

We report first STM observation of the Li$$^{+}$$ ion endohedral C$$_{60}$$, which is of a new class of endohedral fullerenes, prepared by means of evaporation of high-purity Li$$^{+}$$@C$$_{60}$$[PF$$_{6}$$$$^{-}$$] salt in ultra-high vacuum. Prior to the STM measurements, the electronic structure of Li$$^{+}$$@C$$_{60}$$ in the Li$$^{+}$$@C$$_{60}$$[PF$$_{6}$$$$^{-}$$] salt was also precisely determined. In the salt, it is shown that Li and PF$$_{6}$$ have nearly single positive and negative charge, respectively, and the C$$_{60}$$ cage is nearly neutral, suggesting that Li$$^{+}$$@C$$_{60}$$ in the salt retains its original electronic state.

Language

 :

English

Journal

 :

Carbon

Volume

 :

133

Number

 :

Pages

 :

p.23 - 30

Publication Year/Month

 :

2018/07

Meeting title

 :

Held date

 :

Location (city)

 :

Location (country)

 :

Patent information

 :

PDF

 :


Paper URL

 :

https://doi.org/10.1016/j.carbon.2018.02.106

DOI for research data

 :

Keywords

 :

STM; Fullerenes; XAS

Research Facility

 :

JRR-3実験利用棟(第2棟)

Press Release

 :

Article of JAEA R&D Review

 :

Cooperating Institute

 :

Accesses

 :

- Accesses

InCites™

 :

Percentile:55.14

Category:Chemistry, Physical

Altmetrics

 :

[CLARIVATE ANALYTICS], [WEB OF SCIENCE], [HIGHLY CITED PAPER & CUP LOGO] and [HOT PAPER & FIRE LOGO] are trademarks of Clarivate Analytics, and/or its affiliated company or companies, and used herein by permission and/or license.

Return to the previous page