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Thermodynamic property of cesium-silicates

セシウムシリケートの熱力学特性評価

鈴木 恵理子   ; 中島 邦久  ; 逢坂 正彦  ; 大石 佑治*; 牟田 浩明*; 黒崎 健*

Suzuki, Eriko; Nakajima, Kunihisa; Osaka, Masahiko; Oishi, Yuji*; Muta, Hiroaki*; Kurosaki, Ken*

軽水炉シビアアクシデント時に起こる原子炉構造材へのセシウム(Cs)化学吸着で生成する可能性があるセシウムシリケート(CsFeSiO$$_{4}$$, Cs$$_{2}$$Si$$_{2}$$O$$_{5}$$, Cs$$_{2}$$Si$$_{4}$$O$$_{9}$$)について、その吸着・再蒸発挙動評価に資するため、低温比熱測定実験により熱力学特性データの実測値を得た。この結果、特にCs$$_{2}$$Si$$_{4}$$O$$_{9}$$について、より信頼度の高い高温での標準生成ギブスエネルギーの評価が可能となった。

In LWR severe accident condition, Cesium(Cs)-silicates (CsFeSiO$$_{4}$$, Cs$$_{2}$$Si$$_{2}$$O$$_{5}$$, Cs$$_{2}$$Si$$_{4}$$O$$_{9}$$) could be formed by Cs chemisorption onto reactor structural materials. For evaluation of chemisorption/re-vaporization behaviour, thermal property of each Cesium-silicates were investigated by low temperature heat capacity measurement. As a result, actual measurement values of standard entropy, which have evaluated by estimate values, were obtained. Especially for Cs$$_{2}$$Si$$_{4}$$O$$_{9}$$, more reliable value of standard formation Gibbs energy was able to be evaluated.

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