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Rotational-state distribution and ortho-para conversion of molecularly chemisorbed H$$_{2}$$ on Pd(210)

Ueta, Hirokazu   ; Sasakawa, Yuya*; Ivanov, D.*; Ono, Satoshi*; Fukutani, Katsuyuki

While hydrogen typically chemisorbs dissociatively on a flat metal surface, it is known that hydrogen can molecularly chemisorb on stepped surfaces, such as Pd(210). In this study, using a combination of a pulsed molecular beam, photo-stimulated desorption and resonance-enhanced multiphoton ionization techniques, the rotational states of molecularly chemisorbed H$$_{2}$$ are probed. We will present the rotational state distribution of photo-desorbed H$$_{2}$$, and the o-p conversion process of molecularly chemisorbed H$$_{2}$$ will be discussed.

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