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A Study of ortho-para conversion of molecularly chemisorbed H$$_{2}$$ on Pd(210)

Ueta, Hirokazu   ; Sasakawa, Yuya*; Ivanov, D.*; Ono, Satoshi*; Ogura, Shohei*; Fukutani, Katsuyuki

Surface defects such as step and kink affect surfaced reaction. While hydrogen typically chemisorbs dissociatively on a flat metal surface, it is known that hydrogen can molecularly chemisorb on stepped surfaces, such as Pd(210). Recently, we developed a technique to probe ortho-para conversion of adsorbed hydrogen which consists of a combination of a pulsed molecular beam, photo-stimulated desorption and resonance-enhanced multiphoton ionization techniques. We report a result of orho-para conversion time of molecularly chemisorbed H$$_{2}$$ on Pd(210).

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