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Investigation of silica structure in borosilicate glasses by Raman spectrometry

Nagai, Takayuki  ; Okamoto, Yoshihiro  ; Kaneko, Koji   ; Motokawa, Ryuhei   ; Kobayashi, Hiromi*; Homma, Masanobu*; Hirono, Kazuya*

To understand the structural property of borosilicate glass frit for vitrification of radioactive wastes, we prepared the glass frit samples which coordinated alkaline component and B$$_{2}$$O$$_{3}$$ amount and measured the Si-O bridge structure of those samples by using Raman spectrometer. Moreover, we made the simulated waste glass samples which added non-radioactive nitrate solution to those frit and observed a change of Raman spectra by glass composition.

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