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Report No.
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Chemical reaction behavior between cesium hydroxide and iron oxides

Imoto, Jumpei ; Nakajima, Kunihisa  ; Osaka, Masahiko  

CsOH chemisorption onto stainless steel surface is suggested to occur during a light water reactor severe accident and CsFeO$$_{2}$$ could be formed. In order to elucidate such a Cs chemisorption behavior, it is necessary to examine chemical reaction behavior with iron oxides formed on the stainless steel surface. In this study, chemical reaction behavior between CsOH and iron oxide was investigated by using mixed powders of cesium hydroxide monohydrate and iron oxides, i.e., goethite ($$alpha$$-FeOOH), hematite ($$alpha$$-Fe$$_{2}$$O$$_{3}$$), and magnetite(Fe$$_{3}$$O$$_{4}$$). As the result, it was found that goethite and hematite were more reactive with CsOH than magnetite.

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