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Magnetically induced electric polarization in Ba$$_{3}$$Fe$$_{2}$$O$$_{5}$$Cl$$_{2}$$ with tunable direction in three dimensions

三次元方向への調整可能なBa$$_{3}$$Fe$$_{2}$$O$$_{5}$$Cl$$_{2}$$の磁気誘起電気分極

阿部 伸行*; 塩澤 俊介*; 松浦 慧介*; 佐賀山 基*; 中尾 朗子*; 大原 高志   ; 徳永 祐介*; 有馬 孝尚*

Abe, Nobuyuki*; Shiozawa, Shunsuke*; Matsuura, Keisuke*; Sagayama, Hajime*; Nakao, Akiko*; Ohara, Takashi; Tokunaga, Yusuke*; Arima, Takahisa*

The correlation between magnetism and electric polarization in a chiral insulating magnet Ba$$_{3}$$Fe$$_{2}$$O$$_{5}$$Cl$$_{2}$$ has been investigated. The temperature dependence of magnetic susceptibility shows an anomaly at 564 K, suggesting the onset of antiferromagnetic order of Fe$$^{3+}$$ moments. Electric polarization appears in a magnetic field below TN due to the spin-direction-dependent metal-ligand hybridization. The direction of the electric polarization can be controlled in three-dimensional space by changing the direction of an external magnetic field. This compound also shows an antiferromagnetic-to-weak-ferromagnetic transition accompanied by a structural phase transition at 140 K.

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パーセンタイル:12.9

分野:Materials Science, Multidisciplinary

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