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Report No.
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Effects of steel overpack on aqueous alteration of vitrified high-level radioactive waste

Iwata, Hajime ; Mitsui, Seiichiro ; Sekine, Nobuyuki*

In order to measure Fe-silicates precipitated under geological disposal conditions, a static leaching test has been conducted of simulated vitrified waste in 0.01 M FeCl$$_{2}$$ solution with a surface area to volume ratio = 10 m$$^{-1}$$ at 90$$^{circ}$$C under a N$$_{2(g)}$$ atmosphere. Obtained results indicate that Fe bearing minerals change from green rust to Fe-rich serpentine over time. Such mineral transitions are important as they may have an effect on the alteration behavior of glasses used for geological disposal of HLW.

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