Efficient detection of methane seepage using a vehicle-mounted cavity ring-down spectroscopy analyzer

Niwa, Masakazu   ; Shimo, Michito*; Shimada, Koji   ; Goto, Akira

Methane (CH) seepage to the surface in the early stage of hydrocarbon exploration has attracted increasing attention. Also, detection of CH-rich fluid emission can be applied to reconnaissance surveys for safety management in geological disposal of radioactive waste because high-temperature fluids that come from slab dehydration along a subduction zone are often rich in CH. These fluids likely migrate along faults and fractures. In this study, we employed a portable analyzer that used a wavelength-scanned cavity ring-down spectroscopy (CRDS) with high accuracy (in ppb levels) and short measurement intervals (1 s). An on-vehicle measurement that employed the CRDS system was performed in the Hongu area in southeast Kii Peninsula, Japan, which included CH-bearing hot springs (Kawayu and Yunomine). The measurement near the hot springs detected a clear CH anomaly (2 ppm) that exceeded the background concentration. The estimation of CH diffusion in air based on the Gaussian plume model corresponded to the result of the on-vehicle measurement. This study confirmed that the method using the vehicle-mounted CRDS analyzer can help in quickly and easily identifying CH-bearing fluid emissions at the surface. Additionally, directions for use of the analyzer were summarized in this report.