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Microstructures formed on polymers by atomic oxygen irradiation; effects of polymer's higher-order structures

Goto, Aki*; Tanji, Takashi*; Tagawa, Masahito*; Michishio, Koji*; Oka, Toshitaka   ; Yamashita, Shinichi*

Crystallinity and thermal property were evaluated for polyethylene, polypropylene, polystyrene films, then, they were irradiated with atomic oxygen (AO) and observed by a scanning electron microscope and positron annihilation lifetime spectroscopy. Free-volume holes and thermal motions affected spatial scales for the reactions with AO, determining the sizes and numerical density of formed protrusions.

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