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Report No.

Neutron scattering on an aqueous sodium chloride solution in the gigapascal pressure range

Yamaguchi, Toshio*; Yoshida, Koji*; Machida, Shinichi*; Hattori, Takanori   

Neutron scattering measurements were performed on an aqueous 3 mol/kg NaCl solution in D$$_2$$O at temperature and pressure conditions of 0.1 MPa/298K, 1 GPa/298K, 1 GPa/523K, and 4 GPa/523K. The empirical potential structure refinement method was applied to the obtained data to extract the pair correlation function, coordination number distribution, angular distribution (orientation correlation), and spatial density function (3-D structure). From those results, pressure and temperature dependence of solvation and association of ions and solvent-water structure were discussed.



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Category:Chemistry, Physical



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