Composite with a glassy nonporous coordination polymer enhances gas adsorption selectivity

Zheng, X.*; Kato, Masaru*; Uemura, Yohei*; Matsumura, Daiju ; Yagi, Ichizo*; Takahashi, Kiyonori*; Noro, Shinichiro*; Nakamura, Takayoshi*

A glass-crystal composite (g-NCP/PCP), comprising a glassy nonporous coordination polymer (g-NCP) and a crystalline porous coordination polymer (PCP)/metal-organic framework, was synthesized by using a melt-quenched method. Compared to that of the PCP itself, g-NCP/PCP has an enhanced gas adsorption selectivity. The results should stimulate further studies of the chemistry of g-NCP/PCP glass-crystal composites.

Language	:	English
Journal	:	Inorganic Chemistry
Volume	:	62
Number	:	3
Pages	:	p.1257 - 1263
Publication Year/Month	:	2023/01
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Paper URL	:	https://doi.org/10.1021/acs.inorgchem.2c04068
DOI for research data	:
Keywords	:	配位高分子; ガス吸着; XAFS
Research Facility	:	SPring-8(大型放射光施設)
Press Release	:
Article of JAEA R&D Review	:
Cooperating Institute	:	北海道大学

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InCites™	:	Percentile:58.61 Category:Chemistry, Inorganic & Nuclear
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Registration No. : AA20220944
JAEA Abstracts No. : 51000561
Paper Submission No. : 26493

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