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Development of the continuous monitoring of tritium water by mid-infrared laser spectroscopy (Contract research); FY2022 Nuclear Energy Science & Technology and Human Resource Development Project

Collaborative Laboratories for Advanced Decommissioning Science; National Institutes of Natural Sciences*

The Collaborative Laboratories for Advanced Decommissioning Science (CLADS), Japan Atomic Energy Agency (JAEA), had been conducting the Nuclear Energy Science & Technology and Human Resource Development Project (hereafter referred to "the Project") in FY2022. The Project aims to contribute to solving problems in the nuclear energy field represented by the decommissioning of the Fukushima Daiichi Nuclear Power Station, Tokyo Electric Power Company Holdings, Inc. (TEPCO). For this purpose, intelligence was collected from all over the world, and basic research and human resource development were promoted by closely integrating/collaborating knowledge and experiences in various fields beyond the barrier of conventional organizations and research fields. The sponsor of the Project was moved from the Ministry of Education, Culture, Sports, Science and Technology to JAEA since the newly adopted proposals in FY2018. On this occasion, JAEA constructed a new research system where JAEA-academia collaboration is reinforced and medium-to-long term research/development and human resource development contributing to the decommissioning are stably and consecutively implemented. Among the adopted proposals in FY2021, this report summarizes the research results of the "Development of the continuous monitoring of tritium water by mid-infrared laser spectroscopy" conducted in FY2022. The present study aims to demonstrate the principle of short-time measurement of tritiated water at the "60 Bq/cc level" using a cavity ring-down measurement system with a mid-infrared laser. To achieve the above goal, (1) research on the cavity ring-down system and (2) evaluation of hydrogen isotope composition under environmental conditions and preparation of standard samples (subcontractor: Hirosaki University) were conducted this fiscal year.

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