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Tracer diffusion coefficients measurements on LaPO$$_{4}$$-dispersed LATP by means of neutron radiography

Song, F.*; Chen, H.*; Hayashida, Hirotoshi*; Kai, Tetsuya   ; Shinohara, Takenao   ; Yabutsuka, Takeshi*; Yao, Takeshi*; Takai, Shigeomi*

Lithium tracer diffusion coefficients have been measured in Li$$_{1.3}$$Al$$_{0.3}$$Ti$$_{1.7}$$(PO$$_4$$)$$_3$$ (LATP) and LATP - LaPO$$_4$$ composite solid electrolytes in the temperature range between 300$$^{circ}$$C and 500$$^{circ}$$C by means of neutron radiography technique that utilizes the difference in neutron attenuation of $$^6$$Li and $$^7$$Li isotopes. The diffusion coefficient of LATP - LaPO$$_4$$ composite is higher than that of pristine LATP, although the difference is much smaller than that estimated from the room temperature conductivity. This suggests that the bulk diffusion becomes the predominant diffusion mechanism at 300$$^{circ}$$C to 500$$^{circ}$$C instead of the diffusion along the space charge layer formed around the LaPO$$_4$$ dispersants.



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Category:Chemistry, Physical



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