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Multi-atom resonant X-ray emission in simple binary compounds

Baba, Yuji*  ; Shimoyama, Iwao   

Multi-atom resonance (MAR) effect following the core-level resonant photoexcitation has been investigated for simple binary compounds such as CaCl$$_{2}$$, KCl and SrCl$$_{2}$$. For solid CaCl$$_{2}$$, it was found that the intensity of Cl K$$alpha$$ X-rays was reduced when the energy of the incident X-rays was tuned at the resonance energy of the neighboring Ca K-edge, but such intensity reduction was not observed for aqueous solution of CaCl$$_{2}$$. Similar results were also obtained for the KCl and SrCl$$_{2}$$. From these results, it was clarified that for these binary compounds, the multi-atom resonance does occur only in an atom that is directly bound to the excited atom.

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