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Resonance ionization spectroscopy of high-lying 4sns and 4snd Rydberg levels of odd calcium isotopes

Iwata, Yoshihiro   ; Miyabe, Masabumi   ; Akaoka, Katsuaki ; Wakaida, Ikuo  ; Hasegawa, Shuichi*

Calcium Rydberg levels are of significant interest for efficient and isotope-selective resonance ionization of trace radionuclides such as calcium-41 ($$^{41}$$Ca). In this study, we report novel measurement data on the energy level shifts of calcium-43 ($$^{43}$$Ca) for 4sns $$^{1}$$S$$_{0}$$ and 4s(n-1)d $$^{1}$$D$$_{2}$$ (n=40, 45, 50, 55, 60) Rydberg levels due to hyperfine-induced singlet-triplet mixing specific to isotopes with an odd mass number.

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