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Impact of the Ce$$4f$$ states in the electronic structure of the intermediate-valence superconductor CeIr$$_3$$

Fujimori, Shinichi   ; Kawasaki, Ikuto  ; Takeda, Yukiharu   ; Yamagami, Hiroshi; Sasabe, Norimasa*; Sato, Yoshiki*; Shimizu, Yusei*; Nakamura, Ai*; Maruya, A.*; Homma, Yoshiya*; Li, D.*; Honda, Fuminori*; Aoki, Dai*

The electronic structure of the $$f$$-based superconductor $$mathrm{CeIr_3}$$ was studied by photoelectron spectroscopy. The energy distribution of the $$mathrm{Ce}~4f$$ state was revealed by the $$mathrm{Ce}~3d-4f$$ resonant photoelectron spectroscopy. The $$mathrm{Ce}~4f$$ state was mostly distributed in the vicinity of the Fermi energy, suggesting the itinerant character of the $$mathrm{Ce}~4f$$ state. The contribution of the $$mathrm{Ce}~4f$$ state to the density of states (DOS) at the Fermi energy was estimated to be nearly half of that of the$$mathrm{Ir}~5d$$ states, implying that the $$mathrm{Ce}~4f$$ state has aconsiderable contribution to the DOS at the Fermi energy. The $$mathrm{Ce}~3d$$ core-level and $$mathrm{Ce}~3d$$ X-ray absorption spectra were analyzed based on a single-impurity Anderson model. The number of the $$mathrm{Ce}~4f$$ state in the ground state was estimated to be 0.8-0.9, which is much larger than the values obtained in the previous studies (i.e., 0-0.4).

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