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Report No.
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Reaction mechanism of Wadalite formation process in molten salt treatment

Okumoto, Shunsuke*; Iino, Chiaki*; Oda, Masato*; Muraguchi, Masakazu*; Hayakawa, Kosetsu*; Ishii, Hiroyuki*; Honda, Mitsunori   

As part of research and development for environmental restoration of Fukushima, we have conducted study on Cs removal from weathered biotite using molten salt method. 99.9999% or less of Cs removal and formation of crystalline minerals such as ordinary Augite and wadalite were confirmed, but the atomic-level reaction mechanism of the reaction process and products is necessary. In this study, the stable structure of wadalite was investigated using first-principles calculations, and the reaction mechanism was investigated using the obtained stable structure.

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