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Ferroelectric properties of donor-acceptor co-doped BaTiO$$_3$$ ceramics

Kuwata, Kenta*; Matsuo, Hiroki*; Noguchi, Yuji*; Yoneda, Yasuhiro   

Barium titanate (BaTiO$$_3$$) is doped with transition metal (TM) ions such as Ni, which act as acceptors to trap electronic carriers (electrons or holes) generated by reductive calcination. In this study, we fabricated BaTiO$$_3$$ ceramics co-doped with Dy and La and evaluated their ferroelectric and photovoltaic properties. It was found that the Ni valence can be controlled by Dy/Ni co-doping and that the visible photovoltaic effect can be enhanced by introducing impurity levels derived from Ni-3d.

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