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Crystal structure analysis of NaNbO$$_3$$ in high-temperature phase

Aso, Seiyu*; Matsuo, Hiroki*; Noguchi, Yuji*; Yoneda, Yasuhiro   ; Morikawa, Daisuke*; Tsuda, Kenji*

Recently, higher energy storage density than that of typical ferroelectric BaTiO$$_3$$ has been achieved in NaNbO$$_3$$-based antiferroelectrics by utilizing the electric-field-induced phase transition between the antiferroelectric (AFE) and ferroelectric (FE) phases. In this study, we attempted to identify the space group using synchrotron X-ray diffraction and convergent electron diffraction in order to elucidate the full picture of the phase transition behavior in NaNbO$$_3$$ and Ca-doped NaNbO$$_3$$. On the other hand, the Ca-doped sample showed that the space group is Pnma, which is consistent with the results obtained by convergent electron diffraction measurements.

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