The Development and application of the stirred-reactor coupon analysis (SRCA) test method

Stirred-reactor coupon analysis(SRCA)試験法の開発と応用

Reiser, J. T.*; Neeway, J. J.*; Cooley, S. K.*; Parruzot, B.*; Heredia-Langner, A.*; Gin, S.*; Thomas, M.*; Smith, N. J.*; Icenhower, J. P.*; Stone-Weiss, N.*; 高橋 裕太 ; 岩田 孟 ; 三ツ井 誠一郎  ; 佐藤 淳也 ; Lenting, C.*; 稲垣 八穂広*; Harrison, M. T.*; Du, J.*; Xie, W.*; Ferrand, K.*; Thorpe, C. L.*; Ravikumar, R.*; Corkhill, C. L.*; McCloy, J. S.*; Snyder, M. M. V.*; Lawter, A. R.*; Smith, G. L.*; Asmussen, R. M.*; Ryan, J. V.*

Reiser, J. T.*; Neeway, J. J.*; Cooley, S. K.*; Parruzot, B.*; Heredia-Langner, A.*; Gin, S.*; Thomas, M.*; Smith, N. J.*; Icenhower, J. P.*; Stone-Weiss, N.*; Takahashi, Yuta; Iwata, Hajime; Mitsui, Seiichiro; Sato, Junya; Lenting, C.*; Inagaki, Yaohiro*; Harrison, M. T.*; Du, J.*; Xie, W.*; Ferrand, K.*; Thorpe, C. L.*; Ravikumar, R.*; Corkhill, C. L.*; McCloy, J. S.*; Snyder, M. M. V.*; Lawter, A. R.*; Smith, G. L.*; Asmussen, R. M.*; Ryan, J. V.*

A new technique, termed the stirred-reactor coupon analysis (SRCA) method, has been developed to measure the rate of glass dissolution in forward-rate conditions. Monolithic glass coupons are partially masked with an inert material before placement in a large volume of well-mixed solution with known chemistry and temperature for a predetermined duration. After the test, the mask is removed, and the difference in step height between the protected area and the exposed corroded portions of the sample coupon is measured to determine the extent of glass dissolution. The step height is converted to a rate measurement using the test duration and glass density. Test parameters such as sample surface preparation and test duration were evaluated to determine their effects on the measured rates. Additionally, results from an interlaboratory study (ILS) consisting of 12 laboratories from 11 different institutions are presented, where each laboratory performed 12 independent tests. When removing experimental outlier data, the 95% reproducibility limits for the SRCA method has no statistical difference with previously published standardized test methods used to determine the forward rate of glass dissolution. Overall, this paper describes steps necessary to perform the test method and provides the statistical calculations to evaluate test accuracy.