Development of a process for the separation of MA(III) from Ln(III) fission products using HONTA impregnated adsorbent

HONTA含浸吸着材を用いたMA(III)/Ln(III)分離プロセスの開発

久保田 真彦*; Kim, S.-Y.*; Wu, H.*; 渡部 創  ; 佐野 雄一   ; 竹内 正行 ; 新井 剛*

Kubota, Masahiko*; Kim, S.-Y.*; Wu, H.*; Watanabe, So; Sano, Yuichi; Takeuchi, Masayuki; Arai, Tsuyoshi*

To minimize the use of organic solvents and achieve a selective adsorption separation of minor actinides (MA(III)) and Ln(III), adsorbents consisting of SiO-P particles impregnated with hexaoctylnitrilotriacetamide (HONTA) were prepared. Batch experiments were performed to evaluate the adsorption properties of the HONTA/SiO-P adsorbent for MA(III) and simulated fission products in HNOsolution. The uniform distribution of Eu(III) on the adsorbent was confirmed via particle induced X-ray emission analysis, and X-ray photoelectron spectroscopy revealed that EuNO was the adsorbed species. This study provides a simplified process for the separation of MA(III) using a HONTA/SiO-P packed column.