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Development of a H$$_{2}$$ measurement method for radioactive waste analysis

Kumagai, Yuta   ; Kawai, Masashi*; Ikarugi, Riko; Oka, Toshitaka   ; Toigawa, Tomohiro   ; Kitatsuji, Yoshihiro  ; Kumagai, Jun*

We have developed a highly sensitive H$$_{2}$$ analysis method by employing a gas chromatograph with a senser diode, aiming to apply for small amounts of H$$_{2}$$ production from radioactive wastes. The H$$_{2}$$ analysis method was tested with an X-ray irradiation experiment of Na$$_{2}$$WO$$_{4}$$ 2H$$_{2}$$O. Even though the absorbed dose was less than 100 Gy, the H$$_{2}$$ production from only 1 g of the sample can be analyzed by our method. Based on the experimental results, the lower limit of H$$_{2}$$ quantification was evaluated to be 2 $$times$$ 10$$^{-10}$$ mol.

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