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Neutron spectroscopy study on crystalline electric field excitations in NdB$$_4$$

山内 宏樹   ; 目時 直人   ; 綿貫 竜太*; Hong, T.*; Fernandez-Baca, J. A.*; 萩原 雅人   ; 益田 隆嗣*; 吉沢 英樹*; 伊藤 晋一*

Yamauchi, Hiroki; Metoki, Naoto; Watanuki, Ryuta*; Hong, T.*; Fernandez-Baca, J. A.*; Hagihara, Masato; Masuda, Takatsugu*; Yoshizawa, Hideki*; Ito, Shinichi*

The $textit{f}$-electron states of NdB$$_4$$ were determined by observing crystalline electric field (CEF) excitations with inelastic neutron scattering experiments. Our analysis yields CEF excitation energies of 2.8, 12.4, 17.2, and 25.4 meV. The $textit{f}$-electron states are simply described by one of $$J$$-multiplets $$left|pm J_z rightrangle$$ with negligibly small mixing. The ground state is the pseudo-quartet consist of the ground doublet dominated by $$left|pm frac{5}{2} rightrangle$$ and the first excited doublet dominated by $$left|pm frac{7}{2} rightrangle$$ at 2.8 meV, which is consistent with magnetic specific heat and entropy reported in earlier study. The simple $textit{f}$-electron states in NdB$$_4$$ are the consequence of the strong uniaxial and in-plane isotropic CEF potential due to the local structure of Nd$$^{3+}$$ ions with point symmetry $$C_{2v}$$.

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分野:Physics, Multidisciplinary

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