Development of XAFS analysis to elucidate the structural change of weathered biotite under high temperature

Hayakawa, Kosetsu*; Muraguchi, Masakazu*; Masebo, Yumeno*; Kojima, Yoichiro*; Oda, Masato*; Yabuta, Rina*; Ishii, Hiroyuki*; Honda, Mitsunori   

We are developing materials using clay minerals for thermoelectric materials that can be used at high temperatures in environmental friendly applications. We have succeeded in obtaining thermoelectric properties at high temperatures, but we do not know why these properties are exhibited. In order to elucidate the structural changes of weathered biotite under high temperature conditions, we will develop an XAFS analysis method and clarify the local structure of Fe at high temperatures. The local structure analysis of Fe in samples sintered in atmospheric and vacuum environments reveals changes in the chemical bonding state of Fe.