Visualisation and quantitative evaluation of chlorides in corroded crevice of stainless steel using radioisotope Cl

Aoki, So  ; Abe, Yosuke  ; Abe, Hiroshi*; Watanabe, Yutaka*; Yamamoto, Masahiro*

This study aimed to visualise the distribution of chloride in the corroded crevice of stainless steel and to evaluate the chloride content quantitatively. Crevice corrosion tests were carried out using Cl, a radioactive isotope of chloride, as a tracer in NaCl test solutions. After crevice corrosion tests, stainless steel specimens were placed on an imaging plate. The imaging plate was sensitised by -ray emitted by Cl adhering to the crevice. As a result, the chloride distribution in the corroded area inside the crevice was visualised. A calibration curve for the amount of Cl was obtained from the relationship between the time of photosensitivity to -ray emitted by Cl and the luminance of the imaging plate. The chloride content in the corroded crevice was quantitatively evaluated based on the calibration curve. These visualisation and quantitative evaluation methods were also applied to tests in which specimens were left in pure water after crevice corrosion tests, and the behaviour of chloride in crevice corrosion was discussed.