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Oxygen chemical diffusion in fast neutron reactor fuel U$$_{0.698}$$Pu$$_{0.289}$$Am$$_{0.013}$$O$$_{2-x}$$

高速中性子炉燃料U$$_{0.698}$$Pu$$_{0.289}$$Am$$_{0.013}$$O$$_{2-x}$$における酸素の化学拡散

Vauchy, R.  ; 堀井 雄太 ; 廣岡 瞬 ; 赤司 雅俊 ; 砂押 剛雄*; 中道 晋哉  ; 齋藤 浩介

Vauchy, R.; Horii, Yuta; Hirooka, Shun; Akashi, Masatoshi; Sunaoshi, Takeo*; Nakamichi, Shinya; Saito, Kosuke

The oxygen chemical diffusion of fast neutron reactor MOX U$$_{0.698}$$Pu$$_{0.289}$$Am$$_{0.013}$$O$$_{2-x}$$ was investigated by thermogravimetric analysis between 1773 and 1923 K, using an innovative experimental procedure. At a given temperature, the oxygen chemical diffusion coefficients were shown to decrease when the Oxygen/Metal ratio decreases (in hypo-stoichiometry). The variations of the oxygen chemical diffusion coefficients as a function of temperature and oxygen partial pressure (hence oxygen stoichiometry) were paralleled to a defect chemistry model.

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