Effects of the size of fillers on viscoelasticity in the glassy state of poly(styrene--butadiene) reinforced by carbon black

カーボンブラックで強化したポリ(スチレン--ブタジエン)のガラス領域における粘弾性に及ぼすフィラーサイズの影響

Watanabe, Yuki*; 熊川 大幹*; Karitani, Shu*; 井上 正志*; 岩蕗 仁*; 中西 洋平*; 柴田 基樹*; 元川 竜平   ; 杉田 剛   ; 上田 祐生   ; 熊田 高之   ; 山本 勝宏*; 三田 一樹*; 宮崎 司*; 竹中 幹人*

Watanabe, Yuki*; Kumagawa, Daiki*; Karitani, Shu*; Inoue, Tadashi*; Iwabuki, Hitoshi*; Nakanishi, Yohei*; Shibata, Motoki*; Motokawa, Ryuhei; Sugita, Tsuyoshi; Ueda, Yuki; Kumada, Takayuki; Yamamoto, Katsuhiro*; Mita, Kazuki*; Miyazaki, Tsukasa*; Takenaka, Mikihito*

We investigated how the particle size of carbon black (CB) affects the reinforcement of CB to vulcanized poly(styrene-co-butadiene) (SBR) in the glassy region. When the average diameter of CB d is larger than 100 nm, the enhancement of modulus can be expressed by the Eshelby/Mori-Tanaka model, which agrees with the results obtained for an SBR/silica system. On the other hand, at d 100nm, the volume fraction dependence of the enhancement becomes stronger than the theory's prediction. The scattering studies on the SBR/CB systems revealed that the aggregates of CB at d 100nm consist of densely packed CB, while the aggregates of CB at d 100nm exhibit branch structures. At d 100nm, the voids or the occluded region in the packed CB increase the volume fraction, resulting in a stronger volume fraction dependence of the enhancement.