International benchmark on radionuclide solubility and speciation for the Long-term In-situ Test (LIT) at Grimsel Test Site (GTS, Switzerland)

Noseck, U.*; Schfer, T.*; Alonso, U.*; Hamamoto, Takafumi*; Havlova, V.*; Hibberd, R.*; Ishidera, Takamitsu ; Kitamura, Akira  ; Klajmon, M.*; Missana, T.*; Quinto, F.*; Blechschmidt, I.*; Schneeberger, R.*

Thermodynamic benchmark calculations have been performed to better understand the behavior of Se(VI), Tc(VII), U(VI), Np(V), Am(III), Th(IV) and Pu(IV)) in the evolving geochemical conditions of the Long-term In-situ Test (LIT) at the Grimsel Test Site (GTS) and corresponding mock-up experiment. It also aims to identify the status of the geochemical speciation models and databases for these elements. The experiments are simulating the near-field conditions in some radioactive waste repository concept including a bentonite engineered barrier emplaced in crystalline rock and the findings are contributing to the long-term safety assessment of these facilities.