Structural investigation of borosilicate glasses by using XAFS measurement in soft X-ray region, 4 (Joint research)

Nagai, Takayuki; Okamoto, Yoshihiro; Shibata, Daisuke*; Kojima, Kazuo*; Hasegawa, Takehiko*; Sato, Seiichi*; Fukaya, Akane*; Hatakeyama, Kiyoshi*

JAEA-Research 2024-014, 54 Pages, 2025/02

JAEA-Research-2024-014.pdf:7.02MB

XAFS measurements in the soft X-ray region are suitable for evaluating the chemical state of the surface layer of a measurement sample because the X-ray transmittance is low. In this study, the purpose of the study was to confirm the difference between the coagulated surface layer and the inside of the simulated waste glasses by measuring the K-edge of the glass constituent elements boron, oxygen, sodium, and silicon, and the L edge of the waste component cerium. As a result, the B K-edge XANES spectra showed that the proportion of B-O tetracoordinate sp structures (BO) on the surface layer of the coagulated glass samples was higher than that on the cut surface inside the glass samples, which is expected to improve the water resistance of the coagulated surface. On the other hand, the O K-edge XANES spectra suggested that the O abundance in the coagulated surface layer was lower than that in the cut surface inside the glass samples, and that alkali metal elements may be concentrated in the coagulated surface layer. However, no difference was observed in the Na K-edge XANES spectra between the coagulated surface layer and the cut surface, and no difference was observed in the Si K-edge XANES spectra between the solidified surface and the inside of glass samples. In addition, the Ce L-edge XANES spectra confirmed that the Ce valence in the surface layer of coagulated glass samples were oxidized compared to the inside of glass samples.

Structural investigation of borosilicate glasses by using XAFS measurement in soft X-ray region, 3 (Joint research)

Nagai, Takayuki; Okamoto, Yoshihiro; Yamagishi, Hirona*; Shibata, Daisuke*; Kojima, Kazuo*; Hasegawa, Takehiko*; Sato, Seiichi*; Fukaya, Akane*; Hatakeyama, Kiyoshi*

JAEA-Research 2023-004, 45 Pages, 2023/09

JAEA-Research-2023-004.pdf:6.07MB

The local structure of glass-forming elements and waste elements in borosilicate glasses varies with its chemical composition. In this study, simulated waste glass samples were prepared and the chemical state regarding boron (B), silicon (Si) and waste elements of iron (Fe), cesium (Cs) were estimated by using XAFS measurement in soft X-ray region. To understand the chemical stability of simulated waste glasses, XANES spectra of B K-edge, Fe L, L-edge, and Cs M, M-edge were measured on the glass surface exposed to the leachate. As a result, it was found that the glass surface exposed to the leachate was changed and it was difficult to obtain a clear XANES spectrum. From the B K-edge XANES spectra on glass surfaces exposed to the leachate, an increase in three-coordination of B-O (BO) and a decrease in four-coordination of B-O (BO) were observed compared to the glass surfaces before immersion. The XANES spectra of Fe L, L-edge, and Cs M, M-edge show that as the exposure time in the leachate increases, the Cs present on the glass surface dissolves into the leachate. The XANES spectra of Si K-edge were measured on simulated waste glass surfaces before immersion, and it was confirmed that the change in XANES spectra given by NaO concentration had a larger effect than the waste component concentration.

High temperature gas-cooled reactors

Takeda, Tetsuaki*; Inagaki, Yoshiyuki; Aihara, Jun; Aoki, Takeshi; Fujiwara, Yusuke; Fukaya, Yuji; Goto, Minoru; Ho, H. Q.; Iigaki, Kazuhiko; Imai, Yoshiyuki; et al.

High Temperature Gas-Cooled Reactors; JSME Series in Thermal and Nuclear Power Generation, Vol.5, 464 Pages, 2021/02

https://doi.org/10.1016/C2018-0-05383-9

As a general overview of the research and development of a High Temperature Gas-cooled Reactor (HTGR) in JAEA, this book describes the achievements by the High Temperature Engineering Test Reactor (HTTR) on the designs, key component technologies such as fuel, reactor internals, high temperature components, etc., and operational experience such as rise-to-power tests, high temperature operation at 950C, safety demonstration tests, etc. In addition, based on the knowledge of the HTTR, the development of designs and component technologies such as high performance fuel, helium gas turbine and hydrogen production by IS process for commercial HTGRs are described. These results are very useful for the future development of HTGRs. This book is published as one of a series of technical books on fossil fuel and nuclear energy systems by the Power Energy Systems Division of the Japan Society of Mechanical Engineers.

Azimuthal correlations of electrons from heavy-flavor decay with hadrons in and Au+Au collisions at = 200 GeV

Adare, A.*; Afanasiev, S.*; Aidala, C.*; Ajitanand, N. N.*; Akiba, Yasuyuki*; Al-Bataineh, H.*; Alexander, J.*; Aoki, Kazuya*; Aphecetche, L.*; Aramaki, Y.*; et al.

Physical Review C, 83(4), p.044912_1 - 044912_16, 2011/04

https://doi.org/10.1103/PhysRevC.83.044912

Measurements of electrons from the decay of open-heavy-flavor mesons have shown that the yields are suppressed in Au+Au collisions compared to expectations from binary-scaled collisions. Here we extend these studies to two particle correlations where one particle is an electron from the decay of a heavy flavor meson and the other is a charged hadron from either the decay of the heavy meson or from jet fragmentation. These measurements provide more detailed information about the interaction between heavy quarks and the quark-gluon matter. We find the away-side-jet shape and yield to be modified in Au+Au collisions compared to collisions.

User's manual of PASCAL-EC for evaluating structural reliability of piping with wall thinning

Ito, Hiroto; Kato, Daisuke*; Onizawa, Kunio; Shibata, Katsuyuki

JAEA-Data/Code 2006-001, 33 Pages, 2006/02

JAEA-Data-Code-2006-001.pdf:1.33MB

As a part of the aging and structural integrity research for LWR components, new probabilistic fracture mechanics (PFM) analysis code PASCAL-EC (PFM Analysis of Structural Components in Aging LWR - Erosion/-Corrosion) has been developed. This code evaluates the failure probability of an aged piping with a wall thinning by Monte Carlo method. PASCAL-EC treats the wall thinning due to erosion/corrosion or flow accelerated corrosion (FAC) in piping. The development of this code has been aimed to improve the accuracy and reliability of analysis by introducing new analysis methodologies and algorithms considering the recent developments in the structural mechanics and aging researches. This report provides the user's manual and theoretical background of PASCAL-EC.

Rise-to-power test in high temperature engineering test reactor in the high temperature test operation mode; Test progress and summary of test results up to 30MW of reactor thermal power

Takamatsu, Kuniyoshi; Nakagawa, Shigeaki; Sakaba, Nariaki; Takada, Eiji*; Tochio, Daisuke; Shimakawa, Satoshi; Nojiri, Naoki; Goto, Minoru; Shibata, Taiju; Ueta, Shohei; et al.

JAERI-Tech 2004-063, 61 Pages, 2004/10

JAERI-Tech-2004-063.pdf:3.14MB

The High Temperature engineering Test Reactor (HTTR) is a graphite moderated and gas cooled reactor with the thermal power of 30MW and the reactor outlet coolant temperature of 850C/950C. Rise-to-power test in the HTTR was performed from March 31th to May 1st in 2004 as phase 5 test up to 30MW in the high temperature test operation mode. It was confirmed that the thermal reactor power and the reactor outlet coolant temperature reached to 30MW and 950C respectively on April 19th in the single operation mode using only the primary pressurized water cooler. The parallel loaded operation mode using the intermediate heat exchanger and the primary pressurized water cooler was performed from June 2nd and JAERI (Japan Atomic Energy Research Institute) obtained the certificate of the pre-operation test on June 24th from MEXT (Ministry of Education Culture Sports Science and Technology) after all the pre-operation tests were passed successfully in the high temperature test operation mode. Achievement of the reactor-outlet coolant temperature of 950C is the first time in the world. It is possible to extend highly effective power generation with a high-temperature gas turbine and produce hydrogen from water with a high-temperature. This report describes the results of the high-temperature test operation of the HTTR.

Probabilistic fracture mechanics analyses of reactor pressure vessel under PTS transients

Onizawa, Kunio; Shibata, Katsuyuki; Kato, Daisuke*; Li, Y.*

JSME International Journal, Series A, 47(3), p.486 - 493, 2004/07

The probabilistic fracture mechanics (PFM) analysis code PASCAL has been developed in JAERI. This code can evaluate the conditional probabilities of crack initiation and fracture of a reactor pressure vessel (RPV) under transient conditions such as pressurized thermal shock (PTS). Based on the temperature and stress distributions in the vessel wall for four PTS sequences in a typical 3-loop PWR, parametric PFM analyses are performed using PASCAL on the variables such as pre-service inspection model, crack geometry, fracture toughness curve and irradiation embrittlement prediction equation. The results showed that the good perfomance inspection model had a significant effect on the fracture probability and reduced it by more than 3 orders of magnitude. The fracture probability calculated by the fracture toughness estimation method in Japan was about 2 orders of magnitude lower than that by the USA method. It was found that the treatment of a semi-elliptical crack in PASCAL reduced the conservatism in a conventional method that it is transformed into an infinite length crack.

Probabilistic fracture mechanics analyses of RPV under some PTS transients

Onizawa, Kunio; Shibata, Katsuyuki; Kato, Daisuke*; Li, Y.*

Proceedings of 11th International Conference on Nuclear Engineering (ICONE-11) (CD-ROM), 8 Pages, 2003/04

Probabilistic Fracture Mechanics (PFM) has been used in the fields of reliability analysis for important structural components. At JAERI, the PFM analysis code PASCAL has been developed. This code evaluates the conditional probabilities of crack initiation and fracture of a reactor pressure vessel (RPV) under transient conditions such as pressurized thermal shock (PTS). Four cases of PTS transients were selected based on the severity for a typical 3-loop PWR. Based on thermal stress analyses, PFM analyses were performed by using PASCAL code focusing on some important variables on the RPV fracture probability. The results showed that non-destructive examination methods had a significant effect on the fracture probability by more than three orders of magnitude. The comparisons of the results using fracture toughness estimation methods between in Japan and USA, and crack geometries between a semi-elliptical surface crack and an infinite surface crack are also made.

Introduction of ductile crack extension analysis model based on R6 method into PFM code PASCAL

Shibata, Katsuyuki; Onizawa, Kunio; Li, Y.*; Kato, Daisuke*

Proceedings of 4th International Workshop on the Integrity of Nuclear Components, p.31 - 41, 2002/00

no abstracts in English

Improvements to a probabilistic fracture mechanics code for evaluating the integrity of a RPV under transient loading

Li, Y.*; Kato, Daisuke*; Shibata, Katsuyuki; Onizawa, Kunio

International Journal of Pressure Vessels and Piping, 78(4), p.271 - 282, 2001/04

https://doi.org/10.1016/S0308-0161(01)00019-9

no abstracts in English