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Journal Articles

Incorporation of boron into metakaolin-based geopolymers for radionuclide immobilisation and neutron capture potential

Niu, X.*; Elakneswaran, Y.*; Li, A.*; Seralathan, S.*; Kikuchi, Ryosuke*; Hiraki, Yoshihisa; Sato, Junya; Osugi, Takeshi; Walkley, B.*

Cement and Concrete Research, 190, p.107814_1 - 107814_17, 2025/04

 Times Cited Count:8 Percentile:85.46(Construction & Building Technology)

Journal Articles

Evaluation on cementation by silicates in bentonite

Saito, Yuki*; Ishiwata, Tobimaru*; Horiuchi, Misato*; Nishiki, Yuto*; Kikuchi, Ryosuke*; Otake, Tsubasa*; Kawakita, Ryohei; Takayama, Yusuke; Mitsui, Seiichiro; Sato, Tsutomu*

Shigen, Sozai Koenshu (Internet), 11(1), 7 Pages, 2024/03

no abstracts in English

Journal Articles

Difference in expansion and dehydration behaviors between NH$$_4$$- and K-montmorillonite

Kawakita, Ryohei; Saito, Akito*; Sakuma, Hiroshi*; Anraku, Sohtaro; Kikuchi, Ryosuke*; Otake, Tsubasa*; Sato, Tsutomu*

Applied Clay Science, 231, p.106722_1 - 106722_7, 2023/01

 Times Cited Count:6 Percentile:43.96(Chemistry, Physical)

Journal Articles

Selenide [Se(-II)] immobilization in anoxic, Fe(II)-rich environments; Coprecipitation and behavior during phase transformations

Francisco, P. C. M.; Matsumura, Daiju; Kikuchi, Ryosuke*; Ishidera, Takamitsu; Tachi, Yukio

Environmental Science & Technology, 56(5), p.3011 - 3020, 2022/03

 Times Cited Count:2 Percentile:8.46(Engineering, Environmental)

Journal Articles

Origin of magnetovolume effect in a cobaltite

Miao, P.*; Tan, Z.*; Lee, S. H.*; Ishikawa, Yoshihisa*; Torii, Shuki*; Yonemura, Masao*; Koda, Akihiro*; Komatsu, Kazuki*; Machida, Shinichi*; Sano, Asami; et al.

Physical Review B, 103(9), p.094302_1 - 094302_18, 2021/03

 Times Cited Count:6 Percentile:30.80(Materials Science, Multidisciplinary)

The layered perovskite PrBaCo$$_{2}$$O$$_{5.5}$$ demonstrates a strong negative thermal expansion (NTE) which holds potential for being fabricated into composites with zero thermal expansion. The NTE was found to be intimately associated with the spontaneous magnetic ordering, known as magneto-volume effect (MVE). Here we report with compelling evidences that the continuous-like MVE in PrBaCo$$_{2}$$O$$_{5.5}$$ is intrinsically of discontinuous character, originating from an magnetoelectric transition from an antiferromagnetic insulating large-volume (AFILV) phase to a ferromagnetic less-insulating small-volume (FLISV) phase. Furthermore, the magnetoelectric effect (ME) shows high sensitivity to multiple external stimuli such as temperature, carrier doping, hydrostatic pressure, magnetic field etc. In contrast to the well-known ME such as colossal magnetoresistance and multi-ferroic effect which involve symmetry breaking of crystal structure, the ME in the cobaltite is purely isostructural. Our discovery provides a new path way to realizing the ME as well as the NTE, which may find applications in new techniques.

Journal Articles

Mineralogical characterization of radioactive particles from Fukushima soil using $$mu$$-XRD with synchrotron radiation

Motai, Satoko*; Mukai, Hiroki*; Watanuki, Tetsu; Owada, Kenji; Fukuda, Tatsuo; Machida, Akihiko; Kuramata, Chisaki*; Kikuchi, Ryosuke*; Yaita, Tsuyoshi; Kogure, Toshihiro*

Journal of Mineralogical and Petrological Sciences, 111(5), p.305 - 312, 2016/10

 Times Cited Count:17 Percentile:45.29(Mineralogy)

no abstracts in English

Journal Articles

Cesium adsorption/desorption behavior of clay minerals considering actual contamination conditions in Fukushima

Mukai, Hiroki*; Hirose, Atsushi*; Motai, Satoko*; Kikuchi, Ryosuke*; Tanoi, Keitaro*; Nakanishi, Tomoko*; Yaita, Tsuyoshi; Kogure, Toshihiro*

Scientific Reports (Internet), 6, p.21543_1 - 21543_7, 2016/02

 Times Cited Count:148 Percentile:96.13(Multidisciplinary Sciences)

Journal Articles

Proximity factor on transformation from subsurface to surface flaw

Hasegawa, Kunio*; Li, Y.; Serizawa, Ryosuke*; Kikuchi, Masanori*; Lacroix, V.*

Procedia Materials Science, 12, p.36 - 41, 2016/00

 Times Cited Count:1 Percentile:57.09(Engineering, Mechanical)

If subsurface flaws are detected that are close to component free surfaces, flaw-to-surface proximity rule is used to determine whether the flaws should be treated as subsurface flaws as is, or transformed to surface flaws. However, specific factors for the proximity rules on transforming subsurface to surface flaws differ among fitness-for-service codes. The objective of the paper is to reveal the proximity factor from the stress intensity factor interaction between the subsurface flaw and the free surface.

Journal Articles

Suppression of time-reversal symmetry breaking superconductivity in Pr(Os$$_{1-x}$$Ru$$_x$$)$$_4$$Sb$$_{12}$$ and Pr$$_{1-y}$$La$$_y$$Os$$_4$$Sb$$_{12}$$

Shu, L.*; Higemoto, Wataru; Aoki, Yuji*; Hillier, A. D.*; Oishi, Kazuki*; Ishida, Kenji*; Kadono, Ryosuke*; Koda, Akihiro*; Bernal, O. O.*; MacLaughlin, D. E.*; et al.

Physical Review B, 83(10), p.100504_1 - 100504_4, 2011/03

 Times Cited Count:36 Percentile:77.11(Materials Science, Multidisciplinary)

Zero-field muon spin relaxation experiments have been carried out in the Pr(Os$$_{1-x}$$Ru$$_x$$)$$_4$$Sb$$_{12}$$ and Pr$$_{1-y}$$La$$_y$$Os$$_4$$Sb$$_{12}$$ alloy systems to investigate broken time-reversal symmetry (TRS) in the superconducting state, signaled by the onset of a spontaneous static local magnetic field B$$_s$$. In both alloy series B$$_s$$ initially decreases linearly with solute concentration. Ru doping is considerably more efficient than La doping, with a 50% faster initial decrease. The data suggest that broken TRS is suppressed for Ru concentration $$xgeq$$0.6 but persists for essentially all La concentrations. Our data support a crystal-field excitonic cooper pairing mechanism for TRS-breaking superconductivity.

Journal Articles

Novel features in filled skutterudites containing rare-earth elements with a plural number of 4f-electrons

Sato, Hideyuki*; Aoki, Yuji*; Kikuchi, Daisuke*; Sugawara, Hitoshi*; Higemoto, Wataru; Oishi, Kazuki; Ito, Takashi; Heffner, R. H.; Saha, S. R.*; Koda, Akihiro*; et al.

Physica B; Condensed Matter, 404(5-7), p.749 - 753, 2009/04

 Times Cited Count:5 Percentile:24.22(Physics, Condensed Matter)

Wide varieties of strongly correlated electron phenomena are performed on the stage of a filled skutterudite structure. Especially when one of the players contains a plural number of 4f electrons, the orbital degrees of freedom play a major role as a new type of nonmagnetic and/or weak-magnetic phenomena. Several examples found in Pr- and Sm-based filled skutterudites are introduced in relation to muon spin relaxation experiments.

Journal Articles

Muon spin relaxation and hyperfine-enhanced $$^{141}$$Pr nuclear spin dynamics in Pr(Os,Ru)$$_4$$Sb$$_{12}$$ and (Pr,La)Os$$_4$$Sb$$_{12}$$

Shu, L.*; MacLaughlin, D. E.*; Aoki, Yuji*; Tsunashima, Yoshino*; Yonezawa, Yuki*; Sanada, Shotaro*; Kikuchi, Daisuke*; Sato, Hideyuki*; Heffner, R. H.; Higemoto, Wataru; et al.

Physical Review B, 76(1), p.014527_1 - 014527_8, 2007/07

 Times Cited Count:22 Percentile:64.52(Materials Science, Multidisciplinary)

Journal Articles

Knight shift measurements in the superconducting state of Pr$$_{1-x}$$La$$_x$$Os$$_4$$Sb$$_{12}$$ (X=0.4) probed by $$mu$$SR

Higemoto, Wataru; Aoki, Yuji*; Oishi, Kazuki; Ito, Takashi; Heffner, R. H.; Saha, S. R.*; Koda, Akihiro*; Sato, Hideyuki*; Kadono, Ryosuke*; Kikuchi, Daisuke*; et al.

Journal of Magnetism and Magnetic Materials, 310(2, Part1), p.620 - 622, 2007/03

no abstracts in English

Journal Articles

Introduction to plasma fusion energy

Takamura, Shuichi*; Kado, Shinichiro*; Fujii, Takashi*; Fujiyama, Hiroshi*; Takabe, Hideaki*; Adachi, Kazuo*; Morimiya, Osamu*; Fujimori, Naoji*; Watanabe, Takayuki*; Hayashi, Yasuaki*; et al.

Kara Zukai, Purazuma Enerugi No Subete, P. 164, 2007/03

no abstracts in English

Journal Articles

Time reversal symmetry breaking in superconducting (Pr,La)Os$$_4$$Sb$$_{12}$$ and Pr(Os,Ru)$$_4$$Sb$$_{12}$$

Shu, L.*; Higemoto, Wataru; Aoki, Yuji*; Frederick, N. A.*; Yuhasz, W. M.*; Heffner, R. H.; Oishi, Kazuki; Ishida, Kenji*; Kadono, Ryosuke*; Koda, Akihiro*; et al.

Journal of Magnetism and Magnetic Materials, 310(2, Part1), p.551 - 553, 2007/00

 Times Cited Count:7 Percentile:33.76(Materials Science, Multidisciplinary)

Oral presentation

Design and characterisation of different characteristics of metakaolin-based geopolymer for fuel debris removal, 1; Assessment of the influence of boron (as a neutron absorber) incorporation

Elakneswaran, Y.*; Niu, X.*; Kikuchi, Ryosuke*; Osugi, Takeshi; Sato, Junya; Hiraki, Yoshihisa; Chaerun, R. I.

no journal, , 

no abstracts in English

Oral presentation

Selenide [Se(-II)] retention and mobilization in anoxic, iron-rich environments; Impacts of iron phase precipitation and transformation

Francisco, P. C. M.; Matsumura, Daiju; Kikuchi, Ryosuke*; Ishidera, Takamitsu; Tachi, Yukio

no journal, , 

Oral presentation

Se(-II, IV) interactions with Fe(II) species and phases under anoxic and reducing conditions

Francisco, P. C. M.; Kikuchi, Ryosuke*; Matsumura, Daiju; Shiwaku, Hideaki; Ishidera, Takamitsu; Tachi, Yukio

no journal, , 

Oral presentation

Relationship between petrographic texture and swelling property in cemented bentonite ores

Ishiwata, Tobimaru*; Kikuchi, Ryosuke*; Otake, Tsubasa*; Sato, Tsutomu*; Kawakita, Ryohei; Takayama, Yusuke; Mitsui, Seiichiro

no journal, , 

It is known that the cementation of bentontie may cause the reduction of swelling pressure. However, fundamental mechanism of this reducing swelling pressure has not been well understood. To understand the mechanism, it is essential to identify the cementitious materials and observe the changes in microstructure associated with cementation. In this study, the microstructural observation and swelling tests were conducted on several bentonite ores collected from Tsukinuno Mine in Yamagata Prefecture, Japan, as natural analog of cementation, and the relationship between petrographic texture and swelling pressure was discussed. Thin sections of bentonite ores were prepared by dry polishing technique to observe flat surfaces in micro scales. Scanning electron microscopy (SEM) demonstrated the widespread distribution of authigenic, a few micron silica in the matrix of montmorillonite. Transmission electron microscopy (TEM) revealed that the micro silica minerals (commonly quartz and less commonly amorphous silica) adhered to the edge of montmorillonite grains. These observations suggest that the adherence of these cementitious materials to montmorillonite prevents water access to the interlayer of montmorillonite and swelling, resulting in a decrease in swelling pressure. While these microstructures were observed commonly in all samples collected from several bentonite beds, the relative abundance of montmorillonite and micro silica minerals varied among different beds. It is possible that the swelling pressure in the cemented bentonite is affected by the relative abundance of montmorillonite and cementitious materials.

Oral presentation

Design and characterisation of different characteristics of metakaolin-based geopolymer for fuel debris removal, 2; Interaction between metakaolin-based geopolymers and colloids

Niu, X.*; Elakneswaran, Y.*; Kikuchi, Ryosuke*; Osugi, Takeshi; Sato, Junya; Hiraki, Yoshihisa; Chaerun, R. I.

no journal, , 

In the Primary Containment Vessel (PCV) of the Fukushima Daiichi Nuclear Power Plant, fuel debris and contaminated water form a complex slurry that contains fine particles and colloids mainly composed of iron, barium, and carbonates. In this study, the physicochemical interactions, structural formation behaviour, and the effects on solidification performance were systematically evaluated when these colloids were incorporated into metakaolin-based geopolymers.

Oral presentation

Selenium reactions in ferrous and sulfide-rich environments; Effects of sulfide speciation

Francisco, P. C. M.; Ishidera, Takamitsu; Shiwaku, Hideaki; Kikuchi, Ryosuke*; Tachi, Yukio

no journal, , 

27 (Records 1-20 displayed on this page)