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photocatalysts by oxidative annealing of TiCChoi, Y.; Umebayashi, Tsutomu; Yamamoto, Shunya; Tanaka, Shigeru
Journal of Materials Science Letters, 22(17), p.1209 - 1211, 2003/09
Times Cited Count:48 Percentile:77.81(Materials Science, Multidisciplinary)no abstracts in English
nanoparticles by pulsed laser ablation; Ambient pressure dependence of crystallizationMatsubara, Masakazu*; Yamaki, Tetsuya; Ito, Hisayoshi; Abe, Hiroaki*; Asai, Keisuke*
Japanese Journal of Applied Physics, Part 2, 42(5A), p.L479 - L481, 2003/05
Pulsed laser ablation with a KrF excimer laser was used to prepare fine particles of titanium dioxide (TiO
). The ablation in an atmosphere of Ar and O
(5:5) at total pressures of
1 Torr led to the formation of TiO
nanoparticles composed of anatase and rutile structures without any suboxides. The weight fraction of the rutile/anatase crystalline phases was controlled by the pressure of the Ar/O
gas. The TiO
nanoparticles had a spherical shape and their size, ranging from 10 and 14 nm, also appeared to be dependent on the ambient pressure.
Choi, Y.; Yamamoto, Shunya; Saito, Hiroshi*; Sumita, Taishi*; Ito, Hisayoshi
Nuclear Instruments and Methods in Physics Research B, 206(1-4), p.241 - 244, 2003/05
Times Cited Count:7 Percentile:46.07(Instruments & Instrumentation)no abstracts in English
thin films grown on
-Al
O
substrates by pulsed laser depositionShinohara, Ryuji*; Yamaki, Tetsuya; Yamamoto, Shunya; Ito, Hisayoshi; Asai, Keisuke*
Journal of Materials Science Letters, 21(12), p.967 - 969, 2002/06
Times Cited Count:10 Percentile:38.43(Materials Science, Multidisciplinary)no abstracts in English
Yamaki, Tetsuya; Asai, Keisuke*
Langmuir, 17(9), p.2564 - 2567, 2001/05
Times Cited Count:44 Percentile:92.20(Chemistry, Multidisciplinary)A new type of TiO
nanosheet-organic complex multilayer film was successfully prepared by the Langmuir-Blodgett technique. Surface pressure-area curves demonstrated that a stable monolayer of dioctadecyldimethylammonium bromide (DODAB) was formed on an aqueous suspension of TiO
nanosheets derived from an exfoliated layered titanate, H
Ti
□
O
・H
O (x
0.7; □, vacancy). The hybrid monolayer of the ammonium amphiphiles and the TiO
nanosheet was quantitatively transferred onto a hydrophobic quartz plate to form a multilayer film. X-ray diffraction measurements confirmed the formation of an ordered structure of DODAB/TiO
with an interlayer distance of 3.4 nm.
F
compounds in fluorine-implanted TiO
Yamaki, Tetsuya; Sumita, Taishi; Yamamoto, Shunya
Journal of Materials Science Letters, 21(1), p.33 - 35, 2001/01
Times Cited Count:91 Percentile:90.45(Materials Science, Multidisciplinary)We showed the effects of 200 keV F
implantation in TiO
rutile single crystals followed by the thermal annealing. The isochronal annealing at 573 and 873 K for 5 h for each step led to the formation of an F-doped TiO
phase, along with the recovery of the radiation damage and the simultaneous impurity diffusion. This phase was identified to be a TiO
F
compound with x = 0.0039 in the outmost region as determined by X-ray photoelectron spectroscopy (probably the first few atomic layers). The fluorination of TiO
leads to interesting characteristics and opens avenues towards photoelectronic films with various applications. In addition, our method enabled dopants to be introduced in a controlled manner at specific locations to realize impurity concentration gradients in TiO
.