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Journal Articles

Fabrication of TiO$$_{2}$$ photocatalysts by oxidative annealing of TiC

Choi, Y.; Umebayashi, Tsutomu; Yamamoto, Shunya; Tanaka, Shigeru

Journal of Materials Science Letters, 22(17), p.1209 - 1211, 2003/09

 Times Cited Count:48 Percentile:77.81(Materials Science, Multidisciplinary)

no abstracts in English

Journal Articles

Preparation of TiO$$_{2}$$ nanoparticles by pulsed laser ablation; Ambient pressure dependence of crystallization

Matsubara, Masakazu*; Yamaki, Tetsuya; Ito, Hisayoshi; Abe, Hiroaki*; Asai, Keisuke*

Japanese Journal of Applied Physics, Part 2, 42(5A), p.L479 - L481, 2003/05

Pulsed laser ablation with a KrF excimer laser was used to prepare fine particles of titanium dioxide (TiO$$_{2}$$). The ablation in an atmosphere of Ar and O$$_{2}$$ (5:5) at total pressures of $$geq$$ 1 Torr led to the formation of TiO$$_{2}$$ nanoparticles composed of anatase and rutile structures without any suboxides. The weight fraction of the rutile/anatase crystalline phases was controlled by the pressure of the Ar/O$$_{2}$$ gas. The TiO$$_{2}$$ nanoparticles had a spherical shape and their size, ranging from 10 and 14 nm, also appeared to be dependent on the ambient pressure.

Journal Articles

Influence of carbon-ion irradiation and hydrogen-plasma treatment on photocatalytic properties of titanium dioxide films

Choi, Y.; Yamamoto, Shunya; Saito, Hiroshi*; Sumita, Taishi*; Ito, Hisayoshi

Nuclear Instruments and Methods in Physics Research B, 206(1-4), p.241 - 244, 2003/05

 Times Cited Count:7 Percentile:46.07(Instruments & Instrumentation)

no abstracts in English

Journal Articles

High-quality epitaxial TiO$$_{2}$$ thin films grown on $$alpha$$-Al$$_{2}$$O$$_{3}$$ substrates by pulsed laser deposition

Shinohara, Ryuji*; Yamaki, Tetsuya; Yamamoto, Shunya; Ito, Hisayoshi; Asai, Keisuke*

Journal of Materials Science Letters, 21(12), p.967 - 969, 2002/06

 Times Cited Count:10 Percentile:38.43(Materials Science, Multidisciplinary)

no abstracts in English

Journal Articles

Alternate multilayer deposition from ammonium amphiphiles and titanium dioxide crystalline nanosheets using the Langmuir-Blodgett technique

Yamaki, Tetsuya; Asai, Keisuke*

Langmuir, 17(9), p.2564 - 2567, 2001/05

 Times Cited Count:44 Percentile:92.20(Chemistry, Multidisciplinary)

A new type of TiO$$_{2}$$ nanosheet-organic complex multilayer film was successfully prepared by the Langmuir-Blodgett technique. Surface pressure-area curves demonstrated that a stable monolayer of dioctadecyldimethylammonium bromide (DODAB) was formed on an aqueous suspension of TiO$$_{2}$$ nanosheets derived from an exfoliated layered titanate, H$$_{x}$$Ti$$_{2-x/4}$$$$_{x/4}$$O$$_{4}$$・H$$_{2}$$O (x$$sim$$0.7; □, vacancy). The hybrid monolayer of the ammonium amphiphiles and the TiO$$_{2}$$ nanosheet was quantitatively transferred onto a hydrophobic quartz plate to form a multilayer film. X-ray diffraction measurements confirmed the formation of an ordered structure of DODAB/TiO$$_{2}$$ with an interlayer distance of 3.4 nm.

Journal Articles

Formation of TiO$$_{2-x}$$F$$_{x}$$ compounds in fluorine-implanted TiO$$_{2}$$

Yamaki, Tetsuya; Sumita, Taishi; Yamamoto, Shunya

Journal of Materials Science Letters, 21(1), p.33 - 35, 2001/01

 Times Cited Count:91 Percentile:90.45(Materials Science, Multidisciplinary)

We showed the effects of 200 keV F$$^{+}$$ implantation in TiO$$_{2}$$ rutile single crystals followed by the thermal annealing. The isochronal annealing at 573 and 873 K for 5 h for each step led to the formation of an F-doped TiO$$_{2}$$ phase, along with the recovery of the radiation damage and the simultaneous impurity diffusion. This phase was identified to be a TiO$$_{2-x}$$F$$_{x}$$ compound with x = 0.0039 in the outmost region as determined by X-ray photoelectron spectroscopy (probably the first few atomic layers). The fluorination of TiO$$_{2}$$ leads to interesting characteristics and opens avenues towards photoelectronic films with various applications. In addition, our method enabled dopants to be introduced in a controlled manner at specific locations to realize impurity concentration gradients in TiO$$_{2}$$.

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