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Li, F.*; Tang, X.*; Fei, Y.*; Zhang, J.*; Liu, J.*; Lang, P.*; Che, G.*; Zhao, Z.*; Zheng, Y.*; Fang, Y.*; et al.
Journal of the American Chemical Society, 147(17), p.14054 - 14059, 2025/04
被引用回数：1 パーセンタイル：56.36(Chemistry, Multidisciplinary)2,2'-ビピラジン(BPZ)の圧力誘起重合により結晶性グラファンナノリボン(GANR)を合成した。中性子回折データのリートベルト精密化,核磁気共鳴スペクトル,赤外スペクトル,理論計算を行った結果、BPZは
積層した芳香環の間でディールス・アルダー重合し、並外れた長距離秩序を持つ伸びたボート型GANR構造を形成することがわかった。未反応の-C=N-基がボートの両端を橋渡ししており、さらなる機能化の余地がある。このGANRのバンドギャップは2.25eVであり、光電応答は良好である(I
/I
=18.8)。われわれの研究は、高圧トポケミカル重合法が、特定の構造と望んだ特性を持つグラファンの精密な合成に有望な方法であることを強調している。
Che, G.*; Fei, Y.*; Tang, X.*; Zhao, Z.*; 服部 高典; 阿部 淳*; Wang, X.*; Ju, J.*; Dong, X.*; Wang, Y.*; et al.
Physical Chemistry Chemical Physics, 27(2), p.1112 - 1118, 2025/01
被引用回数：3 パーセンタイル：51.78(Chemistry, Physical)芳香族分子の圧力誘起重合(PIP)は、様々な炭素系材料を合成するための効果的な方法として浮上してきた。目的とする構造や機能を得るためには、適切な官能基化された分子前駆体の選択が極めて重要である。本研究では、1,4-ジフルオロベンゼン(1,4-DFB)をPIPの構成要素として選択した。1,4-DFBをその場高圧で調べた結果、約12.0GPaで相転移が起こり、18.7GPaで不可逆的な化学反応が起こることがわかった。生成物の構造解析と反応のカイネティクスから、直線的な成長を伴う擬六方晶積層フッ素ダイヤモンドナノスレッドの形成が明らかになった。高圧下のベンゼンの結晶構造と比較して、1,4-DFBは[001]軸に沿って高い圧縮を示す。この異方的な圧縮は、[01
]軸に沿ったより強いH
相互作用と、[100]軸と[010]軸に沿った潜在的な圧縮阻害H
F相互作用に起因し、[01]軸に沿った可能な反応経路を促進する。この研究は、分子スタッキングを調節し、反応経路に影響を与える官能基化の重要な役割を強調している。
; 
SR studies and charge-spin percolation modelSheng, Q.*; 金子 竜也*; Yamakawa, Kohtaro*; Guguchia, Z.*; Gong, Z.*; Zhao, G.*; Dai, G.*; Jin, C.*; Guo, S.*; Fu, L.*; et al.
Physical Review Research (Internet), 4(3), p.033172_1 - 033172_14, 2022/09
A pyrite system NiS
Se
exhibits a bandwidth controlled Mott transition via (S,Se) substitutions in a two-step process: the antiferromagnetic insulator (AFI) to antiferromagnetic metal (AFM) transition at 
0.45 followed by the AFM to paramagnetic metal (PMM) transition at 1.0. Among a few other Mott systems which exhibit similar two-step transitions, Ni(S,Se) is of particular interest because a large intermediate AFM region in the phase diagram would provide unique opportunities to study the interplay between the spin and charge order. By comparing and combining our muon spin relaxation studies and previous neutron scattering studies, here we propose a picture where the spin order is maintained by the percolation of "nonmetallic" localized and dangling Ni moments surrounded by S, while the charge transition from AFI to AFM is caused by the percolation of the conducting paths generated by the Ni-Se-Ni bonds.
K(Zn
Mn
)As studied by X-ray magnetic circular dichroism and resonant inelastic X-ray scattering鈴木 博人*; Zhao, G.*; 岡本 淳*; 坂本 祥哉*; Chen, Z.-Y.*; 野中 洋亮*; 芝田 悟朗; Zhao, K.*; Chen, B.*; Wu, W.-B.*; et al.
Journal of the Physical Society of Japan, 91(6), p.064710_1 - 064710_5, 2022/06
被引用回数：4 パーセンタイル：41.57(Physics, Multidisciplinary)The magnetic properties and the electronic excitations of the new diluted magnetic semiconductor BaK(ZnMn)As have been studied by X-ray magnetic circular dichroism (XMCD) and resonant inelastic X-ray scattering (RIXS). The sum rule analysis of the XMCD spectra indicates that the Mn atoms are in the high-spin configurations of 
, whereas the presence of competing ferromagnetic and antiferromagnetic interactions between the Mn ions reduces the net spin moment. Based on a comparison of the RIXS line shapes with those of GaMnAs, it is concluded that the ground state of Mn in BaK(ZnMn)As consists of both the 
and 
electron configurations.
T
As
(
= Co,Ni)Tam, D. M.*; Song, Y.*; Man, H.*; Cheung, S. C.*; Yin, Z.*; Lu, X.*; Wang, W.*; Frandsen, B. A.*; Liu, L.*; Gong, Z.*; et al.
Physical Review B, 95(6), p.060505_1 - 060505_6, 2017/02
被引用回数：24 パーセンタイル：66.96(Materials Science, Multidisciplinary)We use neutron diffraction and muon spin relaxation to study the effect of in-plane uniaxial pressure on the antiferromagnetic (AF) orthorhombic phase in BaFeTAs and its Co- and Ni-substituted members near optimal superconductivity. In the low-temperature AF ordered state, uniaxial pressure necessary to detwin the orthorhombic crystals also increases the magnetic ordered moment, reaching an 11% increase under 40 MPa for BaFe
Co
As, and a 15% increase for BaFe
Ni
As. We also observe an increase of the AF ordering temperature (
) of about 0.25 K/MPa in all compounds, consistent with density functional theory calculations that reveal better Fermi surface nesting for itinerant electrons under uniaxial pressure. The doping dependence of the magnetic ordered moment is captured by combining dynamical mean field theory with density functional theory, suggesting that the pressure-induced moment increase near optimal superconductivity is closely related to quantum fluctuations and the nearby electronic nematic phase.
(As
P
) superconductorHu, D.*; Yin, Z.*; Zhang, W.*; Ewings, R. A.*; 池内 和彦*; 中村 充孝; Roessli, B.*; Wei, Y.*; Zhao, L.*; Chen, G.*; et al.
Physical Review B, 94(9), p.094504_1 - 094504_7, 2016/09
被引用回数：21 パーセンタイル：62.87(Materials Science, Multidisciplinary)最適Pドープされた超伝導体BaFe(AsP) (T
=30K)におけるスピン励起の温度及びエネルギー依存性が非弾性中性子散乱実験を使って調べられた。我々の実験結果は密度汎関数理論や動的平均場理論で予想される計算結果と矛盾しておらず、BaFe(AsP)における平均プニクトゲン高さの減少が、電子相関の強さを弱め、磁気励起の有効バンド幅の増加に寄与することを示唆している。
plasmas on JT-60U and DIII-D松永 剛; 岡林 典男*; 相羽 信行; Boedo, J. A.*; Ferron, J. R.*; Hanson, J. M.*; Hao, G. Z.*; Heidbrink, W. W.*; Holcomb, C. T.*; In, Y.*; et al.
Nuclear Fusion, 53(12), p.123022_1 - 123022_13, 2013/12
被引用回数：7 パーセンタイル：27.51(Physics, Fluids & Plasmas)In the wall-stabilized high- plasmas in JT-60U and DIII-D, interactions between energetic particle (EP) driven modes (EPdMs) and edge localized modes (ELMs) have been observed. The interaction between the EPdM and ELM are reproducibly observed. Many EP diagnostics indicate that strong correlation between the distorted waveform of the EPdM and the EP transport to edge. The waveform distortion is composed of higher harmonics 
and it looks like a density snake near the plasma edge. According to statistical analyses, the ELM triggering by the EPdMs needs finite level of waveform distortion and pedestal recovery. The ELM pacing by the EPdMs occurs when the repetition frequency of the EPdMs is higher than the natural ELM frequency. Transported EPs by the EPdMs are thought to contribute to change the edge stability.
RbHe, C.*; Shen, S.*; Wen, S.*; Zhu, L.*; Wu, X.*; Li, G.*; Zhao, Y.*; Yan, Y.*; Bai, Z.*; Wu, Y.*; et al.
Physical Review C, 87(3), p.034320_1 - 034320_10, 2013/03
被引用回数：6 パーセンタイル：41.04(Physics, Nuclear)High-spin states of Rb are studied via the fusion-evaporation reactions 
Cu+
F, 
Zn+
O, and 
Zn+
O with the beam energies of 75 MeV, 76 MeV, and 80 MeV, respectively. Twenty-three states with twenty-eight 
transitions are added to the previously proposed level scheme, where the second negative-parity band is significantly pushed up to spins of 22
and 15 and two sidebands are built on the known first negative-parity band. Two successive band crossings with frequencies 0.51 MeV and 0.61 MeV in the 
= 0 branch as well as another one in the =1 branch of the second negative-parity band are observed. Signature inversions occur in the positive-parity and first negative-parity bands at the spins of 11
and 16, respectively. The signature splitting is seen obviously in the second negative-parity band, but the signature inversion is not observed. It is also found that the structure of the two negative-parity bands is similar to that of its isotone 
Y. Signature inversion in the positive-parity yrast band with configuration g9/2 
g9/2 in this nucleus is discussed using the projected shell model.
松永 剛; 岡林 典男*; 相羽 信行; Boedo, J. A.*; Ferron, J. R.*; Hanson, J. M.*; Hao, G. Z.*; Heidbrink, W. W.*; Holcomb, C. T.*; In, Y.*; et al.
Proceedings of 24th IAEA Fusion Energy Conference (FEC 2012) (CD-ROM), 8 Pages, 2013/03
In the wall-stabilized high- plasmas in JT-60U and DIII-D, interactions between energetic particle (EP) driven modes and MHD modes such as edge localized modes (ELMs) have been observed. The ELM triggering by EP driven modes (EPdMs) occurs when the repetition frequency of the EPdMs is higher than that of the ELM. The EPdMs have strong waveform distortion that is composed of higher toroidal harmonics. In particular, EP behavior seems to be sensitive to the waveform distortion, thus, waveform distortion can rapidly increase EP transport to edge. According to statistical analysis, the ELM triggering by the EPdMs infrequently occurs just after the ELM crash. Transported EPs by the EPdMs are thought to contribute to change the edge stability.
トカマクプラズマにおけるMHDモードの振舞い松永 剛; 岡林 典男*; 相羽 信行; Boedo, J. A.*; Ferron, J. R.*; Hanson, J. M.*; Hao, G. Z.*; Heidbrink, W. W.*; Holcomb, C. T.*; In, Y.*; et al.
no journal, ,
高運転では高い核融合出力密度を得ることができるため、コンパクトな原型炉が実現可能である。このような核燃焼・高領域では、MHD安定性が臨界安定に近く、かつ高エネルギーイオンが多数存在するためこれらの相互作用が予想される。JT-60U及びDIII-Dの壁なし限界を超える高プラズマにおいて、高エネルギーイオン駆動不安定性が発生し、抵抗性壁モードや周辺局在化モードを誘発する現象を観測した。これらの誘発現象には、高エネルギーイオン駆動不安定性によって増加した高エネルギーイオンの周辺への輸送がこれらの相互作用と関係していると考えられる。本講演ではJT-60UとDIII-Dでの実験結果について詳細に紹介する。
