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論文

Microscopic origin of the spin-reorientation transition in the kagome topological magnet TbMn$$_{6}$$Sn$$_{6}$$

Huang, Z.*; Wang, W.*; Ye, H.*; Bao, S.*; Shangguan, Y.*; Liao, J.*; Cao, S.*; 梶本 亮一; 池内 和彦*; Deng, G.*; et al.

Physical Review B, 109(1), p.014434_1 - 014434_9, 2024/01

 被引用回数:0

TbMn$$_{6}$$Sn$$_{6}$$ is a correlated topological magnet with a Mn-based kagome lattice, in which a Chern gap opens at the Dirac point at low temperatures. The magnetic moment direction of the ferrimagnetic order changes from in the kagome plane to the out-of-plane upon cooling, which is essential for generating the Chern gap, but the underlying mechanism for the spin reorientation remains elusive. Here, we investigate the spin-reorientation transition in TbMn$$_{6}$$Sn$$_{6}$$ using neutron scattering. We provide direct evidence for the spin-reorientation transition and unveil the coexistence of two Tb modes at 200 K. To account for these results, we put forward a model based on SU(N) spin-wave theory, in which there is a temperature evolution of the ground state Tb $$4f$$ orbitals, driven by the crystalline electric field, single-ion anisotropy, and exchange interactions between Tb and Mn ions. Our findings shed light on the complex magnetism of TbMn$$_{6}$$Sn$$_{6}$$, despite its relatively simple ground state magnetic structure, and provide insights into the mechanisms for tuning magnetic topological materials.

論文

Synergistic hybrid electrocatalysts of platinum alloy and single-atom platinum for an efficient and durable oxygen reduction reaction

Liu, B.*; Feng, R.*; Busch, M.*; Wang, S.*; Wu, H.*; Liu, P.*; Gu, J.*; Bahadoran, A.*; 松村 大樹; 辻 卓也; et al.

ACS Nano, 16(9), p.14121 - 14133, 2022/09

 被引用回数:49 パーセンタイル:98.33(Chemistry, Multidisciplinary)

Pt single-atom materials possess an ideal atom economy but suffer from limited intrinsic activity and side reaction of producing H$$_{2}$$O$$_{2}$$ in catalyzing the oxygen reduction reaction (ORR). Here, we demonstrate that anchoring platinum alloys on single-atom Pt-decorated carbon (Pt- SAC) surmounts their inherent deficiencies, thereby enabling a complete four-electron ORR pathway catalysis with high efficiency and durability. Pt$$_{3}$$Co@Pt-SAC demonstrates an exceptional mass and specific activities 1 order of magnitude higher than those of commercial Pt/C. They are durable throughout 50000 cycles, showing only a 10 mV decay in halfwave potential. The superior durability is attributed to the shielding effect of the Pt-SAC coating, which significantly mitigates the dissolution of Pt$$_{3}$$Co cores.

論文

J/$$psi$$ near $$T_c$$

Song, T.*; Gubler, P.; Hong, J.*; Lee, S. H.*; 森田 健司*

Physics Letters B, 813, p.136065_1 - 136065_5, 2021/02

 被引用回数:3 パーセンタイル:34.88(Astronomy & Astrophysics)

We calculate the mass shift and thermal decay width of the J/$$psi$$ near the QCD transition temperature $$T_c$$ by imposing two independent constraints on these variables that can be obtained first by solving the Schrodinger equation and second from the QCD sum rule approach. While the real part of the potential is determined by comparing the QCD sum rule result for charmonium and the D meson to that from the potential model result, the imaginary potential is taken to be proportional to the perturbative form multiplied by a constant factor, which in turn can be determined by applying the two independent constraints. The result shows that the binding energy and the thermal width becomes similar in magnitude at around T = 1.09 $$T_c$$, above which the sum rule analysis also becomes unstable, strongly suggesting that the J/$$psi$$ will melt slightly above $$T_c$$.

論文

Review of Fukushima Daiichi Nuclear Power Station debris endstate location in OECD/NEA preparatory study on analysis of fuel debris (PreADES) project

仲吉 彬; Rempe, J. L.*; Barrachin, M.*; Bottomley, D.; Jacquemain, D.*; Journeau, C.*; Krasnov, V.; Lind, T.*; Lee, R.*; Marksberry, D.*; et al.

Nuclear Engineering and Design, 369, p.110857_1 - 110857_15, 2020/12

 被引用回数:7 パーセンタイル:30.13(Nuclear Science & Technology)

福島第一原子力発電所(1F)の各ユニットの燃料デブリの最終状態位置については、まだ多くは不明である。不確実性の低減に向けた最初のステップとして、OECD/NEAは、燃料デブリ分析予備的考察(PreADES)プロジェクトが立ち上げた。PreADESプロジェクトのタスク1の一環として、関連情報をレビューし、燃料デブリの状態の推定図の正確さを確認した。これは、将来の燃料デブリの分析を提案するための基礎となる。具体的にタスク1では2つのアクティビティを実施した。第一に、1Fでの廃止措置活動に資するTMI-2とチェルノブイリ原子力発電所4号機での重大事故の関連知識、プロトタイプ試験とホットセル試験の結果の知見を収集した。第二に、プラント情報とBSAFプロジェクトのシビアアクシデントコード分析からの関連知識が組み込まれている1F燃料デブリの原子炉内の状態に関する現状の推定図を見直した。この報告は、PreADESプロジェクトのタスク1の洞察に焦点を当て、1Fの将来の除染および廃止措置活動に情報を提供するだけでなく、シビアアクシデント研究、特にシビアアクシデントにより損傷した原子力サイトの長期管理に関する重要な視点を提供する。

論文

Main findings, remaining uncertainties and lessons learned from the OECD/NEA BSAF Project

Pellegrini, M.*; Herranz, L.*; Sonnenkalb, M.*; Lind, T.*; 丸山 結; Gauntt, R.*; Bixler, N.*; Morreale, A.*; Dolganov, K.*; Sevon, T.*; et al.

Nuclear Technology, 206(9), p.1449 - 1463, 2020/09

 被引用回数:35 パーセンタイル:98.28(Nuclear Science & Technology)

The OECD/NEA Benchmark Study at the Accident of Fukushima Daiichi Nuclear Power Station (BSAF) project, which started in 2012 and continued until 2018, was one of the earliest responses to the accident at Fukushima Daiichi. The project, divided into two phases addressed the investigation of the accident at Unit 1, 2 and 3 by Severe Accident (SA) codes until 500 h focusing on thermal-hydraulics, core relocation, Molten Corium Concrete Interaction (MCCI) and fission products release and transport. The objectives of BSAF were to make up plausible scenarios based primarily on SA forensic analysis, support the decommissioning and inform SA codes modeling. The analysis and comparison among the institutes have brought up vital insights regarding the accident progression identifying periods of core meltdown and relocation, Reactor Pressure Vessel (RPV) and Primary Containment Vessel (PCV) leakage/failure through the comparison of pressure, water level and CAMS signatures. The combination of code results and inspections (muon radiography, PCV inspection) has provided a picture of the current status of the debris distribution and plant status. All units present a large relocation of core materials and all of them present ex-vessel debris with Unit 1 and Unit 3 showing evidences of undergoing MCCI. Uncertainties have been identified in particular on the time and magnitude of events such as corium relocation in RPV and into cavity floor, RPV and PCV rupture events. Main uncertainties resulting from the project are the large and continuous MCCI progression predicted by basically all the SA codes and the leak pathways from RPV to PCV and PCV to reactor building and environment. The BSAF project represents a pioneering exercise which has set the basis and provided lessons learned not only for code improvement but also for the development of new related projects to investigate in detail further aspects of the Fukushima Daiichi accident.

論文

Current situation of OECD/NEA, Preparatory Study on Analysis of Fuel debris (PreADES) project

仲吉 彬; Journeau, C.*; Rempe, J.*; Barrachin, M.*; Bottomley, D.; Nauchi, Y.*; Song, J. H.*

Proceedings of 2019 International Workshop on Post-Fukushima Challenges on Severe Accident Mitigation and Research Collaboration (SAMRC 2019) (USB Flash Drive), 6 Pages, 2019/11

In recognition of the broad international interest in learning from post-accident examinations and other activities related to the Fukushima Daiichi Nuclear Power Station (1F), Japan recommended, to the Organization for Economic Co-operation and Development/Nuclear energy Agency/Committee on Safety of Nuclear Installations (OECD/NEA/CSNI) in 2013, that they identified and followed up on opportunities to address safety research gaps. The CSNI set up the Senior Expert Group (SEG) on Safety Research Opportunities Post-Fukushima (SAREF). In 2016-2017, Preparatory Study on Analysis of Fuel Debris (PreADES) project was recommended by the SEG on SAREF as a near-term project. The PreADES project will summarize the collected knowledge and expertise of debris characterization and identify the needs for debris analyses that will most contribute to the decommissioning of 1F. The project also aims to improve the understanding of severe accidents and reactor safety assessments as well as creating appropriate and optimal methodologies for future debris sampling, retrieval, and storage. Consequently, the project provides important input for a future international project of sample examination based on long-term considerations. The PreADES project launched discussions among interested organizations at the preliminary meeting in July 2017 about the objectives, scope, output, and direction of the project. The contents of the PreADES project were agreed as the three following tasks: Task 1: Joint study on fuel debris' expected properties and characterization, Task 2: Identifying needs and major issues for future fuel debris sampling, retrieval, and analyses, Task 3: Planning of future international R&D framework. Currently, 4th meeting took place on July in Tokyo Japan. Task 1 is almost completed and Task 2 will be summarized soon.

論文

Comparison of heavy-ion transport simulations; Collision integral with pions and $$Delta$$ resonances in a box

小野 章*; Xu, J.*; Colonna, M.*; Danielewicz, P.*; Ko, C. M.*; Tsang, M. B.*; Wang, Y,-J.*; Wolter, H.*; Zhang, Y.-X.*; Chen, L.-W.*; et al.

Physical Review C, 100(4), p.044617_1 - 044617_35, 2019/10

AA2019-0025.pdf:2.76MB

 被引用回数:58 パーセンタイル:98.56(Physics, Nuclear)

2017年4月に開催された国際会議Transport2017において、重イオン核反応モデルの国際的な比較が議論された。重イオン加速器の安全評価や宇宙飛行士の被ばく評価等で重要な役割を果たすため、世界中で重イオン核反応の様々な理論モデルが開発されている。本研究では、辺の長さが20fmの直方体に320個の中性子と陽子をランダム配置し、それらが70fm/cの間に起こす散乱の回数やエネルギーを計算した。ここでは、特にパイオンやその前駆体であるデルタ共鳴の生成に注目して比較を行った。参加コードは、個々の粒子の時間発展を追うQMD型コードと、粒子の位置や運動量の確率分布を決めておき、散乱や崩壊が発生したときそれらを乱数サンプリングするBUU型コードがあり、発表者が用いたJQMDは前者に属する。本研究により、計算における時間刻みが各コードによる結果の差の主な原因であることが分かった。さらに、今後のJQMDの改良方針の策定に有益な知見を得ることができた。

論文

Main findings, remaining uncertainties and lessons learned from the OECD/NEA BSAF Project

Pellegrini, M.*; Herranz, L.*; Sonnenkalb, M.*; Lind, T.*; 丸山 結; Gauntt, R.*; Bixler, N.*; Morreale, A.*; Dolganov, K.*; Sevon, T.*; et al.

Proceedings of 18th International Topical Meeting on Nuclear Reactor Thermal Hydraulics (NURETH-18) (USB Flash Drive), p.1147 - 1162, 2019/08

The OECD/NEA Benchmark Study at the Accident of the Fukushima Daiichi NPS project (BSAF) has started in 2012 until 2018 as one of the earliest responses to the accident at Fukushima Daiichi NPS. The project addressed the investigation of the accident at Units 1, 2 and 3 by severe accident (SA) codes focusing on thermal-hydraulics, core relocation, molten core/concrete interaction (MCCI) and fission products release and transport. The objectives of BSAF were to make up plausible scenarios based primarily on SA forensic analysis, support the decommissioning and inform SA codes modeling. The analysis and comparison among the institutes have brought up vital insights regarding the accident progression identifying periods of core meltdown and relocation, reactor vessel (RV) and primary containment vessel (PCV) leakage/failure through the comparison of pressure, water level and CAMS measurement. The combination of code results and inspections has provided a picture of the current state of the debris distribution and plant state. All units present a large relocation of core materials and all of them present ex-vessel debris with units 1 and 3 showing evidences of undergoing MCCI. Uncertainties have been identified in particular on the time and magnitude of events such as corium relocation in RV and into cavity floor, RV and PCV rupture events. Main uncertainties resulting from the project are the large and continuous MCCI progression predicted by basically all the SA codes and the leak pathways from RV to PCV and PCV to reactor building and environment. The BSAF project represents a pioneering exercise which has set the basis and provided lessons learned not only for code improvement but also for the development of new related projects to investigate in details further aspects of the Fukushima Daiichi NPS accident.

論文

Comparison of heavy-ion transport simulations; Collision integral in a box

Zhang, Y.-X.*; Wang, Y,-J.*; Colonna, M.*; Danielewicz, P.*; 小野 章*; Tsang, M. B.*; Wolter, H.*; Xu, J.*; Chen, L.-W.*; Cozma, D.*; et al.

Physical Review C, 97(3), p.034625_1 - 034625_20, 2018/03

 被引用回数:98 パーセンタイル:99.11(Physics, Nuclear)

2017年4月に開催された国際会議Transport2017において、重イオン核反応モデルの国際的な比較が議論された。重イオン加速器の安全評価や宇宙飛行士の被ばく評価等で重要な役割を果たすため、世界中で重イオン核反応の様々な理論モデルが開発されている。本研究はモデル間の共通点と差異を明らかにし、各モデルの問題点を明らかにした。比較において、辺の長さが20fmの直方体に320個の中性子と320個の陽子をランダム配置し、それらが時間発展に伴って起こす散乱の回数や散乱時のエネルギーなどを計算する条件が設定された。また、結果以外にも、理論モデルを構成するアルゴリズムについても比較を行った。発表者は重イオン核反応モデルJQMD(JAERI Quantum Molecular Dynamics)を用いて計算を行い、世界で開発されている15の計算コードによる計算結果と比較した。コードアルゴリズムの比較では、JQMDは必ず陽子から 優先的に衝突確率を計算し、その後に中性子の衝突を計算するため、物理描像の妥当性が指摘された。一方、JQMDは他のモデルとほぼ同じ計算結果を出すことも判明した。衝突回数や運動量の計算値が平均から2倍以上乖離するモデルもある中で、JQMDは本計算条件で安定した性能を発揮することが確認された。

論文

Overall approaches and experiences of first-time participants in the Nuclear Forensics International Technical Working Group's Fourth Collaborative Material Exercise (CMX-4)

Ho, D. M. L.*; Nelwamondo, A. N.*; 大久保 綾子; Rameb$"a$ck, H.*; Song, K.*; Han, S.-H.*; Hancke, J. J.*; Holmgren, S.*; Jonsson, S.*; 片岡 修; et al.

Journal of Radioanalytical and Nuclear Chemistry, 315(2), p.353 - 363, 2018/02

 被引用回数:2 パーセンタイル:20.93(Chemistry, Analytical)

国際核鑑識作業グループが主催する第4回核鑑識共同試料分析演習には、過去最大の17か国からの参加があり、このうち7か国は初めての参加であった。本稿では、演習に初めて参加した5か国のラボラトリが、演習で実施した分析試料の準備および分析内容について情報を共有した。核鑑識共同試料分析演習は、各ラボラトリで確立した分析法のテスト、他の目的で確立した方法の核鑑識への適用化、分析技術の修練に非常に有用であることが確認された。また、演習実施後に開催されたレビュー会合によって、核鑑識シグネチャとその解釈に関する理解を深めることができた。

論文

The Application of radiochronometry during the 4th collaborative materials exercise of the nuclear forensics international technical working group (ITWG)

Kristo, M. J.*; Williams, R.*; Gaffney, A. M.*; Kayzar-Boggs, T. M.*; Schorzman, K. C.*; Lagerkvist, P.*; Vesterlund, A.*; Rameb$"a$ck, H.*; Nelwamondo, A. N.*; Kotze, D.*; et al.

Journal of Radioanalytical and Nuclear Chemistry, 315(2), p.425 - 434, 2018/02

 被引用回数:14 パーセンタイル:81.7(Chemistry, Analytical)

最新の核鑑識国際共同試料分析演習では、低濃縮ウラン試料について、10か国の核鑑識ラボラトリーが精製年代測定を実施して良好な結果を得た。これらの測定のうち、3つの異なる核種ペアを用いた精製年代測定も実施された。10か国の核鑑識ラボラトリーが提出した精製年代測定の結果は、実際の精製日と概ね一致した。また、質量分析法による結果は、放射線計測法を用いたものに比べて、高精度な結果を示した。さらに、一部のラボラトリーによって示された$$^{235}$$U-$$^{231}$$Pa法と$$^{234}$$U-$$^{230}$$Th法による精製年代測定の結果の一致は、結果の確証性を高めた。

論文

Uniaxial pressure effect on the magnetic ordered moment and transition temperatures in BaFe$$_{2-x}$$T$$_{x}$$As$$_{2}$$ ($$T$$ = Co,Ni)

Tam, D. M.*; Song, Y.*; Man, H.*; Cheung, S. C.*; Yin, Z.*; Lu, X.*; Wang, W.*; Frandsen, B. A.*; Liu, L.*; Gong, Z.*; et al.

Physical Review B, 95(6), p.060505_1 - 060505_6, 2017/02

 被引用回数:23 パーセンタイル:71.49(Materials Science, Multidisciplinary)

We use neutron diffraction and muon spin relaxation to study the effect of in-plane uniaxial pressure on the antiferromagnetic (AF) orthorhombic phase in BaFe$$_{2-x}$$T$$_{x}$$As$$_{2}$$ and its Co- and Ni-substituted members near optimal superconductivity. In the low-temperature AF ordered state, uniaxial pressure necessary to detwin the orthorhombic crystals also increases the magnetic ordered moment, reaching an 11% increase under 40 MPa for BaFe$$_{1.9}$$Co$$_{0.1}$$As$$_2$$, and a 15% increase for BaFe$$_{1.915}$$Ni$$_{0.085}$$As$$_2$$. We also observe an increase of the AF ordering temperature ($$T_N$$) of about 0.25 K/MPa in all compounds, consistent with density functional theory calculations that reveal better Fermi surface nesting for itinerant electrons under uniaxial pressure. The doping dependence of the magnetic ordered moment is captured by combining dynamical mean field theory with density functional theory, suggesting that the pressure-induced moment increase near optimal superconductivity is closely related to quantum fluctuations and the nearby electronic nematic phase.

論文

Commissioning results of the KSTAR neutral beam system

Bae, Y. S.*; Park, Y. M.*; Kim, J. S.*; Han, W. S.*; Kwak, S. W.*; Chang, Y. B.*; Park, H. T.*; Song, N. H.*; Chang, D. H.*; Jeong, S. H.*; et al.

Proceedings of 23rd IAEA Fusion Energy Conference (FEC 2010) (CD-ROM), 9 Pages, 2011/03

中性粒子入射(NBI)システムは、韓国超伝導トカマク先進研究装置(KSTAR)における高性能運転と長パルス運転のためのイオン加熱と電流駆動を行うように設計された。KSTAR用NBIは2つのビームラインで構成されている。各々のビームラインはイオン源1台あたり最大ビームエネルギー120keVで重水素中性粒子ビームパワー2.5MW以上を入射できるよう設計されたイオン源を3台内蔵している。したがって、KSTAR用NBIシステムの最終目標は2つのビームラインで重水素中性粒子ビームパワー14MW以上の入射を目指している。NBIシステムの計画に則り、各々のコンポーネントとサブシステムの試運転を含めた2010年活動においては、最初のNBIシステムにより、KSTARトカマク・プラズマへ1台のイオン源からビーム入射を行うことである。この論文では、1台のイオン源を用いた最初のNBIシステムの建設と調整運転について紹介する。

論文

Status and result of the KSTAR upgrade for the 2010's campaign

Yang, H. L.*; Kim, Y. S.*; Park, Y. M.*; Bae, Y. S.*; Kim, H. K.*; Kim, K. M.*; Lee, K. S.*; Kim, H. T.*; Bang, E. N.*; Joung, M.*; et al.

Proceedings of 23rd IAEA Fusion Energy Conference (FEC 2010) (CD-ROM), 8 Pages, 2011/03

韓国超伝導トカマク先進研究装置(KSTAR)における高楕円度でダイバータ配位を有するプラズマ生成を目指した2010年の運転のため、プラズマ形状制御に不可欠なハードウェア・システムが新たに据え付けられ改良された。この論文では、改良されたシステムの一般的な構成の概要を述べる。さらに、システムにおいてキーとなる幾つかの性能と試験結果についても報告する。

論文

Study of ion-beam-induced damage and luminescence properties in terbium-implanted AlGaN

Park, J.-H.*; 若原 昭浩*; 岡田 浩*; 古川 雄三*; Kim, Y.-T.*; Chang, H.-J.*; Song, J.*; Shin, S.*; Lee, J.-H.*; 佐藤 真一郎; et al.

Japanese Journal of Applied Physics, 49(3), p.032401_1 - 032401_5, 2010/03

 被引用回数:1 パーセンタイル:5.52(Physics, Applied)

Terbium (Tb) ions were implanted into Al$$_{0.35}$$Ga$$_{0.65}$$N epitaxial layers at room temperature to investigate ion-beam-induced damage and luminescence properties at various doses of $$1times 10^{12}$$ - $$2.8times 10^{16}$$ Tb/cm$$^2$$. Rutherford backscattering spectrometry/channeling (RBS/channeling) reveals that on-beam-induced damage level steeply increases and that the damage cannot be fully recovered even after rapid thermal annealing at 1100 $$^{circ}$$C, when the dose exceeds $$5times 10^{14}$$ Tb/cm$$^2$$. On the other hand, cathodoluminescence (CL) intensity related to Tb$$^{3+}$$ transitions increased initially and saturated above a dose of $$1times 10^{13}$$ Tb/cm$$^2$$. The results suggest that Tb-related luminescence properties are much susceptible to defects and nonradiative defects, namely, Tb-defect complexes, are formed under low-dose conditions even at a very low structural defect density.

論文

Electronic structure and magnetism of the diluted magnetic semiconductor Fe-doped ZnO nanoparticles

片岡 隆史*; 小林 正起*; 坂本 勇太*; Song, G. S.*; 藤森 淳*; Chang, F.-H.*; Lin, H.-J.*; Huang, D. J.*; Chen, C. T.*; 大河内 拓雄*; et al.

Journal of Applied Physics, 107(3), p.033718_1 - 033718_7, 2010/02

AA2009-0977.pdf:1.0MB

 被引用回数:54 パーセンタイル:86.13(Physics, Applied)

We have studied the electronic structure of Fe-doped ZnO nanoparticles, which have been reported to show ferromagnetism at room temperature, by X-ray photoemission spectroscopy (XPS), resonant photoemission spectroscopy (RPES), X-ray absorption spectroscopy (XAS) and X-ray magnetic circular dichroism (XMCD). From the experimental and cluster-model calculation results, we find that Fe atoms are predominantly in the Fe$$^{3+}$$ ionic state with mixture of a small amount of Fe$$^{2+}$$ and that Fe$$^{3+}$$ ions are dominant in the surface region of the nanoparticles. It is shown that the room temperature ferromagnetism in the Fe-doped ZnO nanoparticles is primarily originated from the antiferromagnetic coupling between unequal amounts of Fe$$^{3+}$$ ions occupying two sets of nonequivalent positions in the region of the XMCD probing depth of $$sim$$2-3 nm.

論文

Hybridization between the conduction band and 3$$d$$ orbitals in the oxide-based diluted magnetic semiconductor In$$_{2-x}$$V$$_x$$O$$_3$$

小林 正起*; 石田 行章*; Hwang, J. I.*; Song, G. S.*; 滝沢 優*; 藤森 淳; 竹田 幸治; 大河内 拓雄*; 岡根 哲夫; 斎藤 祐児; et al.

Physical Review B, 79(20), p.205203_1 - 205203_5, 2009/05

 被引用回数:7 パーセンタイル:33.2(Materials Science, Multidisciplinary)

The electronic structure of In$$_{2-x}$$V$$_x$$O$$_3$$ ($$x=0.08$$) has been investigated by photoemission spectroscopy and X-ray absorption spectroscopy (XAS). The V $$2p$$ core-level photoemission and XAS spectra revealed that the V ion is in the trivalent state, which is the same valence state as that of In in In$$_2$$O$$_3$$. The V $$3d$$ partial density of states obtained by the resonant photoemission technique showed a sharp peak above the O $$2p$$ band. While the O $$1s$$ XAS spectrum of In$$_{2-x}$$V$$_x$$O$$_3$$ was similar to that of In$$_2$$O$$_3$$, there were differences in the In $$3p$$ and $$3d$$ XAS spectra between the V-doped and pure In$$_2$$O$$_3$$. The observations give clear evidence for hybridization between the In-derived conduction band and the V $$3d$$ orbitals in In$$_{2-x}$$V$$_x$$O$$_3$$.

論文

Systematic changes of the electronic structure of the diluted ferromagnetic oxide Li-doped Ni$$_{1-x}$$Fe$$_x$$O with hole doping

小林 正起*; Hwang, J. I.*; Song, G.*; 大木 康弘*; 滝沢 優*; 藤森 淳; 竹田 幸治; 藤森 伸一; 寺井 恒太*; 岡根 哲夫; et al.

Physical Review B, 78(15), p.155322_1 - 155322_4, 2008/10

 被引用回数:5 パーセンタイル:26.23(Materials Science, Multidisciplinary)

The electronic structure of Li-doped Ni$$_{1-x}$$Fe$$_x$$O has been investigated using photoemission spectroscopy (PES) and X-ray absorption spectroscopy (XAS). The Ni $$2p$$ core-level PES and XAS spectra were not changed by Li doping. In contrast, the Fe$$^{3+}$$ intensity increased with Li doping relative to the Fe$$^{2+}$$ intensity. However, the increase of Fe$$^{3+}$$ is only $$sim 5%$$ of the doped Li content, suggesting that most of the doped holes enter the O $$2p$$ and/or the charge-transferred configuration Ni $$3d^8underline{L}$$. The Fe $$3d$$ partial density of states and the host valence-band emission near valence-band maximum increased with Li content, consistent with the increase of electrical conductivity. Based on these findings, percolation of bound magnetic polarons is proposed as an origin of the ferromagnetic behavior.

論文

Electronic structure of Ga$$_{1-x}$$Cr$$_{x}$$N and Si-doping effects studied by photoemission and X-ray absorption spectroscopy

Song, G.*; 小林 正起*; Hwang, J. I.*; 片岡 隆*; 滝沢 優*; 藤森 淳; 大河内 拓雄; 竹田 幸治; 岡根 哲夫; 斎藤 祐児; et al.

Physical Review B, 78(3), p.033304_1 - 033304_4, 2008/07

 被引用回数:8 パーセンタイル:37.3(Materials Science, Multidisciplinary)

The electronic structure of the magnetic semiconductor Ga$$_{1-x}$$Cr$$_{x}$$N, and the effect of Si doping on it have been investigated by photoemission and soft X-ray absorption spectroscopy. We have confirmed that Cr in GaN is predominantly trivalent when substituting for Ga and that Cr 3$$d$$ states appear within the band gap of GaN just above the N 2$$p$$-derived valence-band maximum. As a result of Si doping, downward shifts of the core levels (except for Cr 2$$p$$) and the formation of new states near the Fermi level were observed, which we attribute to the upward chemical-potential shift and the formation of a small amount of Cr$$^{2+}$$ species caused by electron doping. Possibility of Cr-rich cluster growth by Si doping are discussed based on the spectroscopic and magnetization data.

論文

Local electronic structure of Cr in the II-VI diluted ferromagnetic semiconductor Zn$$_{1-x}$$Cr$$_x$$Te

小林 正起*; 石田 行章*; Hwang, J. I.*; Song, G. S.*; 藤森 淳; Yang, C. S.*; Lee, L.*; Lin, H.-J.*; Huang, D.-J.*; Chen, C. T.*; et al.

New Journal of Physics (Internet), 10, p.055011_1 - 055011_15, 2008/05

 被引用回数:15 パーセンタイル:64.38(Physics, Multidisciplinary)

The electronic structure of the Cr ions in the diluted ferromagnetic semiconductor Zn$$_{1-x}$$Cr$$_x$$Te ($$x$$=0.03 and 0.15) thin films has been investigated using X-ray magnetic circular dichroism (XMCD) and photoemission spectroscopy (PES). The line shape of the Cr $$2p$$ XMCD spectra is independent of $$H$$, $$T$$, and $$x$$, indicating that the ferromagnetism is originated from the same electronic states of the Cr ion. Cluster-model analysis indicates that the ferromagnetic XMCD signal is originated from Cr ions substituted for the Zn site. The Cr $$3d$$ partial density of states extracted using Cr $$2p to 3d$$ resonant PES shows a broad feature near the top of the valence band, suggesting strong $$s$$,$$p$$-$$d$$ hybridization. Based on these findings, we conclude that double exchange mechanism cannot explain the ferromagnetism in Zn$$_{1-x}$$Cr$$_{x}$$Te.

口頭

Recent progress in ITER tritium plant systems design and layout

Glugla, M.*; Beloglazov, S.*; Carlson, B.*; Cho, S.*; Cristescu, I.*; Cristecu, I.*; Chung, H.*; Girard, J.-P.*; 林 巧; Mardoch, D.*; et al.

no journal, , 

For the operation of ITER with equimolar DT mixtures a rather complex chemical plant -the ITER tritium plant - is needed. Fuel cycle systems are designed to process considerable and unprecedented DT flow rates with high flexivility and reliability. Multiple confinement of tritium will be achieved through passive physical barriers and active detritiation systems. High decomtamination factor for effluent and release streams and low tritium inventories in all systems are required to minimize chronic and accidental emissions, respectively. The paper will provide an update of all aspects of the ITER tritium plant design, will report on construction supporting R&D and will identify issues remaining for the immediate future.

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