Initialising ...
Initialising ...
Initialising ...
Initialising ...
Initialising ...
Initialising ...
Initialising ...
neutron imaging and diffraction analysis revealing spatial lithiation phase evolution in an ultra-thick graphite electrodeStrobl, M.*; Baur, M. E.*; Samothrakitis, S.*; Malamud, F.*; Zhang, X.*; Tung, P. K. M.*; Schmidt, S.*; Woracek, R.*; Lee, J.*; 鬼柳 亮嗣; et al.
Advanced Energy Materials, 15(20), p.2405238_1 - 2405238_9, 2025/05
被引用回数：8 パーセンタイル：93.13(Chemistry, Physical)Energy-efficient, safe, and reliable Li-ion batteries (LIBs) are required for a wide range of applications. The introduction of ultra-thick graphite anodes, desired for high energy densities, meets limitations in internal electrode transport properties, leading to detrimental consequences. Yet, there is a lack of experimental tools capable of providing a complete view of local processes. Here, a multi-modal measurement approach is introduced, enabling quantitative spatio-temporal observations of Li concentrations and intercalation phases in ultra-thick graphite electrodes. Neutron imaging and diffraction concurrently provide correlated multiscale information from the scale of the cell down to the crystallographic scale. In particular, the evolving formation of the solid electrolyte interphase (SEI), observation of gradients in total lithium content, as well as in the formation of ordered Li
C
phases and trapped lithium are mapped throughout the first charge-discharge cycle of the cell. Different lithiation stages co-exist during charging and discharging; delayed lithiation and delithiation processes are observed in central regions of the electrode, while the SEI formation, potential plating, and dead lithium are predominantly found closer to the interface with the separator. The study emphasizes the potential to investigate Li-ion diffusion and the kinetics of lithiation phase formation in thick electrodes.
Pandian, K.*; Neikter, M.*; Ekh, M.*; Harjo, S.; 川崎 卓郎; Woracek, R.*; Hansson, T.*; Pederson, R.*
JOM, 77(4), p.1803 - 1815, 2025/04
被引用回数：2 パーセンタイル：74.40(Materials Science, Multidisciplinary)To produce dense Ti-6Al-4V components, electron beam powder bed fusion is typically followed by post-heat treatment like hot isostatic pressing (HIP). Standard HIP at 920
C/100 MPa for 2 h coarsens the microstructure and reduces yield strength, while low-temp HIP at 800C/200 MPa for 2 h limits coarsening and retains strength comparable to as-built material. A coarser microstructure negatively affects tensile properties. Tensile tests at various temperatures suggest that thermally activated slip systems may influence elongation, requiring further study. In situ neutron time-of-flight diffraction during tensile loading enables analysis of strain evolution and slip plane activity. A two-phase elastic-plastic self-consistent model was used to compare with experiments. Results show basal slip {0002} activated at 20C, pyramidal slip {10-11} at 350C, and 
phase carrying higher stress than 
in the plastic regime.
Morgano, M.*; Kalentics, N.*; Carminati, C.*; Capek, J.*; Makowska, M.*; Woracek, R.*; Maimaitiyili, T.*; 篠原 武尚; Loge, R.*; Strobl, M.*
Additive Manufacturing, 34, p.101201_1 - 101201_6, 2020/08
被引用回数：28 パーセンタイル：68.22(Engineering, Manufacturing)Additive manufacturing is a promising and rapidly rising technology in metal processing. However, besides a number of key advantages the constitution of a part through a complex thermo-mechanical process implies also some severe issues with the potential of impacting the quality of products. In laser powder bed fusion (LPBF) the repetitive heating and cooling cycles induce severe strains in the built material, which can have a number of adverse consequences such as deformation, cracking and decreased fatigue life that might lead to severe failure even already during processing. Here we demonstrate how lattice strains implied by LPBF and laser shock peening (LSP) can efficiently be characterized through diffraction contrast neutron imaging. Despite the spatial resolution need with regards to the significant gradients of the stress distribution and the specific microstructure, which prevent the application of more conventional methods, Bragg edge imaging succeeds to provide essential two-dimensionally spatial resolved strain maps in full field single exposure measurements.
