Initialising ...
Initialising ...
Initialising ...
Initialising ...
Initialising ...
Initialising ...
Initialising ...
半那 拓*; 松石 聡*; 樹神 克明; 大友 季哉*; 社本 真一; 細野 秀雄*
Physical Review B, 87(2), p.020401_1 - 020401_5, 2013/01
被引用回数:35 パーセンタイル:78.6(Materials Science, Multidisciplinary)Manganese oxyarsenide hydrides LaMnAsOH ( = 0-0.73) were synthesized by a solid state reaction under a high pressure of 2 GPa. The hydride ions H in O sites induced an insulator-to-metal conversion and suppressed the antiferromagnetic ordering of Mn spins. Instead, ferromagnetism with negative magnetoresistance was observed. The Curie temperature and saturated moment per Mn increased with up to 264 K and 1.5 , respectively, at = 0.73. These results indicate that H donate conduction electrons to the MnAs layer, mediating a direct ferromagnetic interaction between Mn atoms.
松石 聡*; 半那 拓*; 村場 善行*; Kim, S. W.*; Kim, J. E.*; 高田 昌樹*; 社本 真一; Smith, R. I.*; 細野 秀雄*
Physical Review B, 85(1), p.014514_1 - 014514_6, 2012/01
被引用回数:46 パーセンタイル:84.61(Materials Science, Multidisciplinary)LnFeAsOH(=lanthanoid)の1111型鉄系超伝導体を代表して、CeFeAsO(D,H) (=0.0-0.48)で粉末中性子回折と放射光X線回折測定を行った。これらの結果は、出発物質の水素の種類に関係なく両方の試料でHイオンが酸素サイトを占めていることを強く示唆している。
半那 拓*; 村場 善行*; 松石 聡*; 井川 直樹; 樹神 克明; 社本 真一; 細野 秀雄*
Physical Review B, 84(2), p.024521_1 - 024521_7, 2011/07
被引用回数:102 パーセンタイル:94.65(Materials Science, Multidisciplinary)Utilizing the high stability of calcium and rare-earth hydrides, CaFeAsFH ( = 0.0-1.0) and SmFeAsOH ( = 0.0-0.47) have been synthesized using high pressure to form hydrogen-substituted 1111-type iron-arsenide superconductors. Neutron diffraction and density functional calculations have demonstrated that the hydrogens are incorporated as H ions occupying F sites in the blocking layer of CaFeAsF. The resulting CaFeAsOH is nonsuperconducting, whereas, SmFeAsOH is a superconductor, with an optimal =55 K at 0.2. It was found that up to 40% of the O ions can be replaced by H ions, with electrons being supplied into the FeAs layer to maintain neutrality (O = H + e). When exceeded 0.2, was reduced corresponding to an electron overdoped region.