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論文

Sodium-cooled Fast Reactors

大島 宏之; 森下 正樹*; 相澤 康介; 安藤 勝訓; 芦田 貴志; 近澤 佳隆; 堂田 哲広; 江沼 康弘; 江連 俊樹; 深野 義隆; et al.

Sodium-cooled Fast Reactors; JSME Series in Thermal and Nuclear Power Generation, Vol.3, 631 Pages, 2022/07

ナトリウム冷却高速炉(SFR: Sodium-cooled Fast Reactor)の歴史や、利点、課題を踏まえた安全性、設計、運用、メンテナンスなどについて解説する。AIを利用した設計手法など、SFRの実用化に向けた設計や研究開発についても述べる。

論文

Systematic changes of the electronic structure of the diluted ferromagnetic oxide Li-doped Ni$$_{1-x}$$Fe$$_x$$O with hole doping

小林 正起*; Hwang, J. I.*; Song, G.*; 大木 康弘*; 滝沢 優*; 藤森 淳; 竹田 幸治; 藤森 伸一; 寺井 恒太*; 岡根 哲夫; et al.

Physical Review B, 78(15), p.155322_1 - 155322_4, 2008/10

 被引用回数:5 パーセンタイル:26.23(Materials Science, Multidisciplinary)

The electronic structure of Li-doped Ni$$_{1-x}$$Fe$$_x$$O has been investigated using photoemission spectroscopy (PES) and X-ray absorption spectroscopy (XAS). The Ni $$2p$$ core-level PES and XAS spectra were not changed by Li doping. In contrast, the Fe$$^{3+}$$ intensity increased with Li doping relative to the Fe$$^{2+}$$ intensity. However, the increase of Fe$$^{3+}$$ is only $$sim 5%$$ of the doped Li content, suggesting that most of the doped holes enter the O $$2p$$ and/or the charge-transferred configuration Ni $$3d^8underline{L}$$. The Fe $$3d$$ partial density of states and the host valence-band emission near valence-band maximum increased with Li content, consistent with the increase of electrical conductivity. Based on these findings, percolation of bound magnetic polarons is proposed as an origin of the ferromagnetic behavior.

論文

Photoemission and X-ray absorption studies of valence states in (Ni,Zn,Fe,Ti)$$_3$$O$$_4$$ thin films exhibiting photoinduced magnetization

小林 正起*; 大木 康弘*; 滝沢 優*; Song, G. S.*; 藤森 淳; 竹田 幸治; 寺井 恒太*; 岡根 哲夫; 藤森 伸一; 斎藤 祐児; et al.

Applied Physics Letters, 92(8), p.082502_1 - 082502_3, 2008/02

 被引用回数:12 パーセンタイル:44.62(Physics, Applied)

By means of photoemission and X-ray absorption spectroscopy, we have studied the electronic structure of (Ni,Zn,Fe,Ti)$$_{3}$$O$$_{4}$$ thin films, which exhibits a cluster glass behavior with a spin-freezing temperature $$T_f$$ of $$sim 230$$ K and photo-induced magnetization (PIM) below $$T_f$$. The Ni and Zn ions were found to be in the divalent states. Most of the Fe and Ti ions in the thin films were trivalent (Fe$$^{3+}$$) and tetravalent (Ti$$^{4+}$$), respectively. While Ti doping did not affect the valence states of the Ni and Zn ions, a small amount of Fe$$^{2+}$$ ions increased with Ti concentration, consistent with the proposed charge-transfer mechanism of PIM.

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