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論文

Magnetic and transport properties of the pseudobrookite Al$$_{1-x}$$Ti$$_{2+x}$$O$$_{5}$$ single crystals

高濱 隆成*; 有薗 実駿*; 犬童 代梧*; 吉永 汰正*; 寺倉 千恵子*; 竹下 直*; 白崎 巧*; 野田 正亮*; 桑原 英樹*; 梶本 亮一; et al.

JPS Conference Proceedings (Internet), 38, p.011114_1 - 011114_6, 2023/05

We investigated the transport and magnetic properties of single crystals of the pseudobrookite Al$$_{1-x}$$Ti$$_{2+x}$$O$$_{5}$$ for $$0 le x le 1$$ grown using a floating zone. We found a correlation of spin-singlet Ti$$^{3+}$$-Ti$$^{3+}$$ dimers even in the conductive $$alpha$$ and $$lambda$$ phases which develops with increasing $$x$$. The development of the dimer correlation suppresses the magnetic susceptibility at the low temperature and enhances the electric conductivity perhaps due to the suppression of the magnetic scattering at the isolated Ti$$^{3+}$$ ions. The compound shows the best conductivity in the $$lambda$$ phase near the phase boundary between the $$lambda$$ and $$beta$$ phases where the dimer correlation is much developed. Some exotic conductive state may be realized under the background of fluctuation of the spin-singlet dimer in the $$lambda$$ phase near the phase boudary.

論文

Structural, magnetic, transport, and thermoelectric properties of the pseudobrookite AlTi$$_{2}$$O$$_{5}$$-Ti$$_{3}$$O$$_{5}$$ system

高濱 隆成*; 石井 透依*; 犬童 代梧*; 有薗 実駿*; 寺倉 千恵子*; 十倉 好紀*; 竹下 直*; 野田 正亮*; 桑原 英樹*; 斎木 琢夫*; et al.

Physical Review Materials (Internet), 4(7), p.074401_1 - 074401_11, 2020/07

 被引用回数:6 パーセンタイル:40.97(Materials Science, Multidisciplinary)

We investigated the structural, magnetic, transport, and high-temperature thermoelectric properties of single crystals of the pseudobrookite Al$$_{1-x}$$Ti$$_{2+x}$$O$$_{5}$$ for $$0 le x le 1$$ grown using a floating zone. We found a correlation of spin-singlet Ti$$^{3+}$$-Ti$$^{3+}$$ dimers coupled with the lattice even in the conductive $$alpha$$ and $$lambda$$ phases which develops with increasing $$x$$. This developing dimer correlation reduces the number of unpaired Ti$$^{3+}$$ ions, which makes the compound more conductive owing to the suppression of disorder for $$x$$ up to about 0.75. The dimer fluctuation causes a critical enhancement of the magnetic susceptibility at around 150 K in the $$lambda$$ phase near the boundary ($$x sim 0.9$$) between the $$lambda$$ and the $$beta$$ phases. Such a correlation of the spin-singlet Ti$$^{3+}$$-Ti$$^{3+}$$ dimers may produce a high Seebeck coefficient in the conductive $$alpha$$ and $$lambda$$ phases leading to a large thermoelectric power factor at high temperatures.

論文

Schottky specific heat of the lightly Mn-substituted electron-doped SrTiO$$_3$$

奥田 哲治*; 梶本 亮一; 野田 正亮*; 桑原 英樹*

AIP Advances (Internet), 8(10), p.101339_1 - 101339_5, 2018/10

 被引用回数:1 パーセンタイル:4.48(Nanoscience & Nanotechnology)

Large changes in the low-temperature specific heat (low-$$TC$$) by applying magnetic fields up to 9 Tesla were found in the lightly Mn-substituted electron-doped perovskites Sr$$_{1-x}$$La$$_{x}$$TiO$$_{3}$$. The changes in the low-$$TC$$ are qualitatively well explained by the Schottky specific heat ($$C_mathrm{Sch}$$) of localized spins of the Mn 3d electrons in weak internal magnetic fields via itinerant electrons. According to the analysis by using the conventional model, the doped Mn ions are apparently not Mn$$^{4+}$$ ($$S$$ = 3/2) ions, but are Jahn-Teller active Mn$$^{3+}$$ ($$S$$ = 2) ions or mixtures of Mn$$^{3+}$$ and Mn$$^{2+}$$ ions. However, the actual numbers of localized spins estimated from $$C_mathrm{Sch}$$ are about 30% smaller than the expected values. Part of the localized spins of the Mn 3d electrons may disappear due to Kondo coupling with the itinerant electrons, leading to the observed enhancement of the electronic specific heat coefficients.

論文

Elastic and dynamical structural properties of La and Mn-doped SrTiO$$_{3}$$ studied by neutron scattering and their relation with thermal conductivities

梶本 亮一; 中村 充孝; 村井 直樹; 社本 真一; 本田 孝志*; 池田 一貴*; 大友 季哉*; 畑 博人*; 江藤 貴弘*; 野田 正亮*; et al.

Scientific Reports (Internet), 8(1), p.9651_1 - 9651_8, 2018/06

 被引用回数:6 パーセンタイル:30.6(Multidisciplinary Sciences)

The electron-doped SrTiO$$_{3}$$ exhibits good thermoelectric properties, which makes this material a promising candidate of an n-type oxide thermoelectric device. Recent studies indicated that only a few percent co-doping of La and Mn in SrTiO$$_{3}$$ substantially reduces the thermal conductivity, thereby greatly improving the thermoelectric figure of merit at room temperature. Our time-of-flight neutron scattering studies revealed that by doping both La and Mn into SrTiO$$_{3}$$, the inelastic scattering spectrum shows a momentum-independent increase in the low-energy spectral weight approximately below 10 meV. The increase in the low-energy spectral weight exhibits a clear correlation with thermal conductivity. The correlation is attributed to dynamical and local structural fluctuations caused by the Jahn-Teller instability in Mn$$^{3+}$$ ions coupled with the incipient ferroelectric nature of SrTiO$$_{3}$$, as the origin of the low thermal conductivity.

論文

Effects of Mn substitution on the thermoelectric properties and thermal excitations of the electron-doped perovskite Sr$$_{1-x}$$La$$_{x}$$TiO$$_{3}$$

奥田 哲治*; 畑 博人*; 江藤 貴弘*; 草原 彰吾*; 小田 涼佑*; 梶 創揮*; 仁科 康佑*; 桑原 英樹*; 中村 充孝; 梶本 亮一

Journal of the Physical Society of Japan, 85(9), p.094717_1 - 094717_6, 2016/09

 被引用回数:5 パーセンタイル:40.27(Physics, Multidisciplinary)

We studied how Mn substitution affects the thermoelectric properties and thermal excitations of the electron-doped perovskite Sr$$_{1-x}$$La$$_{x}$$TiO$$_{3}$$ by measuring its electrical and thermal transport properties, magnetization, specific heat, and inelastic neutron scattering. Slight Mn substitution with the lattice defects enhanced the Seebeck coefficient, perhaps because of coupling between itinerant electrons and localized spins or between itinerant electrons and local lattice distortion around Mn$$^{3+}$$ ions, while it enhanced anharmonic lattice vibrations, which effectively suppressed thermal conductivity in a state of high electrical conductivity. Consequently, slight Mn substitution increased the dimensionless thermoelectric figure of merit for Sr$$_{1-x}$$La$$_{x}$$TiO$$_{3}$$ near room temperature.

論文

Science from the initial operation of HRC

伊藤 晋一*; 横尾 哲也*; 益田 隆嗣*; 吉澤 英樹*; 左右田 稔*; 池田 陽一*; 井深 壮史*; 川名 大地*; 佐藤 卓*; 南部 雄亮*; et al.

JPS Conference Proceedings (Internet), 8, p.034001_1 - 034001_6, 2015/09

Since the installation of the High Resolution Chopper Spectrometer, HRC, experiments using the HRC are being conducted to observe the dynamics in wide range of physics. Scientific results during the period since the initial construction are summarized.

論文

Effects of Mn substitution on the thermoelectric properties of the electron-doped perovskite Sr$$_{1-x}$$La$$_{x}$$TiO$$_{3}$$

奥田 哲治*; 畑 博人*; 江藤 貴弘*; 仁科 康佑*; 桑原 英樹*; 中村 充孝; 梶本 亮一

Journal of Physics; Conference Series, 568(Part 2), p.022035_1 - 022035_5, 2014/12

 被引用回数:7 パーセンタイル:91.37

We have tried to improve the n-type thermoelectric properties of the electron-doped Perovskite Sr$$_{1-x}$$La$$_{x}$$TiO$$_{3}$$ by a Mn substitution. The 1-2% Mn substitution enhances the Seebeck coefficient ($$S$$) and reduces the thermal conductivity ($$kappa$$) by about 50% at room temperature (RT) without largely increasing the resistivity for the 5% electron-doped SrTiO$$_{3}$$. Consequently, the power factor at RT keeps a large value comparable to that of Bi$$_{2}$$Te$$_{3}$$ and the dimensionless figure-of-merits at RT increases twofold by the slight Mn substitution. Such a large reduction of $$kappa$$ at RT is perhaps due to the effect of Jahn-Teller active Mn$$^{3+}$$ ions, around which dynamical local lattice distortion may occur.

論文

Recent progress in the energy recovery linac project in Japan

坂中 章悟*; 明本 光生*; 青戸 智浩*; 荒川 大*; 浅岡 聖二*; 榎本 収志*; 福田 茂樹*; 古川 和朗*; 古屋 貴章*; 芳賀 開一*; et al.

Proceedings of 1st International Particle Accelerator Conference (IPAC '10) (Internet), p.2338 - 2340, 2010/05

日本においてERL型放射光源を共同研究チームで提案している。電子銃,超伝導加速空洞などの要素技術開発を進めている。また、ERL技術の実証のためのコンパクトERLの建設も進めている。これら日本におけるERL技術開発の現状について報告する。

論文

Ferroelectric polarization and magnetic structure in Eu$$_{0.595}$$Y$$_{0.405}$$MnO$$_{3}$$

梶本 亮一; 横尾 哲也*; 古府 麻衣子*; 野田 耕平*; 桑原 英樹*

Journal of Physics and Chemistry of Solids, 68(11), p.2087 - 2090, 2007/11

 被引用回数:4 パーセンタイル:22.75(Chemistry, Multidisciplinary)

Eu$$_{0.595}$$Y$$_{0.405}$$MnO$$_3$$$$T_mathrm{N}=47$$K以下の温度で反強磁性転移を示す。$$T_mathrm{C}^c=25$$K以下で$$c$$軸方向に自発分極($$P$$)が生じるが、$$P$$の向きは$$T_mathrm{C}^a=23$$K以下で$$a$$軸方向へ変化する。$$P$$と磁気構造の関係を調べるために、Eu$$_{0.595}$$Y$$_{0.405}$$MnO$$_3$$の単結晶試料に対して中性子回折実験を行った。中性子回折実験は高エネルギー加速器研究機構(KEK)のパルス中性子研究施設KENSに設置されている熱外中性子回折計EXCEDで行った。非整合波数ベクトル$$(0, 0.31, 1)$$を持つ磁気ブラッグ反射を観測した。散乱ベクトル$$mathbf{Q}$$がほぼ$$b$$軸に平行な磁気ブラッグピークと、ほぼ$$c$$軸に平行なものの強度を比較することで、$$P$$が出現する温度、及びその向きが変わる温度にて磁気構造が変化していることが確認できた。磁気散乱強度の変化は誘電特性の変化に応じてスパイラル磁気構造が形成され、また、その容易面が変化しているとして解釈でき、最近の理論とも整合する。

論文

Spin wave and orbital ordering in the C-type antiferromagnetic phase of Nd$$_{1-x}$$Sr$$_{x}$$MnO$$_{3}$$

梶本 亮一; 吉澤 英樹*; 川崎 隆一*; 野田 耕平*; 桑原 英樹*

Journal of the Physical Society of Japan, 74(1), p.502 - 503, 2005/01

 被引用回数:2 パーセンタイル:19.79(Physics, Multidisciplinary)

Nd$$_{0.25}$$Sr$$_{0.75}$$MnO$$_{3}$$におけるC型反強磁性スピン波の分散関係を中性子散乱実験によって決定した。スピン交換相互作用は大きな異方性を示し、d$$_{3z^2-r^2}$$軌道が$$c$$軸方向に整列した軌道秩序状態が形成されているためと解釈できる。$$c$$軸方向の交換相互作用はかなり大きく、強磁性金属相での値と同程度である。このことは軌道秩序方向に沿って有限の電荷のホッピングが存在することを示唆する。

口頭

Eu$$_{0.595}$$Y$$_{0.405}$$MnO$$_{3}$$の電気分極と磁気構造

梶本 亮一; 横尾 哲也*; 古府 麻衣子*; 野田 耕平*; 桑原 英樹*

no journal, , 

Eu$$_{0.595}$$Y$$_{0.405}$$MnO$$_{3}$$$$T_N=47$$K以下で反強磁性転移を示す。$$T_C^c=25$$K以下で$$c$$軸に平行な自発電気分極が生じるが、その向きは$$T_C^a=23$$K以下で$$a$$軸方向へと変化する。強誘電性を示す$$R$$MnO$$_{3}$$の多くは長周期磁気秩序相がらせん秩序となるときに自発電気分極$$P$$が出現している。Eu$$_{0.595}$$Y$$_{0.405}$$MnO$$_{3}$$における電気分極の変化と磁気構造の関係を調べるためにEu$$_{0.595}$$Y$$_{0.405}$$MnO$$_{3}$$の単結晶試料に対してパルス中性子回折実験を行った。散乱ベクトル$$mathbf{Q}$$の向きが大きく異なる2つの磁気反射$$(0,q_s,1)$$$$(0,2-q_s,1)$$($$q_ssim0.3b$$)の強度の温度変化を測定したところ、両者は$$T_C^c$$$$T_C^a$$を境に異なる変化を示し、$$P$$の向きの変化に対応してスピンの向きが変化していることがわかった。その温度変化は、スピン秩序が$$T_C^a$$$$<$$T$$<$$$$T_C^c$$($$P parallel c$$)では$$bc$$面内でらせんを描き、T$$<$$$$T_C^a$$($$P parallel c$$)では$$ab$$面内でらせんを描いている、と考えることで説明できる。

口頭

Eu$$_{0.595}$$Y$$_{0.405}$$MnO$$_{3}$$の電気分極と磁気構造

梶本 亮一; 横尾 哲也*; 古府 麻衣子*; 野田 耕平*; 桑原 英樹*

no journal, , 

$$R$$MnO$$_{3}$$は長周期磁気秩序相で強誘電性を示すことで最近注目されているが、その多くでは自発電気分極$$P$$は長周期磁気秩序がらせん秩序となる時に出現している。Eu$$_{0.595}$$Y$$_{0.405}$$MnO$$_{3}$$$$T_N=47$$K以下で反強磁性転移を示す。$$T^c_C=25$$K以下で$$c$$軸に平行な自発電気分極が生じるが、その向きは$$T^a_C=23$$K以下で$$a$$軸方向へと変化する。この電気分極の変化と磁気構造の関係を実験的に調べるためにEu$$_{0.595}$$Y$$_{0.405}$$MnO$$_{3}$$の単結晶試料に対して中性子回折実験を行った。磁気反射は$$mathbf{Q}=(h, k pm q, l)$$, $$q sim 0.3$$の位置に観測された。散乱ベクトル$$mathbf{Q}$$$$c$$軸にほぼ平行な$$(0, q, 1)$$$$b$$軸にほぼ平行な$$(0, 2-q, 1)$$の2つの磁気反射強度の温度変化の比較から磁気構造の変化を考察した。両者ともに$$T^c_C$$, $$T^a_C$$で変化が見られ、$$P$$の向きの変化に対応してスピンの向きが変化していることがわかった。らせん秩序及びサイン波秩序を仮定したモデルを元に2つの磁気反射強度を解析し、$$P$$の向きとの関係について考察した。

口頭

Elastic and dynamical structural properties of La and Mn-doped SrTiO$$_{3}$$ studied by neutron scattering and their relation with thermal conductivities

梶本 亮一; 中村 充孝; 村井 直樹; 社本 真一; 本田 孝志*; 池田 一貴*; 大友 季哉*; 畑 博人*; 江藤 貴弘*; 野田 正亮*; et al.

no journal, , 

The electron-doped SrTiO$$_{3}$$ exhibits good thermoelectric properties. Recent studies indicated that only a few percent co-doping of La and Mn in SrTiO$$_{3}$$ substantially reduces the thermal conductivity. Then, we investigated the static as well as dynamical structural properties of La and Mn-doped SrTiO$$_{3}$$ by time-of-flight elastic and inelastic neutron scattering. We found that the La-Mn co-doped samples show tetragonal structures similar to the low-temperature structure of SrTiO$$_{3}$$, while the La-doped and Mn-doped samples maintain cubic structures with the same symmetry as the high-temperature structure of SrTiO$$_{3}$$. However, it is unlikely that it is the origin of the low thermal conductivity, since the structural transition in SrTiO$$_{3}$$ does not significantly change the thermal conductivity. On the other hand, we found that the inelastic scattering spectrum shows a momentum-independent increase in the low-energy spectral weight by the co-doping. Interestingly, the increase in the low-energy spectral weight exhibits a clear correlation with thermal conductivity. The substitution of Sr$$^{2+}$$ ions by La$$^{3+}$$ ions results in the electron doping, and further doping of the Mn ions are expected to create Jahn-Teller active Mn$$^{3+}$$ ions. We consider that dynamical and local structural fluctuations caused by the Jahn-Teller instability in Mn$$^{3+}$$ ions coupled with the incipient ferroelectric nature of SrTiO$$_{3}$$ induce additional low-energy scatterings and correspond to the origin of low thermal conductivity in the La and Mn co-doped compounds.

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