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吉田 亨次*; 真田 雄介*; 山口 敏男*; 松浦 直人*; 玉造 博夢; 内山 裕士*
Journal of Molecular Liquids, 366, p.120218_1 - 120218_9, 2022/11
被引用回数:1 パーセンタイル:16.81(Chemistry, Physical)The translational, rotational, and phonon dynamics of water in zirconium oxide (ZrO) nanofluid were investigated by quasi-elastic neutron scattering, O NMR relaxation, and inelastic X-ray scattering, respectively. The particle size of ZrO is 3 100 nm, and the concentration of ZrO nanoparticles is 5, 10, 20, and 30 wt%. The translational and rotational motions of water molecules become retarded with increasing the concentration of ZrO. This indicates that there is an attractive interaction between water molecules and the surface of the nanoparticles. The high-frequency sound velocity of the nanofluid obtained from phonon dynamics measurements is slightly larger than that of pure water although it is not much difference compared to the case of the translation and rotation. These findings indicate that water dynamics in the nanofluid is different from that of the bulk. It might be reasons for the enhancement of the thermal conductivity of the nanofluid.
吉田 亨次*; 禪院 知寛*; Fujiyoshi, Ayako*; 真田 雄介*; 山口 敏男*; Murata, Kunihiko*; 高田 慎一; 廣井 孝介; 竹清 貴浩*; 吉村 幸浩*
Journal of Molecular Liquids, 293, p.111477_1 - 111477_9, 2019/11
被引用回数:8 パーセンタイル:39.14(Chemistry, Physical)Differential scanning calorimetry (DSC), small-angle X-ray scattering (SAXS), small-angle neutron scattering (SANS) measurements, and scanning and transmission electron microscope (SEM and TEM) of -lactoglobulin (-LG) are performed in alkyl (methyl, ethyl, and propyl) ammonium nitrate ionic liquids (RAN-ILs)-water mixtures at 25-100C. The addition of these RANs decreased the thermal denaturation temperature of -LG, and the effect is larger with an increase of the hydrophobic part of the cation of the ILs. In ethyl ammonium nitrate (EAN) and propyl ammonium nitrate (PAN) mixtures, the fractal aggregate structure of -LG was found after the thermal denaturation occurred. These results are similar to those of alcohol-water mixtures. The nanoheterogeneous structure of the RAN-water mixture which consists of the hydrophobic and hydrophilic parts might affect the aggregation structure of -LG.