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論文

Effects of mesopore internal surfaces on the structure of immobilized Pd-bisphosphine complexes analyzed by variable-temperature XAFS and their catalytic performances

本倉 健*; 福田 拓磨*; 上村 洋平*; 松村 大樹; 池田 まりか*; 南保 雅之*; Chun, W.-J.*

Catalysts, 8(3), p.106_1 - 106_8, 2018/03

 被引用回数:4 パーセンタイル:10.16(Chemistry, Physical)

In this study, mesoporous and nonporous silica-supported Pd complexes were synthesized and characterized. Variable-temperature XAFS measurements and a curve-fitting analysis showed a slightly larger contribution of $$sigma^{2}_{rm static}$$ when the Pd complexes were on a nonporous support in comparison to a mesoporous support. In contrast, the catalytic performance of the attached Pd complex in the Suzuki-Miyaura cross-coupling reaction was not affected by such small differences in the static disorder of the Pd complex.

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