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玉造 博夢; 長谷川 巧*; 佐賀山 基*; 水牧 仁一朗*; 村上 洋一*; 梶谷 丈*; 東中 隆二*; 松田 達磨*; 青木 勇二*; 筒井 智嗣*
Physical Review B, 107(2), p.024303_1 - 024303_8, 2023/01
被引用回数:0 パーセンタイル:0(Materials Science, Multidisciplinary)The phonon dispersion of a BiS-based superconductor LaBiSOF is investigated by first-principles calculations and inelastic X-ray scattering experiments. The origin of superlattice (SL) reflections arising from transverse-type lattice modulation, which were recently reported in [J. Kajitani ., J. Phys. Soc. Jpn. , 103601 (2021)], is discussed in terms of lattice dynamics. Our first-principles calculations of phonon dispersion and the Fermi surfaces (FSs) demonstrate that the phonon mode corresponding to the transverse-type lattice modulation is unstable, and the propagation vector corresponding to the SL reflections is close to the FS nesting vector, which suggests that the phonon softening originates from the FS nesting. Against these calculated expectations, measured phonon dispersion in LaBiSOF along the Z-A direction, where the SL point is located, shows no remarkable temperature dependence, and there are no steeply declining branches accompanied with a softening around the SL point. Based on these results, we discuss the two possibilities for the transverse lattice modulation in LaBiSOF: the order-disorder type structural transition and the displacive structural transition with an overdamped mode, for both of which the local structure distortion or the short range correlation within the BiS plane would be essential.
Gruner, T.*; Lucas, S.*; Geibel, C.*; 金子 耕士; 筒井 智嗣*; Schmalzl, K.*; Stockert, O.*
Physical Review B, 106(11), p.115142_1 - 115142_6, 2022/09
被引用回数:1 パーセンタイル:18.86(Materials Science, Multidisciplinary)The disappearance of a charge-density-wave (CDW) transition in Lu(PtPd)In is thought to be closely linked to a maximum of the superconducting transition temperature in the system. We studied the superstructure and the phonon softening in Lu(PtPd)In by means of neutron and high-resolution inelastic X-ray scattering. A full phonon softening at = (0.5, 0.5, 0) with the appearance of superstructure peaks could be clearly identified. The large tail of the superstructure intensity above the CDW transition indicates the importance of critical fluctuations.
筒井 智嗣; 東中 隆二*; 中村 頼人*; 藤原 孝将*; 中村 仁*; 小林 義男*; 伊藤 孝; 依田 芳卓*; 加藤 和男*; 新田 清文*; et al.
Hyperfine Interactions, 242(1), p.32_1 - 32_10, 2021/12
被引用回数:1 パーセンタイル:84.42Sm synchrotron-radiation-based Mssbauer spectroscopy was performed in Sm-based intermetallics having a cubic crystal structure, SmGe, SmB, SmBe, and SmAl ( = transition metals). In spite of the difference of the local structure around the Sm sites, the observed Mssbauer spectra consist of a single line at 300 K. On the other hand, Sm L-edge X-ray absorption spectra consist of two components, suggesting Sm and Sm states. Difference of the number of the spectral components between the Mssbauer spectroscopy and X-ray absorption spectroscopy is caused by the difference of the time window in the scattering process of these measurements. Correlation between the isomer shifts in the Mssbauer spectroscopy and average Sm valence states estimated from the X-ray absorption spectroscopy exhibits a linear correlation.
Doleal, P.*; Cejpek, P.*; 筒井 智嗣*; 金子 耕士; Legut, D.*; Carva, K.*; Javorsk, P.*
Scientific Reports (Internet), 11(1), p.20878_1 - 20878_10, 2021/10
被引用回数:0 パーセンタイル:0(Multidisciplinary Sciences)The interaction between phonons and 4f electrons, which is forming a new quantum state (quasi-bound state) beyond Born-Oppenheimer approximation, is very prominent and lattice dynamics plays here a key role. There is only a small number of compounds in which the experimental observation suggest such a scenario. One of these compounds is CePdAl. The inelastic X-ray scattering technique was used for mapping the phonon modes at X and Z points as well as in L and D directions, where the symmetry analysis of phonon modes was performed. The measured spectra are compared with the theoretical calculation, showing very good agreement. The results are discussed with respect to the magneto-elastic interaction. The phonon mode symmetry A1g was found to be unaffected by the interaction, which is in contrast to previous assumptions.
金子 耕士; Cheung, Y. W.*; Hu, Y.*; 今井 正樹*; 谷奥 泰明*; 金川 響*; 村川 譲一*; 森山 広大*; Zhang, W.*; Lai, K. T.*; et al.
JPS Conference Proceedings (Internet), 30, p.011032_1 - 011032_6, 2020/03
A quantum critical point appears as a second-order phase transition which takes place at zero temperature. In contrast to heavy-fermion systems in which magnetism often plays a vital role, recent studies revealed that structural instabilities can drive a system to a quantum critical point as well. In quasi-skutterudite (Ca,Sr)Sn (=Rh, Ir), SrIrSn exhibits superconductivity around 5 K and a structural transition at 147 K. Applying physical or chemical pressure on SrIrSn suppresses rapidly, and a quasi-linear dependence of electrical resistivity, signature of non-Fermi liquid behavior, was observed where extrapolates to 0 K. The isomorphs (CaSr)RhSn exhibits similar behavior, where the criticality can be reached by 0.9 without external pressure. Neutron scattering experiments in SrIrSn evidences the second order nature of the structural transition at by the observation of a continuous evolution of superlattice peak below and a gradual increase of critical scattering upon approaching to by cooling. Increase of in (CaSr)RhSn toward the quantum critical point leads to the systematic variation of the critical exponents of the order parameter. In addition, this substitution induces the phonon softening around the M point towards zero energy revealed by inelastic X-ray scattering experiment. We will present systematic variations in both elastic and inelastic channels upon approaching to the quantum critical point.
Cheung, Y. W.*; Hu, Y. J.*; 今井 正樹*; 谷奥 泰明*; 金川 響*; 村川 譲一*; 森山 広大*; Zhang, W.*; Lai, K. T.*; 吉村 一良*; et al.
Physical Review B, 98(16), p.161103_1 - 161103_5, 2018/10
被引用回数:19 パーセンタイル:67.65(Materials Science, Multidisciplinary)Approaching a quantum critical point has been an effective route to stabilize superconductivity. While the role of magnetic QCPs has been extensively discussed, similar exploration of a structural QCP is scarce. Using inelastic X-ray scattering, we examine the phonon spectrum of the nonmagnetic quasi-skutterudite (CaSr)RhSn, which represents a precious system to explore the interplay between structural instabilities and superconductivity by tuning the Ca concentration x. We unambiguously detect the softening of phonon modes around the M point on cooling towards the structural transition. Intriguingly, at x = 0:85, the soft mode energy squared at the M point extrapolates to zero at -5.7 K, providing the first compelling microscopic evidence of a structural QCP in (CaSr)RhSn. The enhanced phonon density-of-states at low energy provides the essential ingredient for realizing strong-coupling superconductivity near the structural QCP.
大和田 謙二*; 塚田 慎也*; 福田 竜生; 筒井 智嗣*; Baron, A. Q. R.*; 水木 純一郎*; 大和 英弘*; 安田 直彦*; 寺内 暉*
Physical Review B, 98(5), p.054106_1 - 054106_10, 2018/08
被引用回数:3 パーセンタイル:15.79(Materials Science, Multidisciplinary)The effect of -site randomness on the antiferroelectric/relaxor nature of the ground state was investigated by studying diffuse and inelastic X-ray scattering from ordered and disordered Pb(InNb)O (O- and D-PIN) single crystals. The diffuse scattering measurement of O-PIN (antiferroelectric at ) shows the existence of ferroelectrically interactive local polarization above . Inelastic X-ray scattering shows that the transverse-acoustic (TA) and transverse-optic (TO) modes are dominant at 800 K, while the central peak (CP) and TA modes are coupled and majorly contribute to the critical behavior of the diffuse scattering at . Upon these results, the -site randomness is discussed in terms of suppressing the antiferroelectric instability and enhancing the polarization fluctuation.
筒井 智嗣*; 金子 耕士; Pospisil, J.; 芳賀 芳範
Physica B; Condensed Matter, 536, p.24 - 27, 2018/05
被引用回数:3 パーセンタイル:15.79(Physics, Condensed Matter)Inelastic X-ray scattering (IXS) experiments of RTAl ( = La Ce, = Cu, Au) were carried out at 300 and 5.5 K. The spectra between LaCuAl and CeCuAl (LaAuAl and CeAuAl) are nearly identical at both temperatures except for temperature factors such as temperature dependence of Bose factor in IXS spectra and effect on thermal expansion. This means that no evident temperature dependence of IXS spectra was observed in CeTAl ( = Cu, Au).
Cheung, Y. W.*; Hu, Y. J.*; Goh, S. K.*; 金子 耕士; 筒井 智嗣; Logg, P. W.*; Grosche, F. M.*; 金川 響*; 谷奥 泰明*; 今井 正樹*; et al.
Journal of Physics; Conference Series, 807(3), p.032002_1 - 032002_4, 2017/04
被引用回数:5 パーセンタイル:83.85(CaSr)RhSn is a member of the substitution series (CaSr)RhSn which has recently been argued to feature a structural quantum critical point at = 0.9. In the stoichiometric compound SrRhSn, the structural transition at 138 K has been shown to be a second-order phase transition. Moving towards xc, we examine the character of the structural transition in (CaSr)RhSn (i.e. = 0.5, 55 K) using electrical resistivity, heat capacity and X-ray scattering. The absence of the thermal hysteresis in specific heat around , and the continuous evolution of the superlattice reflection detected by X-ray diffraction are consistent with the scenario that the structural transition associated with a modulation vector = (0.5, 0.5, 0) in (CaSr)RhSn remains second-order on approaching the quantum critical point.
細川 伸也*; 木村 耕治*; 山崎 倫昭*; 河村 能人*; 吉田 亨次*; 乾 雅祝*; 筒井 智嗣*; Baron, A. Q. R.*; 川北 至信; 伊藤 晋一*
Journal of Alloys and Compounds, 695, p.426 - 432, 2017/02
被引用回数:3 パーセンタイル:16.87(Chemistry, Physical)Inelastic X-ray scattering (IXS) was performed on polycrystalline MgZnY and MgZnY alloys with synchronized long-period stacking ordered (LPSO) phase for investigating the impurity effects in the microscopic elastic properties. Inelastic neutron scattering (INS) was also carried out on the former alloy. LA modes were clearly observed in the IXS spectra of both the LPSO alloys, while TA modes can mainly be detected in the second Brillouin zone. Broader inelastic signals and larger quasielastic peaks are characteristic due to the phonon scattering by the Zn/Y impurities. Only the TA excitation energies increase by adding the impurities, which indicates a harder stiffness of the bond angles relating to the L1-type clusters in the LPSO alloys. New dispersion-less excitation modes are observed at about 10 meV by adding the Zn/Y impurities. By comparing with the INS data, the contributions of the impurities to these excitations are discussed using differences in the scattering cross-sections between neutrons and X-rays.
村井 直樹*; 福田 竜生; 小林 達也*; 中島 正道*; 内山 裕士*; 石川 大介*; 筒井 智嗣*; 中村 博樹; 町田 昌彦; 宮坂 茂樹*; et al.
Physical Review B, 93(2), p.020301_1 - 020301_5, 2016/01
被引用回数:7 パーセンタイル:34.33(Materials Science, Multidisciplinary)Phonon spectra of detwinned SrFeAs crystals, as measured by inelastic X-ray scattering, show clear anisotropyaccompanying the magnetostructural transition at 200 K. We model the mode splitting using magnetic DFT calculations, including a phenomenological reduction in force-constant anisotropy that can be attributed to magnetic fluctuations. This serves as a starting point for a general model of phonons in this material applicable to both the antiferromagnetically ordered phase and the paramagnetic phase. Using this model, the measured splitting in the magnetic phase below T, and the measured phonon linewidth, we set a lower bound on the mean magnetic fluctuation frequency above T at 210 K.
筒井 智嗣
Mssbauer Effect Reference and Data Journal, 38(4), p.105 - 111, 2015/06
アクチノイド化合物のメスバウアー分光は日本でも海外でも実施可能な施設は限られる。日本におけるアクチノイドのメスバウアー分光の研究は1990年代に先端基礎研究センターにおいて開始された。本稿では、1996年に先端基礎研究センターで開始されたU-238メスバウアー分光及び東北大学金属材料研究所で開始されたネプツニウム金属間化合物のメスバウアー分光に関する研究成果について纏めた。また、これらのアクチノイドのメスバウアー分光の研究成果のレビューを行うとともに、その発展に寄与された故那須三郎阪大名誉教授の貢献に関してまとめたものである。
本多 史憲*; 広瀬 雄介*; 三宅 厚志*; 水牧 仁一朗*; 河村 直己*; 筒井 智嗣*; 綿貫 徹; 渡辺 真仁*; 竹内 徹也*; 摂待 力生*; et al.
Journal of Physics; Conference Series, 592(1), p.012021_1 - 012021_5, 2015/03
被引用回数:2 パーセンタイル:61.05重い電子系化合物YbTZn(T: Rh and Ir)について、X線吸収分光法によりYb価数観察を行った。いずれの化合物でもYb価数は温度依存性を示し、約100K以下で冷却とともにYb価数が減少する変化が見られた。これは、同型化合物であるYbCoZnにおいて温度依存性が見られないこととは対照的な結果である。
筒井 智嗣; 金子 耕士; 宮崎 亮一*; 東中 隆二*; 青木 勇二*; 小林 理気*; 脇本 秀一; Baron, A. Q. R.*; 菅原 仁*; 佐藤 英行*
JPS Conference Proceedings (Internet), 3, p.011060_1 - 011060_5, 2014/06
We have investigated the Ru/Os concentration dependence of the Pr guest mode in Pr(OsRu)Sb and its variation with temperature. The Pr guest mode at 3.2 meV in PrOsSb at the N point linearly shifts to a higher energy with the substitution of Ru into the Os site. The energy of the Pr guest mode decreases with decreasing temperature for all compositions, indicating the presence of an anharmonic potential at the Pr site. The slope of the temperature dependence of the guest mode energy is steeper for pure PrOsSb than for the other Pr(OsRu)Sb compounds we measured. The present results imply the importance of the transition metal in determining anharmonicity in Pr(OsRu)Sb.
土居 篤典*; 藤岡 淳*; 福田 竜生; 筒井 智嗣*; 奥山 大輔*; 田口 康二郎*; 有馬 孝尚*; Baron, A. Q. R.*; 十倉 好紀*
Physical Review B, 90(8), p.081109_1 - 081109_4, 2014/01
被引用回数:17 パーセンタイル:58.59(Materials Science, Multidisciplinary)The phonon dynamics of spin-state crossover for perovskite LaCoO was investigated using infrared and inelastic X-ray spectroscopy. We observed that the Co-O bond stretching phonons couples to the thermally excited spin-state. The momentum dispersion of the optical mode is anomalously dispersionless (less than 3 meV), and this supports the spin-state disproportionation scenario. The steep enhancement of spin-state fluctuation compared to the charge gap suggests the density dependent spin state disproportionation; a simple low spin (LS)/high spin (HS)- or LS/intermediate spin (IS)-state disproportionation is realized at the initial stage with dilute HS- (or IS-) state density, while the complex spin-state disproportionation involving all of the LS-, IS- and HS-state is formed when the density of HS- (or IS-) state is enhanced.
中井 裕人*; 海老原 孝雄*; 筒井 智嗣*; 水牧 仁一朗*; 河村 直己*; 道村 真司*; 稲見 俊哉; 中村 俊幸*; 近藤 晃弘*; 金道 浩一*; et al.
Journal of the Physical Society of Japan, 82(12), p.124712_1 - 124712_5, 2013/12
被引用回数:8 パーセンタイル:50.87(Physics, Multidisciplinary)重い電子化合物であるYbRhSiのYb価数の温度磁場依存性をX線吸収分光で観測した。測定からは、何れも突然の変化なしに、Yb価数が2Kから200Kの範囲で温度の下降に伴い減少することと、0Tから33Tの範囲で磁場の増加に伴い増加することが明かになった。Ybの価数は、磁場と温度に依存して、2.92から2.96の範囲であった。価数が2Kでは0Tで2.92で33Tで2.93である点で、YbRhSiは価数揺動状態にあることがわかり、高磁場でも整数価数に届かない。これらの結果はYbの価数が整数価数の3+に非常に近く、降温に伴い減少し、磁場の印加に伴い3+に近づくというこれまでの知識を支持するものである。
筒井 智嗣; 中田 正美
Mssbauer Spectroscopy; Applications in Chemistry, Biology, and Nanotechnology, p.123 - 140, 2013/10
先端基礎研究センターで行われたウラン金属間化合物に関するUメスバウア分光の結果に関してレビューを行った。われわれの研究以前には、U核の第1励起状態の核磁気モーメントの大きさが未知で、内部磁場を用いた磁性に関する定量分析は行うことができなかった。そこで、われわれはU NMRとUメスバウア分光によるUOの内部磁場からU核の第1励起状態の核磁気モーメントを決定した。その後、種々のウラン金属間化合物、特に重い電子的振舞や2次元フェルミ面物質など、強相関電子系に分類される物質群についてのUメスバウア分光を行い、その物性の微 視電子状態について議論を行った。
大和田 謙二; 福田 竜生; 水木 純一郎; 廣田 和馬*; 寺内 暉*; 筒井 智嗣*; Baron, A. Q. R.*; 大和 英弘*; 安田 直彦*
Journal of the Korean Physical Society, 59(3), p.2509 - 2514, 2011/09
被引用回数:2 パーセンタイル:20.2(Physics, Multidisciplinary)Pb(InNb)O(PIN)はペロヴスカイトBサイトの秩序度により反強誘電状態,強誘電状態,リラクサー状態を取りうる物質である。秩序PINは鉛複合ペロヴスカイトPb(B'B'')OにおいてBサイトランダムネスのない系であり、Bサイトランダムネスによる反強誘電状態/リラクサー状態の起源を探るには理想的な物質である。われわれはX線非弾性散乱実験を行った。準弾性散乱(QE)は臨界スローダウンを示し横波音響(TA)フォノンは反強誘電転移点()までソフト化を示す一方、横波光学モードは低温までソフト化を続けた。これらの結果は、反強誘電相転移はQEの起源とTAフォノンによるものであるが、強誘電相関は確固としてその背後に存在していることを示している。これらの結果を元に、Bサイトランダムネスの効果について議論する。
岡根 哲夫; 大河内 拓雄*; 稲見 俊哉; 竹田 幸治; 藤森 伸一; 河村 直己*; 鈴木 基寛*; 筒井 智嗣*; 山上 浩志; 藤森 淳; et al.
Physical Review B, 80(10), p.104419_1 - 104419_7, 2009/09
被引用回数:6 パーセンタイル:29.57(Materials Science, Multidisciplinary)X-ray magnetic circular dichroism (XMCD) experiments were performed at the Np and the Ga absorption edges of NpNiGa to investigate the temperature-dependent changes of magnetic properties of Np 5 and Ga 4 electron states. By the sum-rule analysis of the Np XMCD data, the orbital magnetic moment and the spin magnetic moment were estimated for the Np 5 and 5 electronic configurations, and their comparison with the previous magnetization and neutron scattering experiments suggests that the 5 configuration is more likely than the 5 configuration in NpNiGa. It was found that tends to increase from the high-temperature low-moment ordered state to the low-temperature high-moment ordered state.
梶本 亮一; 佐賀山 基*; 佐々井 健蔵*; 福田 竜生; 筒井 智嗣*; 有馬 孝尚*; 廣田 和馬*; 三井 由佳利*; 吉澤 英樹*; Baron, A. Q. R.*; et al.
Physical Review Letters, 102(24), p.247602_1 - 247602_4, 2009/06
被引用回数:12 パーセンタイル:59.08(Physics, Multidisciplinary)TbMnO exhibits a spontaneous electric polarization along concomitantly with a spiral spin ordering modulated along below = 28 K. We have performed inelastic X-ray scattering measurements on a single crystal of TbMnO to clarify whether phonon anomalies related to the ferroelectricity exist. We measured transverse modes, especially the Mn-O-Mn bending mode polarized along and propagating along , which we expect is most relevant to the ferroelectricity. However, no anomaly was found in the phonon dispersion below 50 meV across . The present result suggests that the mechanism of ferroelectricity in TbMnO is different from that of a conventional displacive-type ferroelectric. The weak coupling between electric polarization and lattice in TbMnO strongly suggests that the ferroelectricity is mainly derived from the spiral spin ordering.