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友田 陽*; Gong, W.*; Harjo, S.; 篠崎 智也*
Scripta Materialia, 133, p.79 - 82, 2017/05
被引用回数:24 パーセンタイル:74.12(Nanoscience & Nanotechnology)The microstructure evolution during reverse transformation of a Cr-Ni-Mo steel consisting of tempered lath martensite and Cr carbide was examined using neutron diffraction at high temperatures. The microstructural change from a reversed coarse-grained structure to a fine-grained polygonal structure by further annealing was monitored through a decrease in the diffraction intensity caused by primary extinction and the full width at half maximum. This result is different from that for a bainite steel, showing good coincidence with the observations using electron back scatter diffraction.
犬飼 宗弘*; 堀毛 悟史*; 板倉 智也*; 篠崎 良太*; 荻原 直希*; 梅山 大樹*; Nagarker, S.*; 西山 裕介*; Malon, M.*; 林 灯*; et al.
Journal of the American Chemical Society, 138(27), p.8505 - 8511, 2016/07
被引用回数:135 パーセンタイル:95.46(Chemistry, Multidisciplinary)We describe encapsulation of mobile proton carriers into defect sites in non-porous coordination polymers. The proton carriers are encapasulated with high mobility and provide high proton conductivity at 150C under anhydrous condition. The high proton conductivity and non-porous nature allow power generation by fuel cell in which CPs are used as electrolyte. To observe defects and mobile proton carriers, we carried out solid-state NMR, XAFS, XRD, and ICP-AES/EA. On the basis of these analyses, we elucidated that the defect sites provide space for mobile uncoordinated HPO, HPO, and HO. These mobile carriers play a key role to expand proton hopping path and promote the mobility of all protons in coordination frameworks, leading to high proton conductivity and fuel cell power generation.
Gong, W.*; Harjo, S.; 柴田 曉伸*; 友田 陽*; 篠崎 智也*; 辻 伸泰*
no journal, ,
Quenching and partitioning (Q&P) process is an effective approach to control the amount and stability of retained austenite. Our previous study confirmed that carbon partitioning and isothermal transformation simultaneously occurred below martensitic transformation starting (Ms) temperature. In order to deepen the understanding on controlling microstructures through Q&P processes, the effect of ausforming on phase transformation and carbon partitioning during the Q&P process were investigated by the use of in-situ neutron diffraction in the present study.