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Zhao, X.*; Zhang, Z.*; Hattori, Takanori; Wang, J.*; Li, L.*; Jia, Y.*; Li, W.*; Xue, J.*; Fan, X.*; Song, R.*; et al.
Nature Communications (Internet), 16, p.7713_1 - 7713_8, 2025/08
Times Cited Count：0 Percentile：0.00Caloric effects usually occur in the vicinity of solid-state phase transitions with a limited refrigeration temperature span. Here, we introduce and realize an unprecedented concept -all temperature barocaloric effect, i.e., a remarkable barocaloric effect in KPF
across an exceptionally wide temperature span, from 77.5 to 300 K and potentially down to 4 K, covering typical room temperature, liquid nitrogen, liquid hydrogen, and liquid helium refrigeration regions. The directly measured barocaloric adiabatic temperature change reaches 12 K at room temperature and 2.5 K at 77.5 K upon the release of a 250 MPa pressure. This effect is attributed to a persistent phase transition to a rhombohedral high pressure phases. We depict the thermodynamic energy landscape to account for the structural instability. This unique all-temperature barocaloric effect presents a novel approach to highly applicable solid-state refrigeration technology, transcending the conventional multi-stage scenario.
Takeuchi, Yutaro*; Sato, Yuma*; Yamane, Yuta*; Yoon, J.-Y.*; Kanno, Yukinori*; Uchimura, Tomohiro*; De Zoysa, K. V.*; Han, J.*; Kanai, Shun*; Ieda, Junichi; et al.
Science, 389(6762), p.830 - 834, 2025/08
Times Cited Count：0 Percentile：0.00
magnetic orderings in a triangular lattice; Implications for multi- orderings in general two-dimensional latticesPark, P.*; Cho, W.*; Kim, C.*; An, Y.*; Iida, Kazuki*; Kajimoto, Ryoichi; Matin, S.*; Zhang, S.-S.*; Batista, C. D.*; Park, J.-G.*
Physical Review X, 15(3), p.031032_1 - 031032_29, 2025/07
Sugita, Yutaka; Ono, Hirokazu; Beese, S.*; Pan, P.*; Kim, M.*; Lee, C.*; Jove-Colon, C.*; Lopez, C. M.*; Liang, S.-Y.*
Geomechanics for Energy and the Environment, 42, p.100668_1 - 100668_21, 2025/06
Times Cited Count：1 Percentile：70.95(Energy & Fuels)The international cooperative project DECOVALEX 2023 focused on the Horonobe EBS experiment in the Task D, which was undertaken to study, using numerical analyses, the thermo-hydro-mechanical (or thermo-hydro) interactions in bentonite based engineered barriers. One full-scale in-situ experiment and four laboratory experiments, largely complementary, were selected for modelling. The Horonobe EBS experiment is a temperature-controlled non-isothermal experiment combined with artificial groundwater injection. The Horonobe EBS experiment consists of the heating and cooling phases. Six research teams performed the THM or TH (depended on research team approach) numerical analyses using a variety of computer codes, formulations and constitutive laws.
hydridosilicate at high pressures; A Bridge to BaSiH
polyhydrideBeyer, D. C.*; Spektor, K.*; Vekilova, O. Y.*; Grins, J.*; Barros Brant Carvalho, P. H.*; Leinbach, L. J.*; Sannemo-Targama, M.*; Bhat, S.*; Baran, V.*; Etter, M.*; et al.
ACS Omega (Internet), 10(15), p.15029 - 15035, 2025/04
Times Cited Count：0 Percentile：0.00(Chemistry, Multidisciplinary)Hydridosilicates featuring SiH octahedral moieties represent a rather new class of compounds with potential properties relating to hydrogen storage and hydride ion conductivity. Here, we report on the new representative BaSiH obtained from reacting the Zintl phase hydride BaSiH
with H
fluid at pressures above 4 GPa and subsequent decompression to ambient pressure. It consists of complex SiH
ions, which are octahedrally coordinated by Ba
counterions. The arrangement of Ba and Si atoms deviates only slightly from an ideal fcc NaCl structure. IR and Raman spectroscopy showed SiH bending and stretching modes in the ranges 800-1200 and 1400-1800 cm
, respectively. BaSiH is thermally stable up to 95
C above which decomposition into BaH and Si takes place. DFT calculations indicated a direct band gap of 2.5 eV. The discovery of BaSiH consolidates the compound class of hydridosilicates, accessible from hydrogenations of silicides at gigapascal pressures (
10 GPa). The structural properties of BaSiH suggest that it presents an intermediate (or precursor) for further hydrogenation at considerably higher pressures to the predicted superconducting polyhydride BaSiH.
Niu, X.*; Elakneswaran, Y.*; Li, A.*; Seralathan, S.*; Kikuchi, Ryosuke*; Hiraki, Yoshihisa; Sato, Junya; Osugi, Takeshi; Walkley, B.*
Cement and Concrete Research, 190, p.107814_1 - 107814_17, 2025/04
Times Cited Count：2 Percentile：82.67(Construction & Building Technology)Brumm, S.*; Gabrielli, F.*; Sanchez Espinoza, V.*; Stakhanova, A.*; Groudev, P.*; Petrova, P.*; Vryashkova, P.*; Ou, P.*; Zhang, W.*; Malkhasyan, A.*; et al.
Annals of Nuclear Energy, 211, p.110962_1 - 110962_16, 2025/02
Times Cited Count：9 Percentile：96.17(Nuclear Science & Technology)Naeem, M.*; Ma, Y.*; Tian, J.*; Kong, H.*; Romero-Resendiz, L.*; Fan, Z.*; Jiang, F.*; Gong, W.; Harjo, S.; Wu, Z.*; et al.
Materials Science & Engineering A, 924, p.147819_1 - 147819_10, 2025/02
Times Cited Count：1 Percentile：67.80(Nanoscience & Nanotechnology)Yoon, J.-Y.*; Takeuchi, Yutaro*; Takechi, Ryota*; Han, J.*; Uchimura, Tomohiro*; Yamane, Yuta*; Kanai, Shun*; Ieda, Junichi; Ohno, Hideo*; Fukami, Shunsuke*
Nature Communications (Internet), 16, p.1171_1 - 1171_8, 2025/02
Times Cited Count：1 Percentile：68.15(Multidisciplinary Sciences)Yang, X.*; Che, G.*; Wang, Y.*; Zhang, P.*; Tang, X.*; Lang, P.*; Gao, D.*; Wang, X.*; Wang, Y.*; Hattori, Takanori; et al.
Nano Letters, 25(3), p.1028 - 1035, 2025/01
Times Cited Count：2 Percentile：85.69(Chemistry, Multidisciplinary)Saturated sp
-carbon nanothreads (CNTh) have garnered significant interest due to their predicted high Young's modulus and thermal conductivity. While the incorporation of heteroatoms into the central ring has been shown to influence the formation of CNTh and yield chemically homogeneous products, the impact of pendant groups on the polymerization process remains underexplored. In this study, we investigate the pressure-induced polymerization of phenol, revealing two phase transitions occurring below 0.5 and 4 GPa. Above 20 GPa, phenol polymerizes into degree-4 CNThs featuring hydroxyl and carbonyl groups. Hydrogen transfer of hydroxyl groups was found to hinder the formation of degree-6 nanothreads. Our findings highlight the crucial role of the hydroxyl group in halting further intracolumn polymerization and offer valuable insights for future mechanism research and nanomaterial synthesis.
systemPan, Y.-W.*; Liu, Z.-W.*; Geng, L.-S.*; Hosaka, Atsushi; Liu, X.*
Physical Review D, 110(9), p.094004_1 - 094004_8, 2024/11
Times Cited Count：2 Percentile：43.32(Astronomy & Astrophysics)no abstracts in English
Zhu, M.*; Romerio, V.*; Steiger, N.*; Nabi, S. D.*; Murai, Naoki; Kawamura, Seiko; Povarov, K. Y.*; Skourski, Y.*; Sibille, R.*; Keller, L.*; et al.
Physical Review Letters, 133(18), p.186704_1 - 186704_6, 2024/11
Times Cited Count：12 Percentile：93.56(Physics, Multidisciplinary)
-
transitionsYang, Q.*; Yang, X.*; Wang, Y.*; Fei, Y.*; Li, F.*; Zheng, H.*; Li, K.*; Han, Y.*; Hattori, Takanori; Zhu, P.*; et al.
Nature Communications (Internet), 15, p.7778_1 - 7778_9, 2024/09
Times Cited Count：16 Percentile：89.90(Multidisciplinary Sciences)Luminescent materials that simultaneously embody bright singlet and triplet excitons hold great potential in optoelectronics, signage, and information encryption. However, achieving high-performance white-light emission is severely hampered by their inherent unbalanced contribution of fluorescence and phosphorescence. Herein, we address this challenge by pressure treatment engineering via hydrogen bonding cooperativity effect to realize the mixture of n-- transitions, where the triplet state emission was boosted from 7% to 40% in isophthalic acid (IPA). A superior white-light emission based on hybrid fluorescence and phosphorescence was harvested in pressure-treated IPA, and the photoluminescence quantum yield was increased to 75% from the initial 19% (blue-light emission). In-situ high-pressure IR spectra, X ray diffraction, and neutron diffraction reveal continuous strengthening of the hydrogen bonds with the increase of pressure. Furthermore, this enhanced hydrogen bond is retained down to the ambient conditions after pressure treatment, awarding the targeted IPA efficient intersystem crossing for balanced singlet/triplet excitons population and resulting in efficient white-light emission. This work not only proposes a route for brightening triplet states in organic small molecule, but also regulates the ratio of singlet and triplet excitons to construct high-performance white-light emission.
RhSiShamoto, Shinichi; Yamauchi, Hiroki; Iida, Kazuki*; Ikeuchi, Kazuhiko*; Kaneko, Koji; Chen, Y.-S.*; Yano, Shinichiro*; Hsu, P.-T.*; Lee, M. K.*; Hall, A. E.*; et al.
Physical Review Research (Internet), 6(3), p.033303_1 - 033303_7, 2024/09
The magnetic excitation extends at least from 0.3 to 140 meV. The integrated inelastic scattering intensity leads to a localized magnetic moment of about 5
per Mn site fluctuating at 200 K in the wide energy range, although the long-range ordered magnetic moment is only 2.61 at 4 K. The result suggests that a large part of the magnetic moment does not order in MnRhSi.
Ying, H.*; Yang, X.*; He, H.*; Yan, A.*; An, K.*; Ke, Y.*; Wu, Z.*; Tang, S.*; Zhang, Z.*; Dong, H.*; et al.
Scripta Materialia, 250, p.116181_1 - 116181_7, 2024/09
Times Cited Count：5 Percentile：72.95(Nanoscience & Nanotechnology)Nguyen, T.-D.*; Singh, C.*; Kim, Y. S.*; Han, J. H.*; Lee, D.-H.*; Lee, K.*; Harjo, S.; Lee, S. Y.*
Journal of Materials Research and Technology, 31, p.1547 - 1556, 2024/07
Times Cited Count：6 Percentile：78.45(Materials Science, Multidisciplinary)Zeng, Z.*; Zhou, C.*; Zhou, H.*; Han, L.*; Chi, R.*; Li, K.*; Kofu, Maiko; Nakajima, Kenji; Wei, Y.*; Zhang, W.*; et al.
Nature Physics, 20(7), p.1097 - 1102, 2024/07
Times Cited Count：20 Percentile：97.27(Physics, Multidisciplinary)Han, J.*; Uchimura, Tomohiro*; Araki, Yasufumi; Yoon, J.-Y.*; Takeuchi, Yutaro*; Yamane, Yuta*; Kanai, Shun*; Ieda, Junichi; Ohno, Hideo*; Fukami, Shunsuke*
Nature Physics, 20(7), p.1110 - 1117, 2024/07
Times Cited Count：26 Percentile：98.27(Physics, Multidisciplinary)Quantum metric and Berry curvature are two fundamental and distinct factors to describe the geometry of quantum eigenstates. While Berry curvature is known for playing crucial roles in several condensed-matter states, quantum metric, which was predicted to induce new classes of topological phenomena, has rarely been touched, particularly in an ambient circumstance. Using a topological chiral antiferromagnet MnSn adjacent to Pt, at room temperature, we successfully manipulate the quantum-metric structure of electronic states through its interplay with the nanoscale spin texture at the MnSn/Pt interface. This is manifested by a time-reversal-odd second-order Hall effect that is robust against extrinsic electron scattering, in contrast to any transport effects from the Berry curvature. We also verify the flexibility of controlling the quantum-metric structure, as the interacting spin texture can be tuned by moderate magnetic fields or by interface engineering via spin-orbit interactions. Our work paves a way for harnessing the quantum-metric structure to unveil emerging topological physics in practical environments and to build applicable nonlinear devices.
Liao, J.*; Huang, Z.*; Shangguan, Y.*; Zhang, B.*; Cheng, S.*; Xu, H.*; Kajimoto, Ryoichi; Kamazawa, Kazuya*; Bao, S.*; Wen, J.*
Physical Review B, 109(22), p.224411_1 - 224411_10, 2024/06
Times Cited Count：0 Percentile：0.00(Materials Science, Multidisciplinary)BWO
Nagl, J.*; Flavi
n, D.*; Hayashida, S.*; Povarov, K. Y.*; Yan, M.*; Murai, Naoki; Kawamura, Seiko; Simutis, F.*; Hicken, T. J.*; Luetkens, H.*; et al.
Physical Review Research (Internet), 6(2), p.023267_1 - 023267_18, 2024/06
