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Journal Articles

Negligible hydrogen solubility in FeS under high-pressure and high-temperature conditions; Implications for hydrogen storage in planetary cores

Takano, Masahiro*; Kagi, Hiroyuki*; Mori, Yuichiro*; Kobayashi, Hiroki*; Aoki, Katsutoshi*; Takahashi, Yoshio*; Ijichi, Yuta*; Kakizawa, Sho*; Tsujino, Noriyoshi*; Higo, Yuji*; et al.

ACS Earth and Space Chemistry (Internet), 15 Pages, 2026/00

Iron monosulfide (FeS) is an important sulfide phase in planetary materials and has been proposed as a potential host of hydrogen in planetary interiors. However, hydrogen solubility in FeS at high pressure and temperature remains debated. In this study, hydrogen incorporation in the NiAs-type FeS phase (FeS V) was reexamined using synchrotron X-ray absorption spectroscopy, in situ X-ray and neutron diffraction, and first-principles calculations. The experimental results indicate that the volume expansion observed under hydrogen-saturated conditions is explained by the reduction of Fe$$^{3+}$$ to Fe$$^{2+}$$ and a decrease in the $$delta$$ value of Fe-deficient Fe$$_{1-delta}$$S, rather than hydrogen incorporation into the lattice. These results suggest that hydrogen incorporation in FeS is extremely limited, with an upper bound of approximately 200 ppm up to 30 GPa.

Journal Articles

Lyotropic polymer liquid crystal coating; Enabling lamellar ion-conduction pathways for superior C-Rate performance in NCM523 cathodes

Marium, M.*; Aoki, Kentaro*; He, Y.*; Yamamoto, Katsuhiro*; Suwansoontorn, A.*; Ikuta, Seiya*; Hara, Mitsuo*; Nagano, Shusaku*; Nagao, Yuki*; Nishikawa, Kei*; et al.

ACS Applied Energy Materials (Internet), 8(22), p.16589 - 16600, 2025/11

 Times Cited Count:0 Percentile:0.00(Chemistry, Physical)

Journal Articles

Studying the in-medium $$phi$$ meson spectrum through kaons in proton-nucleus reactions

Balassa, G.*; Aoki, Kazuya*; Gubler, P.; Lee, S. H.*; Sako, Hiroyuki; Wolf, G.*

Progress of Theoretical and Experimental Physics (Internet), 2025(11), p.113C01_1 - 113C01_20, 2025/11

 Times Cited Count:0 Percentile:0.00(Physics, Multidisciplinary)

Journal Articles

Potassium abundances in extremely metal poor stars; Implications for nucleosynthesis in the final stages of massive star evolution

Ishigaki, Miho*; Tominaga, Nozomu*; Aoki, Wako*; Wanajo, Shinya*; Takiwaki, Tomoya*; Nakamura, Ko*; Iwamoto, Nobuyuki; Nomoto, Kenichi*; Kobayashi, Chiaki*

Astrophysical Journal, 992(2), p.215_1 - 215_17, 2025/10

 Times Cited Count:2 Percentile:58.10(Astronomy & Astrophysics)

Journal Articles

Magnetic field angle dependence of the magnetic phase diagram in UNi$$_{4}$$B

Hidaka, Hiroyuki*; Yanagisawa, Tatsuya*; Tabata, Chihiro; Kon, Fusako*; Amitsuka, Hiroshi*; Shimizu, Yusei*; Aoki, Dai*

Physical Review B, 112(14), p.144418_1 - 144418_6, 2025/10

 Times Cited Count:0 Percentile:0.00(Materials Science, Multidisciplinary)

Journal Articles

Nuclear hydrogen demonstration project using the HTTR; Demarcation of nuclear-industrial laws and design standards

Aoki, Takeshi; Shimizu, Atsushi; Ishii, Katsunori; Morita, Keisuke; Mizuta, Naoki; Kurahayashi, Kaoru; Yasuda, Takanori; Noguchi, Hiroki; Nomoto, Yasunobu; Iigaki, Kazuhiko; et al.

Annals of Nuclear Energy, 220, p.111503_1 - 111503_7, 2025/09

 Times Cited Count:1 Percentile:59.09(Nuclear Science & Technology)

Aiming to establish coupling technologies between a high temperature gas cooled reactor and a hydrogen production plant, JAEA has initiated the HTTR Heat Application Test Project and is conducting the safety design and the safety analysis for the licensing of the HTTR Heat Application Test Facility. The present study proposed a relative evaluation methodology for the demarcation of applicable laws and design standards for the nuclear hydrogen production system and applied it to the HTTR Heat Application Test Facility. The evaluation results showed that a candidate applying the High Pressure Gas Safety Act to the Heat Application Test Facility (hydrogen production plant) and design standards established under the High Pressure Gas Safety Act to the steam reformer did not show the lowest category in any of the metrics, and was proposed as the most superior demarcation option for the HTTR Heat Application Test Facility.

Journal Articles

Modeling the extraction of bound rubber from silica-filled styrene-butadiene rubber with toluene

Tamura, Yukiko*; Arakawa, Masato*; Takenaka, Mikihito*; Nakanishi, Yohei*; Fujinami, So*; Shibata, Motoki*; Yamamoto, Katsuhiro*; Miyata, Noboru*; Yamada, Masako*; Seto, Hideki*; et al.

Polymer, 333, p.128662_1 - 128662_8, 2025/08

 Times Cited Count:1 Percentile:37.16(Polymer Science)

Journal Articles

Surface and interfacial aggregation states in thin films of a polystyrene/polyrotaxane blend

Taguchi, Miki*; Miyata, Noboru*; Miyazaki, Tsukasa*; Aoki, Hiroyuki; Ozawa, Satoru*; Hasegawa, Ryuichi*; Morimitsu, Yuma*; Kawaguchi, Daisuke*; Yamamoto, Satoru*; Tanaka, Keiji*

Polymer Journal, 57(7), p.737 - 743, 2025/07

 Times Cited Count:0 Percentile:0.00(Polymer Science)

Journal Articles

Neutron reflectometry study on the interfacial layer of epoxy resin to improve adhesion strength

Liu, Y.*; Miyata, Noboru*; Miyazaki, Tsukasa*; Shundo, Atsuomi*; Kawaguchi, Daisuke*; Tanaka, Keiji*; Aoki, Hiroyuki

ACS Applied Materials & Interfaces, 17(25), p.37311 - 37318, 2025/06

Journal Articles

Neutron diffraction study of the crystal and magnetic structures of antiferromagnetic manganese deuteride at high temperatures and high pressures

Machida, Akihiko*; Saito, Hiroyuki*; Aoki, Katsutoshi*; Komatsu, Kazuki*; Hattori, Takanori; Sano, Asami; Funakoshi, Kenichi*; Machida, Shinichi*; Sato, Toyoto*; Orimo, Shinichi*

Physical Review B, 111(22), p.224413_1 - 224413_6, 2025/06

 Times Cited Count:1 Percentile:41.30(Materials Science, Multidisciplinary)

The crystal and magnetic structures of antiferromagnetic Mn deuterides formed by hydrogenating Mn metal at high temperature and high pressure, fcc $$gamma$$-MnDx and hcp $$epsilon$$-MnDx, were investigated by in-situ neutron powder diffraction. Deuterium atoms partially occupied the octahedral interstitial positions of the fcc and hcp metal lattices. The site occupancies increased rapidly with decreasing temperature from $$sim$$700 to $$sim$$450 K and remained down to 300 K. N$'{e}$el temperature of 543(10) K was determined for $$gamma$$-MnD$$_{0.34}$$. For $$epsilon$$-MnD$$_{0.62}$$, saturation magnetic moment and N$'{e}$el temperature were determined to be 0.82(1) $$mu_B$$ and 347(3) K, respectively. The N$'{e}$el temperatures determined for $$gamma$$-MnD$$_{0.34}$$ and $$epsilon$$-MnD$$_{0.62}$$ are consistent with those predicted by the respective Slater-Pauling curves proposed in previous studies. The updated N$'{e}$el temperatures provide insights into the development of more accurate Slater-Pauling curves based on electronic band structure calculations.

Journal Articles

A Focusing supermirror for time-of-flight grazing-incidence small-angle neutron scattering measurement

Yamazaki, Dai; Maruyama, Ryuji; Aoki, Hiroyuki; Hanashima, Takayasu*; Akutsu-Suyama, Kazuhiro*; Miyata, Noboru*; Soyama, Kazuhiko

Quantum Beam Science (Internet), 9(2), p.20_1 - 20_12, 2025/06

Journal Articles

Development of a bio-based adhesive by polymerization of Boc-protected vinyl catechol derived from caffeic acid

Tanizaki, Shiho*; Kubo, Tomohiro*; Bito, Yosuke*; Mori, Shigeki*; Aoki, Hiroyuki; Sato, Kotaro*

RSC Sustainability (Internet), 3(4), p.1714 - 1720, 2025/04

Journal Articles

A Decade of neutron diffraction study of iron hydrides

Aoki, Katsutoshi*; Machida, Akihiko*; Saito, Hiroyuki*; Hattori, Takanori

Koatsuryoku No Kagaku To Gijutsu, 35(1), p.4 - 11, 2025/03

Iron reacts with hydrogen to form solid solutions with body-centered cubic, face-centered cubic, hexagonal close packed, and double hexagonal close packed structures at high temperatures and high pressures. Neutron diffraction is the most powerful tool for determining the occupation sites and occupancies of hydrogen atoms dissolved in a metal lattice. Structural parameters, including hydrogen occupation sites and occupancies, are refined via Rietveld analysis for neutron diffraction data. We present our expertise in Rietveld refinement of iron hydrides accumulated over 10 years.

Journal Articles

Water-intercalated and humidity-responsive lamellar materials by self-assembly of sodium acrylate random copolymers

Horiike, Yuki*; Aoki, Hiroyuki; Ouchi, Makoto*; Terashima, Takaya*

Journal of the American Chemical Society, 147(8), p.6727 - 6738, 2025/02

 Times Cited Count:5 Percentile:82.18(Chemistry, Multidisciplinary)

Journal Articles

$$^{149}$$Sm synchrotron-radiation-based M$"{o}$ssbauer spectroscopy of Sm-based heavy fermion compounds

Tsutsui, Satoshi; Higashinaka, Ryuji*; Mizumaki, Masaichiro*; Kobayashi, Yoshio*; Nakamura, Jin*; Ito, Takashi; Yoda, Yoshitaka*; Matsuda, Tatsuma*; Aoki, Yuji*; Sato, Hideyuki*

Interactions (Internet), 245(1), p.9_1 - 9_10, 2024/12

Journal Articles

Surface depth analysis of chemical changes in random copolymer thin films composed of hydrophilic and hydrophobic silicon-based monomers induced by plasma treatment as studied by hard X-ray photoelectron spectroscopy and neutron reflectivity measurements

Yamamoto, Katsuhiro*; Imai, Tatsuya*; Kawai, Atsuki*; Ito, Eri*; Miyazaki, Tsukasa*; Miyata, Noboru*; Yamada, Norifumi*; Seto, Hideki*; Aoki, Hiroyuki

ACS Applied Materials & Interfaces, 16(48), p.66782 - 66791, 2024/11

 Times Cited Count:1 Percentile:8.69(Nanoscience & Nanotechnology)

Journal Articles

Adsorption isotherm and kinetics of diffusion of water accumulated between polypropylene thin film and Si substrate; Neutron reflectivity investigation

Miyazaki, Tsukasa*; Miyata, Noboru*; Arima-Osonoi, Hiroshi*; Shimokita, Keisuke*; Yamamoto, Katsuhiro*; Takenaka, Mikihito*; Nakanishi, Yohei*; Shibata, Motoki*; Aoki, Hiroyuki; Yamada, Norifumi*; et al.

Colloids and Surfaces A; Physicochemical and Engineering Aspects, 701, p.134928_1 - 134928_8, 2024/11

 Times Cited Count:1 Percentile:6.29(Chemistry, Physical)

Journal Articles

Separating the transverse and longitudinal modes of $$phi$$, $$rho$$, $$K^{ast}$$ and $$K_1$$ mesons through their angular-dependent two-body decay modes

Park, I. W.*; Sako, Hiroyuki; Aoki, Kazuya*; Gubler, P.; Lee, S. H.*

Journal of Subatomic Particles and Cosmology (Internet), 1-2, p.100014_1 - 100014_11, 2024/11

Journal Articles

Methodology development for explosion hazard evaluation in hydrogen production system using high temperature gas-cooled reactor

Morita, Keisuke; Aoki, Takeshi; Shimizu, Atsushi; Sato, Hiroyuki

Proceedings of 31st International Conference on Nuclear Engineering (ICONE31) (Internet), 6 Pages, 2024/11

Journal Articles

JENDL-5 benchmarking for advanced test reactor for preparing burnup analysis using isotopic data from HTGR type fuel irradiation tests

Okita, Shoichiro; Aoki, Takeshi; Fukaya, Yuji; Tachibana, Yukio

Proceedings of 31st International Conference on Nuclear Engineering (ICONE31) (Internet), 5 Pages, 2024/11

659 (Records 1-20 displayed on this page)