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Ebashi, Takeshi; Kawamura, Makoto*; Inagaki, Manabu*; Koo, Shigeru*; Shibata, Masahiro; Itazu, Toru; Nakajima, Kunihiko*; Miyahara, Kaname; Apted, M. J.*
Materials Research Society Symposium Proceedings, Vol.1665, p.39 - 45, 2014/07
In Japan, the likelihood of uplift/erosion on repository performance and waste isolation can be typically greatly reduced or excluded by careful siting, however, the inability to completely exclude the uplift/erosion scenario may require an analysis of the consequences of such a scenario. For this purpose, an assessment approach has been developed to more realistically treat the effect of uplift/erosion for a hypothetical repository located in sedimentary host rock. A key advantage to this approach is the extrapolation of the geohistory of modern analogue sites to develop credible initial inputs for future volunteer sites that may be poorly characterized at the initial stages of site investigation. In addition, the approach provides a systematic basis for bounding the range of possible evolution in thermal-hydrological-mechanical-chemical conditions of a repository experiencing different uplift/ erosion rates.
Sasamoto, Hiroshi; Yui, Mikazu; Randolph C Arthu*; Apted, M. J.*; Iwatsuki, Teruki
JNC TN8400 2001-019, 56 Pages, 2001/02
JNC-TN8400-2001-019.pdf:1.67MB
The purpose of this report is to provide a survey and review on oxidation-reduction ("redox") reactions, with particular emphasis on implications for disposal of high-level waste (HLW) in deep geological formations. As an overview, the focus is on basic principles, problems, and proposed research related specifically to the assessment of redox for a HLW repository in Japan. For a more comprehensive treatment of redox and the myriad associated issues, the reader is directed to the cited textbooks used as primary references in this report. Low redox conditions in deep geological formations is a key assumption in the "Second Progress Report on Research and Development for the Geological Disposal of HLW in Japan" (hereafter called "H12"). The release behavior of multivalent radioelements (e.g., Tc, Se, U, Pu, NP), as well as daughter radioelements of these radioelements, from a deep geological repository are sensitively related to redox conditions. Furthermore, the performance of certain barrier materials, such as overpack and buffer, may be impacted by redox conditions. Given this importance, this report summarizes some key topics for future technical studies supporting site characterization and repository performance as follows : (1)To fully test the conceptual models for system Eh, it will be necessary to measure and evaluate trace element and isotopic information of both coexisting groundwater and reactive minerals of candidate rocks. (2)Because of importance of volatile species (e.g., O
, H etc.) in redox reactions, and given the high total pressure of a repository located 500 to 1000 meter deep, laboratory investigations of redox will necessarily require use of pressurized test devices that can fully simulate repository conditions. (3)The stability (redox capacity) of the repository system with respect to potential changes in redox boundary condition induced by oxidizing waters intrusion should be established experimentally. (4)An overall ...
PATRICIA F SALTE*; Sasamoto, Hiroshi; Apted, M. J.*; Yui, Mikazu
JNC TN8400 99-023, 231 Pages, 1999/05
The groundwater chemistry is one of important geological environment for performance assessment of high level radioactive disposal system. This report describes the results of geostatistical analysis of groundwater chemistry in Japan. Over 15,000 separate groundwater analyses have been collected of deep Japanese groundwaters for the purpose of evaluating the range of geochemical conditions for geological radioactive waste repositories in Japan. The significance to issues such as radioelement solubility limits, sorption, corrosion of overpack, behavior of compacted clay buffers, and many other factors involved in safety assessment. It is important therefore, that a small, but representative set of groundwater types be identified so that defensible models and data for generic repository performance assessment can be established. Principal component analysis (PCA) is used to categorize representative deep groundwater types from this extensive data set. PCA is a multi-variate statistical analysis technique, similar to factor analysis or eigenvector analysis, designed to provide the best possible resolution of the variability within multi-variate data sets. PCA allows the graphical inspection of the most important similarities (clustering) and differences among samples, based on simultaneous consideration of all variables in the dataset, in a low dimensionality plot. It also allows the analyst to determine the reasons behind any pattern that is observed. In this study, PCA has been aided by hierarchical cluster analysis (HCA), in which statistical indices of similarity among multiple samples are used to distinguish distinct clusters of samples. HCA allows the natural, a priori, grouping of data into clusters showing similar attributes and is graphically represented in a dendrogram Pirouette is the multivariate statistical software package used to conduct the PCA and HCA for the Japanese groundwater dataset. An audit of the initial 15,000 sample dataset on the ...
