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Journal Articles

Electronic structure of Li$$^{+}$$@C$$_{60}$$; Photoelectron spectroscopy of the Li$$^{+}$$@C$$_{60}$$[PF$$_{6}$$$$^{-}$$] salt and STM of the single Li$$^{+}$$@C$$_{60}$$ molecules on Cu(111)

Yamada, Yoichi*; Kuklin, A. V.*; Sato, Sho*; Esaka, Fumitaka; Sumi, Naoya*; Zhang, C.*; Sasaki, Masahiro*; Kwon, E.*; Kasama, Yasuhiko*; Avramov, P. V.*; et al.

Carbon, 133, p.23 - 30, 2018/07

 Times Cited Count:8 Percentile:47.45(Chemistry, Physical)

We report first STM observation of the Li$$^{+}$$ ion endohedral C$$_{60}$$, which is of a new class of endohedral fullerenes, prepared by means of evaporation of high-purity Li$$^{+}$$@C$$_{60}$$[PF$$_{6}$$$$^{-}$$] salt in ultra-high vacuum. Prior to the STM measurements, the electronic structure of Li$$^{+}$$@C$$_{60}$$ in the Li$$^{+}$$@C$$_{60}$$[PF$$_{6}$$$$^{-}$$] salt was also precisely determined. In the salt, it is shown that Li and PF$$_{6}$$ have nearly single positive and negative charge, respectively, and the C$$_{60}$$ cage is nearly neutral, suggesting that Li$$^{+}$$@C$$_{60}$$ in the salt retains its original electronic state.

Journal Articles

Contracted interlayer distance in graphene/sapphire heterostructure

Entani, Shiro; Antipina, L. Y.*; Avramov, P.*; Otomo, Manabu*; Matsumoto, Yoshihiro*; Hirao, Norie; Shimoyama, Iwao; Naramoto, Hiroshi*; Baba, Yuji; Sorokin, P. B.*; et al.

Nano Research, 8(5), p.1535 - 1545, 2015/05

 Times Cited Count:21 Percentile:72.73(Chemistry, Physical)

Journal Articles

Contact-induced spin polarization in BNNT(CNT)/TM (TM=Co, Ni)nanocomposites

Kuzubov, A. A.*; Kovaleva, E. A.*; Avramov, P. V.*; Kuklin, A. V.*; Mikhaleva, N. S.*; Tomilin, F. N.*; Sakai, Seiji; Entani, Shiro; Matsumoto, Yoshihiro*; Naramoto, Hiroshi*

Journal of Applied Physics, 116(8), p.084309_1 - 084309_4, 2014/08

 Times Cited Count:8 Percentile:40.13(Physics, Applied)

Journal Articles

Atomic structure and physical properties of fused porphyrin nanoclusters

Avramov, P. V.*; Kuzubov, A. A.*; Sakai, Seiji; Otomo, Manabu*; Entani, Shiro; Matsumoto, Yoshihiro*; Eleseeva, N. S.*; Pomogaev, V. A.*; Naramoto, Hiroshi*

Journal of Porphyrins and Phthalocyanines, 18(7), p.552 - 568, 2014/07

 Times Cited Count:1 Percentile:6.25(Chemistry, Multidisciplinary)

Journal Articles

Contact-induced spin polarization of monolayer hexagonal boron nitride on Ni(111)

Otomo, Manabu; Yamauchi, Yasushi*; Kuzubov, A. A.*; Eliseeva, N. S.*; Avramov, P.*; Entani, Shiro; Matsumoto, Yoshihiro; Naramoto, Hiroshi*; Sakai, Seiji

Applied Physics Letters, 104(5), p.051604_1 - 051604_4, 2014/02

 Times Cited Count:11 Percentile:50.47(Physics, Applied)

Hexagonal boron nitride (h-BN) is a promising barrier material for graphene spintronics. In this study, spin-polarized metastable de-excitation spectroscopy (SPMDS) is employed to study the spin-dependent electronic structure of monolayer h-BN on Ni(111). The extreme surface sensitivity of SPMDS enables us to elucidate a partial filling of the in-gap states of h-BN without any superposition of Ni 3$$d$$ signals. The in-gap states are shown to have a considerable spin polarization parallel to the majority spin of Ni. The positive spin polarization is attributed to the $$pi$$-$$d$$ hybridization and the effective spin transfer to the nitrogen atoms at the h-BN/Ni(111) interface.

Journal Articles

Spin orientation transition across the single-layer graphene/nickel thin film interface

Matsumoto, Yoshihiro; Entani, Shiro; Koide, Akihiro*; Otomo, Manabu; Avramov, P.; Naramoto, Hiroshi*; Amemiya, Kenta*; Fujikawa, Takashi*; Sakai, Seiji

Journal of Materials Chemistry C, 1(35), p.5533 - 5537, 2013/09

 Times Cited Count:22 Percentile:71.5(Materials Science, Multidisciplinary)

Journal Articles

High spin polarization at the Fe/C$$_{60}$$ interface in the Fe-doped C$$_{60}$$ film

Sakai, Seiji; Matsumoto, Yoshihiro; Otomo, Manabu; Entani, Shiro; Avramov, P.; Sorokin, P. B.*; Naramoto, Hiroshi*

Synthetic Metals, 173, p.22 - 25, 2013/06

 Times Cited Count:2 Percentile:11.91(Materials Science, Multidisciplinary)

Journal Articles

Contact-induced spin polarization in graphene/$$h$$-BN/Ni nanocomposites

Avramov, P.; Kuzubov, A. A.*; Sakai, Seiji; Otomo, Manabu; Entani, Shiro; Matsumoto, Yoshihiro; Naramoto, Hiroshi*; Eliseeva, N. S.*

Journal of Applied Physics, 112(11), p.114303_1 - 114303_10, 2012/12

 Times Cited Count:16 Percentile:57.94(Physics, Applied)

Journal Articles

Intrinsic edge asymmetry in narrow zigzag hexagonal heteroatomic nanoribbons causes their subtle uniform curvature

Avramov, P.; Fedorov, D. G.*; Sorokin, P. B.*; Sakai, Seiji; Entani, Shiro; Otomo, Manabu; Matsumoto, Yoshihiro; Naramoto, Hiroshi*

Journal of Physical Chemistry Letters (Internet), 3(15), p.2003 - 2008, 2012/08

 Times Cited Count:30 Percentile:78.76(Chemistry, Physical)

Journal Articles

High hydrogen-adsorption-rate material based on graphane decorated with alkali metals

Antipina, L. Y.*; Avramov, P.; Sakai, Seiji; Naramoto, Hiroshi*; Otomo, Manabu; Entani, Shiro; Matsumoto, Yoshihiro; Sorokin, P. B.*

Physical Review B, 86(8), p.085435_1 - 085435_7, 2012/08

 Times Cited Count:46 Percentile:87.52(Materials Science, Multidisciplinary)

Journal Articles

Bias voltage dependence of tunneling magnetoresistance in granular C$$_{60}$$-Co films with current-perpendicular-to-plane geometry

Sakai, Seiji; Mitani, Seiji*; Matsumoto, Yoshihiro; Entani, Shiro; Avramov, P.; Otomo, Manabu; Naramoto, Hiroshi*; Takanashi, Koki

Journal of Magnetism and Magnetic Materials, 324(12), p.1970 - 1974, 2012/06

 Times Cited Count:3 Percentile:16.62(Materials Science, Multidisciplinary)

Journal Articles

High-capacity electrode material BC$$_{3}$$ for lithium batteries proposed by ${it ab initio}$ simulations

Kuzubov, A. A.*; Fedorov, A. S.*; Eliseeva, N. S.*; Tomilin, F. N.*; Avramov, P.; Fedorov, D. G.*

Physical Review B, 85(19), p.195415_1 - 195415_4, 2012/05

 Times Cited Count:29 Percentile:77.77(Materials Science, Multidisciplinary)

Journal Articles

Precise control of single- and bi-layer graphene growths on epitaxial Ni(111) thin films

Entani, Shiro; Matsumoto, Yoshihiro; Otomo, Manabu; Avramov, P.; Naramoto, Hiroshi*; Sakai, Seiji

Journal of Applied Physics, 111(6), p.064324_1 - 064324_6, 2012/03

 Times Cited Count:17 Percentile:62.03(Physics, Applied)

${it In-situ}$ analysis was performed on the graphene growth in ultrahigh vacuum chemical vapor deposition by exposing the epitaxial Ni(111) thin film to benzene vapor at 873 K. It is shown that the highly uniform single- and bi-layer graphenes can be synthesized by the control of benzene exposure in the range of 10-10$$^{5}$$ langmuirs, reflecting a change in the graphene growth-rate by three orders of magnitude in between the first and second layer. Electron energy loss spectroscopy measurements of single- and bi-layer graphenes indicates that the interface interaction between bi-layer graphene and Ni(111) is weakened in comparison with that between single-layer graphene and Ni(111). It is also clarified from the micro-Raman analysis that the structural and electrical uniformities of the graphene film transformed on a SiO$$_{2}$$ substrate are improved remarkably under the specific exposure conditions at which the growths of single- and bi-layer graphenes are completed.

Journal Articles

Thermo-dynamical contours of electronic-vibrational spectra simulated using the statistical quantum-mechanical methods

Pomogaev, V.*; Pomogaeva, A.*; Avramov, P.; Jalkanen, K. J.*; Kachin, S.*

Theoretical Chemistry Accounts, 130(4-6), p.609 - 632, 2011/12

 Times Cited Count:8 Percentile:21.38(Chemistry, Physical)

Journal Articles

Relative isomer abundance of fullerenes and carbon nanotubes correlates with kinetic stability

Fedorov, A. S.*; Fedorov, D. A.*; Kuzubov, A. A.*; Avramov, P.; Nishimura, Yoshifumi*; Irle, S.*; Witek, H. A.*

Physical Review Letters, 107(17), p.175506_1 - 175506_5, 2011/10

 Times Cited Count:20 Percentile:73.74(Physics, Multidisciplinary)

Journal Articles

Ferromagnetic interlayer coupling in C$$_{60}$$-Co compound/Ni bilayer structure

Matsumoto, Yoshihiro; Sakai, Seiji; Entani, Shiro; Takagi, Yasumasa*; Nakagawa, Takeshi*; Naramoto, Hiroshi*; Avramov, P.; Yokoyama, Toshihiko*

Chemical Physics Letters, 511(1-3), p.68 - 72, 2011/07

 Times Cited Count:5 Percentile:18.35(Chemistry, Physical)

X-ray magnetic circular dichroism (XMCD) spectroscopy was employed to investigate the electronic and magnetic structures of the bilayers of a C$$_{60}$$-Co compound and Ni. A few -several nm thick C$$_{60}$$-Co compound layers on the Ni(111) surface are found to show intense XMCD signals attributed to the localized Co d-spins only with the remanent magnetization of Ni layer. It is suggested that the region of the C$$_{60}$$-Co compound within 3 nm from the interface is ferromagnetically coupled with Ni due to the indirect exchange interaction mediated by C$$_{60}$$, probably relevant to the interlayer charge transfer.

Journal Articles

${it Ab initio}$ LC-DFT study of graphene, multilayer graphenes and graphite

Avramov, P.; Sakai, Seiji; Entani, Shiro; Matsumoto, Yoshihiro; Naramoto, Hiroshi*

Chemical Physics Letters, 508(1-3), p.86 - 89, 2011/05

 Times Cited Count:20 Percentile:62.55(Chemistry, Physical)

Journal Articles

Effect of cotunneling and spin polarization on the large tunneling magnetoresistance effect in granular C$$_{60}$$-Co films

Sakai, Seiji; Mitani, Seiji*; Sugai, Isamu; Takanashi, Koki; Matsumoto, Yoshihiro; Entani, Shiro; Naramoto, Hiroshi*; Avramov, P.; Maeda, Yoshihito

Physical Review B, 83(17), p.174422_1 - 174422_6, 2011/05

 Times Cited Count:8 Percentile:39.13(Materials Science, Multidisciplinary)

Journal Articles

Influence of size effect on the electronic and elastic properties of diamond films with nanometer thickness

Chernozatonskii, L. A.*; Sorokin, P. B.*; Kuzubov, A. A.*; Sorokin, B. P.*; Kvashnin, A. G.*; Kvashnin, D. G.*; Avramov, P.; Yakobson, B. I.*

Journal of Physical Chemistry C, 115(1), p.132 - 136, 2011/01

 Times Cited Count:61 Percentile:86.71(Chemistry, Physical)

Journal Articles

Atomic structure and energetic stability of complex chiral silicon nanowires

Avramov, P.; Minami, Soma*; Irle, S.*; Chernozatonskii, L. A.*; Morokuma, Keiji*

Journal of Physical Chemistry C, 114(35), p.14692 - 14696, 2010/09

 Times Cited Count:1 Percentile:6.17(Chemistry, Physical)

98 (Records 1-20 displayed on this page)