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Che, G.*; Tang, X.*; Liu, J.*; Lang, P.*; Fei, Y.*; Yang, X.*; Wang, Y.*; Gao, D.*; Wang, X.*; Ju, J.*; et al.
Nano Letters, 25(39), p.14467 - 14472, 2025/09
Times Cited Count：1 Percentile：31.65(Chemistry, Multidisciplinary)Mechanochemical radical polymerization has unique advantages in the synthesis of polymer due to its reduced solvent consumption and adaptability of insoluble monomers. However, it suffers from the uncontrollable degradation of the formed polymers during reaction and new synthetic strategy with precise controllability needs to be developed. Here, by employing high static pressure up to 30 GPa, we found 1,3,5-trifluorobenzene undergoes radical polymerization by breaking the conjugated 
-bonds, and forms a carbon nanothread with high selectivity (Polymer-I polymorph). Based on the crystal structure at the threshold pressure and the calculated energy barriers for the bonding pathway, we concluded that the benzene-rings react via a 1-2 radical polymerization pathway. Our work highlights high pressure is a robust method to initiate the solid-state radical polymerization, even for very stable aromatics, and offers fresh insights for the synthesis of polymeric carbon-based materials with high selectivity.
under pressureKnafo, W.*; Thebault, T.*; Raymond, S.*; Manuel, P.*; Khalyavin, D. D.*; Orlandi, F.*; Ressouche, E.*; Beauvois, K.*; Lapertot, G.*; Kaneko, Koji; et al.
Physical Review X, 15(2), p.021075_1 - 021075_16, 2025/05
Times Cited Count：10 Percentile：93.02(Physics, Multidisciplinary)Yang, X.*; Che, G.*; Wang, Y.*; Zhang, P.*; Tang, X.*; Lang, P.*; Gao, D.*; Wang, X.*; Wang, Y.*; Hattori, Takanori; et al.
Nano Letters, 25(3), p.1028 - 1035, 2025/01
Times Cited Count：7 Percentile：87.89(Chemistry, Multidisciplinary)Saturated sp
-carbon nanothreads (CNTh) have garnered significant interest due to their predicted high Young's modulus and thermal conductivity. While the incorporation of heteroatoms into the central ring has been shown to influence the formation of CNTh and yield chemically homogeneous products, the impact of pendant groups on the polymerization process remains underexplored. In this study, we investigate the pressure-induced polymerization of phenol, revealing two phase transitions occurring below 0.5 and 4 GPa. Above 20 GPa, phenol polymerizes into degree-4 CNThs featuring hydroxyl and carbonyl groups. Hydrogen transfer of hydroxyl groups was found to hinder the formation of degree-6 nanothreads. Our findings highlight the crucial role of the hydroxyl group in halting further intracolumn polymerization and offer valuable insights for future mechanism research and nanomaterial synthesis.
Be ground-state molecular structure using Be(
)
He triple differential reaction cross-section measurementsLi, P. J.*; Beaumel, D.*; Lee, J.*; Assi
, M.*; Chen, S.*; Franchoo, S.*; Gibelin, J.*; Hammache, F.*; Harada, T.*; Kanada-En'yo, Yoshiko*; et al.
Physical Review Letters, 131(21), p.212501_1 - 212501_7, 2023/11
Times Cited Count：36 Percentile：94.69(Physics, Multidisciplinary)The cluster structure of the neutron-rich isotope Be has been probed via the () reaction. The triple differential cross-section was extracted and compared to distorted-wave impulse approximation reaction calculations performed in a microscopic framework using the Tohsaki-Horiuchi-Schuck-R
pke wave function and the wave function deduced from Antisymmetrized Molecular Dynamics calculations. The remarkable agreement between calculated and measured cross-sections in both shape and magnitude validates the description of the Be ground-state as a rather compact nuclear molecule.
mesocrystal formationLi, Z.*; Piankova, D.*; Yang, Y.*; Kumagai, Yuta; Zschiesche, H.*; Jonsson, M.*; Tarakina, N. V.*; Soroka, I. L.*
Angewandte Chemie; International Edition, 61(6), p.e202112204_1 - e202112204_9, 2022/02
Times Cited Count：11 Percentile：42.91(Chemistry, Multidisciplinary)The role of intermediate phases in CeO mesocrystal formation from aqueous Ce(III) solutions subjected to 
-radiation was studied. Radiolytically formed hydroxyl radicals convert soluble Ce(III) into less soluble Ce(IV). Transmission electron microscopy and X-ray diffraction studies of samples from different stages of the process allowed the identification of several stages in CeO mesocrystal evolution following the oxidation to Ce(IV): (1) formation of hydrated Ce(IV)-hydroxides, serving as intermediates in the liquid-to-solid phase transformation; (2) CeO primary particle growth inside the intermediate phase; (3) alignment of the primary particles into "pre-mesocrystals" and subsequently to mesocrystals, guided by confinement of the amorphous intermediate phase and accompanied by the formation of mineral bridges. Further alignment of the obtained mesocrystals into supracrystals occurs upon slow drying, making it possible to form complex hierarchical architectures.
Gao, D.*; Tang, X.*; Wang, X.*; Yang, X.*; Zhang, P.*; Che, G.*; Han, J.*; Hattori, Takanori; Wang, Y.*; Dong, X.*; et al.
Physical Chemistry Chemical Physics, 23(35), p.19503 - 19510, 2021/09
Times Cited Count：7 Percentile：34.60(Chemistry, Physical)Pressure-induced phase transition and polymerization of nitrogen-rich molecules are widely focused due to its extreme importance for the development of green high energy density materials. Here, we present a study of the phase transition and chemical reaction of 1H-tetrazole up to 100 GPa by using 
Raman, IR, X-ray diffraction, neutron diffraction techniques and theoretical calculation. A phase transition above 2.6 GPa was identified and the high-pressure structure was determined with one molecule in a unit cell. The 1H-tetrazole polymerizes reversibly below 100 GPa, probably through a carbon-nitrogen bonding instead of nitrogen-nitrogen bonding. Our studies updated the structure model of the high pressure phase of 1H-tetrazole, and presented the possible intermolecular bonding route for the first time, which gives new insights to understand the phase transition and chemical reaction of nitrogen-rich compounds, and benefit for designing new high energy density materials.
Rb isotopesTorres, D. A.*; Chapman, R.*; Kumar, V.*; Hadinia, B.*; Hodsdon, A.*; Labiche, M.*; Liang, X.*; O'Donnell, D.*; Ollier, J.*; Orlandi, R.; et al.
European Physical Journal A, 55(9), p.158_1 - 158_21, 2019/09
Times Cited Count：1 Percentile：9.98(Physics, Nuclear)Sato, Tetsuya; Asai, Masato; Borschevsky, A.*; Beerwerth, R.*; Kaneya, Yusuke*; Makii, Hiroyuki; Mitsukai, Akina*; Nagame, Yuichiro; Osa, Akihiko; Toyoshima, Atsushi; et al.
Journal of the American Chemical Society, 140(44), p.14609 - 14613, 2018/11
Times Cited Count：36 Percentile：70.61(Chemistry, Multidisciplinary)The first ionization potential (IP
) yields information on valence electronic structure of an atom. IP values of heavy actinides beyond einsteinium (Es, Z = 99), however, have not been determined experimentally so far due to the difficulty in obtaining these elements on scales of more than one atom at a time. Recently, we successfully measured IP of lawrencium (Lr, Z = 103) using a surface ionization method. The result suggests that Lr has a loosely-bound electron in the outermost orbital. In contrast to Lr, nobelium (No, Z = 102) is expected to have the highest IP among the actinide elements owing to its full-filled 5f and the 7s orbitals. In the present study, we have successfully determined IP values of No as well as fermium (Fm, Z = 100) and mendelevium (Md, Z = 101) using the surface ionization method. The obtained results indicate that the IP value of heavy actinoids would increase monotonically with filling electrons up in the 5f orbital like heavy lanthanoids.
Even, J.*; Ackermann, D.*; Asai, Masato; Block, M.*; Brand, H.*; Di Nitto, A.*; D
llmann, Ch. E.*; Eichler, R.*; Fan, F.*; Haba, Hiromitsu*; et al.
Journal of Radioanalytical and Nuclear Chemistry, 303(3), p.2457 - 2466, 2015/03
Times Cited Count：16 Percentile：73.42(Chemistry, Analytical)Rapid In situ synthesis of metal carbonyl complexes has been demonstrated using short-lived isotopes produced in nuclear fission and fusion reactions. The short-lived isotopes with high recoil energy directly react with carbon-monoxides and form carbonyl complexes. Only highly volatile complexes were fast transported in a gas stream to counting and chemistry devices. Short-lived Mo, Tc, Ru, Rh, W, Re, Os, and Ir were found to form volatile carbonyl complexes, while no volataile complex of Hf and Ta were detected. This technique has been applied to a chemical investigation of the superheavy element Sg (atomic number 106), and will be applicable to various fields of nuclear science with short-lived transition metal isotopes.
Yakushev, A.*; Gates, J. M.*; Trler, A.*; Sch
del, M.; Dllmann, Ch. E.*; Ackermann, D.*; Andersson, L.-L.*; Block, M.*; Brchle, W.*; Dvorak, J.*; et al.
Inorganic Chemistry, 53(3), p.1624 - 1629, 2014/02
Times Cited Count：124 Percentile：98.99(Chemistry, Inorganic & Nuclear)We report on a gas-solid chromatography study of the adsorption of element 114 (flerovium, Fl) on a Au surface. Fl was produced in the nuclear fusion reaction 
Pu(
Ca, 3-4n)
Fl and was isolated in-flight from the primary beam in a physical recoil separator. The adsorption behavior of Fl, its nuclear 
-decay product Cn, their lighter homologues in groups 14 and 12, i.e., Pb and Hg, and the noble gas Rn were studied simultaneously by isothermal gas chromatography and thermochromatography. Two Fl atoms were detected. They adsorbed on a Au surface at room temperature, but not as readily as Pb and Hg. The observed adsorption behavior of Fl points to a higher inertness compared to its nearest homologue in the group, Pb. However, the measured lower limit for the adsorption enthalpy of Fl on a Au surface points to the formation of a metal-metal bond of Fl with Au. Fl is the least reactive element in the group, but still a metal.
Garcia Rodriguez, D.; Mihalache, O.; Ueda, Masashi
Proceedings of 16th International Symposium on Applied Electromagnetics and Mechanics (ISEM 2013), p.219 - 220, 2013/07
Rothe, S.*; Andreyev, A. N.*; Antalic, S.*; Borschevsky, A.*; Capponi, L.*; Cocolios, T. E.*; De Witte, H.*; Eliav, E.*; Fedorov, D. V.*; Fedosseev, V. N.*; et al.
Nature Communications (Internet), 4, p.1835_1 - 1835_6, 2013/05
Times Cited Count：99 Percentile：94.81(Multidisciplinary Sciences)Garcia Rodriguez, D.; Mihalache, O.; Ueda, Masashi
International Journal of Applied Electromagnetics and Mechanics, 39(1-4), p.297 - 303, 2012/05
Times Cited Count：2 Percentile：17.36(Engineering, Electrical & Electronic)Nakamura, Hiroo; Agostini, P.*; Ara, Kuniaki; Fukada, Satoshi*; Furuya, Kazuyuki*; Garin, P.*; Gessii, A.*; Giusti, D.*; Groeschel, F.*; Horiike, Hiroshi*; et al.
Fusion Engineering and Design, 84(2-6), p.252 - 258, 2009/06
Times Cited Count：26 Percentile：81.96(Nuclear Science & Technology)Nakamura, Hiroo; Agostini, P.*; Ara, Kuniaki; Cevolani, S.*; Chida, Teruo*; Ciotti, M.*; Fukada, Satoshi*; Furuya, Kazuyuki*; Garin, P.*; Gessii, A.*; et al.
Fusion Engineering and Design, 83(7-9), p.1007 - 1014, 2008/12
Times Cited Count：20 Percentile：74.85(Nuclear Science & Technology)This paper describes the latest design of liquid lithium target system in IFMIF. Design requirement of the Li target is to provide a stable Li jet with a speed of 20 m/s to handle an averaged heat flux of 1 GW/m
. A double reducer nozzle and a concaved flow are applied to the target design. On Li purification, a cold trap and two kinds of hot trap are applied to control impurities below permissible levels. Nitrogen concentration shall be controlled below 10 wppm by one of the hot trap. Tritium concentration shall be controlled below 1 wppm by an yttrium hot trap. To maintain reliable continuous operation, various diagnostics are attached to the target assembly. Among the target assembly, a back-plate made of RAFM is located in the most severe region of neutron irradiation (50 dpa/y). Therefore, two design options of replaceable back wall and their remote handling systems are under investigation.
Ni(t,
He)Co reactionGuillot, J.*; Beaumel, D.*; Van den Berg, A. M.*; Brandenburg. S.*; Davids, B.*; Fortier, S.*; Fujiwara, Mamoru; Gal
s, S.*; Harakeh, M. N.*; Hunyadi, M.*; et al.
Nuclear Physics A, 731, p.106 - 113, 2004/02
Times Cited Count：4 Percentile：29.88(Physics, Nuclear)no abstracts in English
Krasznahorkay, A.*; Akimune, Hidetoshi*; Van den Berg, A. M.*; Blasi, N.*; Brandenburg. S.*; Csatl
s, M.*; Fujiwara, Mamoru; Guly
s, J.*; Harakeh, M. N.*; Hunyadi, M.*; et al.
Nuclear Physics A, 731, p.224 - 234, 2004/02
Times Cited Count：77 Percentile：94.51(Physics, Nuclear)no abstracts in English
Mihalache, O.; Garcia Rodriguez, D.*; Yamamoto, Toshihiro*; Cheng, W.*
no journal, ,
