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Auh, Y. H.*; Neal, N. N.*; Arole, K.*; Regis, N. A.*; Nguyen, T.*; 小川 修一*; 津田 泰孝; 吉越 章隆; Radovic, M.*; Green, M. J.*; et al.
ACS Applied Materials & Interfaces, 17(21), p.31392 - 31402, 2025/05
被引用回数：0 パーセンタイル：0.00(Nanoscience & Nanotechnology)MXenes are a promising class of 2D nanomaterials and are of particular interest for gas barrier application. However, MXene nanosheets naturally bear a negative charge, which prevents assembly with negatively charged polymers, such as polyacrylic acid (PAA), into gas barrier coatings. Here, we present MXene- and PAA-based layer-by-layer (MXene/PAA LbL) multilayers formed by leveraging hydrogen bonding interactions. When assembled in acidic conditions, MXene/PAA LbL films exhibit conformal, pin-hole free, nacre-like structures. The MXene/PAA LbL films yield high blocking capability and low permeability (0.14
0.01 cc mm m
day
MPa) for hydrogen gas. These nacre-like structures are also electronically conductive (up to 37030 S cm). Specifically, the reversible deconstruction of these films under basic conditions is experimentally verified. This study shows that hydrogen bonding interactions can be leveraged to form MXene LbL multilayers as gas barriers, electronically conducive coatings, and deconstructable thin films via pH control.
experiment using a 
Cf calibration sourceLee, D. H.*; 百々 拓; 羽賀 勝洋; 原田 正英; 長谷川 勝一; 春日井 好己; 木下 秀孝; 増田 志歩; 明午 伸一郎; 酒井 健二; et al.
Nuclear Instruments and Methods in Physics Research A, 1072, p.170216_1 - 170216_6, 2025/03
被引用回数：2 パーセンタイル：98.29(Instruments & Instrumentation)JSNS investigates short-baseline neutrino oscillations using a 24-meter baseline and a 17-tonne Gd-loaded liquid scintillator target. Accurate event-reconstruction algorithms are crucial for analyzing experimental data. The algorithms undergo meticulous validation through calibration with a Cf source. This paper outlines the methodology and evaluates the reconstruction performance, focusing on neutrino interactions up to approximately 50 MeV for sterile neutrino searches. Both Cf and Michel electron events are studied to evaluate reconstruction accuracy. The analysis concludes that the uncertainty of the fiducial volume, with an appropriate correction, is much less than the requirement of JSNS requirement (10%). Furthermore, the energy resolution is measured to be 3.3 0.1% for the Michel electron endpoint and 4.3 0.1% for the n-Gd peak in the central region.
長澤 真*; 清水 祐輔*; 山口 瑛子; 徳永 紘平; 向井 広樹*; 青柳 登; Mei, H.; 高橋 嘉夫*
Chemical Geology, 670, p.122431_1 - 122431_25, 2024/12
被引用回数：2 パーセンタイル：64.73(Geochemistry & Geophysics)Typical vertical profiles of ion-adsorption type rare earth element deposits (REE-IADs) discovered in the central Japan were studied by various speciation analyses including X-ray absorption fine structure (XAFS) and laser-induced fluorescence (LIF) spectroscopy combined with transmission electron microscope (TEM) and adsorption/desorption experiments. The results revealed that REE speciation, migration and enrichment in the weathered granite is largely controlled by soil pH which control the variable charges of kaolinite as the REE host phase. The distribution coefficient Kd, together with the soil pH, increases as the depth increase, resulting in (i) REE dissolution and migration in upper layers near the surface acidic environment where hydroxyls of kaolinite basal surfaces and edges are deprotonated to a lesser degree and (ii) REE accumulation in relatively high pH environment below the surface where hydroxyls of kaolinite basal surfaces and edges deprotonated to a larger degree to produce variable charges as adsorption sites for REEs. The increase of soil pH above 6 in deeper layers promotes inner-sphere complexation of REEs. The inner-sphere complexation inhibits the ion-exchange extraction of REEs, but the inner-sphere complexes can be still extracted by lowering the pH, which suggests the adsorption of inner- and outer-sphere complexes is reversible. This fact is important both from (i) understanding of vertical profile of REE with variation of pH and (ii) effective recovery of REE from weathered granite at all the depths in the enriched layer.
杉浦 佑樹; 石寺 孝充; 青柳 登; Mei, H.; 斉藤 拓巳*; 舘 幸男
Applied Clay Science, 258, p.107476_1 - 107476_10, 2024/09
被引用回数：2 パーセンタイル：69.91(Chemistry, Physical)This study performed batch sorption experiments using Eu and Sm as chemical analogs of trivalent actinides to evaluate their sorption behavior onto illite in the presence of dissolved inorganic carbon (DIC). The results were analyzed using a thermodynamic sorption model (TSM), which predicted that Eu/Sm forms ternary-surface complexes with carbonate ions. Time-resolved laser fluorescence spectroscopy (TRLFS) measurements were performed to gather information on the chemical forms of sorbed Eu on illite. Parallel factor analysis (PARAFAC) of the TRLFS data indicated the presence of two Eu chemical species. The pH dependence of the chemical species was consistent with that of the surface species predicted by TSM. The dominant chemical species in the presence of carbonate was inferred to be coordinating carbonate ions based on the fluorescence lifetime, supporting the validity of the TSM.
遠藤 駿典; 安部 亮太*; 藤岡 宏之*; 猪野 隆*; 岩本 修; 岩本 信之; 河村 しほり*; 木村 敦; 北口 雅暁*; 小林 龍珠*; et al.
European Physical Journal A, 60(8), p.166_1 - 166_10, 2024/08
被引用回数：2 パーセンタイル：74.11(Physics, Nuclear)Measurements of 
-ray circular polarization emitted from neutron capture reactions provide valuable information for nuclear physics studies. The spin and parity of excited states can be determined by measuring the circular polarization from polarized neutron capture reactions. Furthermore, the -ray circular polarization in a neutron capture resonance is crucial for studying the enhancement effect of parity nonconservation in compound nuclei. The -ray circular polarization can be measured using a polarimeter based on magnetic Compton scattering. A polarimeter was constructed, and its performance indicators were evaluated using a circularly polarized -ray beam. Furthermore, as a demonstration, the -ray circular polarization was measured in 
S(n,)
S reactions with polarized neutrons.
Yuan, X.*; Hu, Q. H.*; Fang, X.*; Wang, Q. M.*; Ma, Y.*; 舘 幸男
Sedimentary Geology, 465, p.106633_1 - 106633_14, 2024/05
被引用回数：0 パーセンタイル：0.00(Geology)Archie's cementation factor, m, is a critical parameter for petrophysical studies, and the value is influenced by several factors such as the shape, type, and size of grains, degrees of diagenesis, and associated pore structure. Using integrated experimental and theoretical approaches, the goal of this study is to obtain the cementation factor of rocks (both reservoir rock and caprock) and assess the impact of diagenesis processes on the values of the cementation factor. Thirteen samples of geologically diverse rocks (six mudstones, four fossiliferous limestones, two marbles, and one sandstone) were selected to achieve these research objectives. Two approaches, the diffusion of gas tracers and the Bosanquet formula calculation using pore-throat sizes from mercury intrusion porosimetry analyses, were used to derive the cementation factors of these rock samples. These rocks were categorized into two groups based on the correlation between average pore-throat diameter and diffusivity, and an exponential-law relationship between the cementation factor and porosity was determined for these sample groups. In addition, thin-section petrography and field emission-scanning electron microscopy observations were utilized to investigate diagenetic processes, with four diagenetic patterns being established: (1) strong compaction, strong cementation, and weak dissolution-diagenesis pattern; (2) weak compaction, medium cementation, and weak dissolution-diagenesis pattern; (3) weak compaction, medium cementation, and strong dissolution-diagenesis pattern; and (4) fracture-matrix pattern. The results indicated that diagenetic processes and microfractures contribute to the variability in the cementation factors in these rock samples.
experimentLee, D. H.*; 百々 拓; 羽賀 勝洋; 原田 正英; 長谷川 勝一; 春日井 好己; 木下 秀孝; 増田 志歩; 明午 伸一郎; 酒井 健二; et al.
European Physical Journal C, 84, p.409_1 - 409_6, 2024/04
被引用回数：1 パーセンタイル：35.96(Physics, Particles & Fields)JSNS (J-PARC Sterile Neutrino Search at J-PARC Spallation Neutron Source) is an experiment that searches for sterile neutrinos via the observation of 
appearance oscillations using muon decay-at-rest neutrinos. The JSNS experiment performed data taking from 2021. In this manuscript, a study of the accidental background is presented. The rate of the accidental background is (9.29
0.39)
10
/ spill with 0.75 MW beam power and comparable to the expected number of signal events.
Mei, H.; 青柳 登; 斉藤 拓巳*; 田中 万也; 杉浦 佑樹; 舘 幸男
Applied Geochemistry, 162, p.105926_1 - 105926_8, 2024/02
被引用回数：2 パーセンタイル：64.73(Geochemistry & Geophysics)The sorption of U(VI) on illite at different pH and dissolved inorganic carbon (DIC) levels was investigated by using batch experiments, surface complexation modeling, and cryogenic time-resolved laser fluorescence spectroscopy (cryo-TRLFS) combined with parallel factor analysis (PARAFAC). The inhibiting effect of DIC on U(VI) sorption was revealed by the macroscopic batch experimental results. An updated 2-site protolysis non-electrostatic surface complexation and cation exchange model considering the formation of two uranyl-carbonate sorption complexes was able to reproduce the experimental results well. Based on the PARAFAC analysis on the cryo-TRLFS spectra, there was clear correspondence in the variation trend of the derived components with the sorption species from the modeling results, validating the formation of ternary uranyl-carbonate sorption species.
SnHuang, Z.*; Wang, W.*; Ye, H.*; Bao, S.*; Shangguan, Y.*; Liao, J.*; Cao, S.*; 梶本 亮一; 池内 和彦*; Deng, G.*; et al.
Physical Review B, 109(1), p.014434_1 - 014434_9, 2024/01
被引用回数：3 パーセンタイル：57.35(Materials Science, Multidisciplinary)TbMnSn is a correlated topological magnet with a Mn-based kagome lattice, in which a Chern gap opens at the Dirac point at low temperatures. The magnetic moment direction of the ferrimagnetic order changes from in the kagome plane to the out-of-plane upon cooling, which is essential for generating the Chern gap, but the underlying mechanism for the spin reorientation remains elusive. Here, we investigate the spin-reorientation transition in TbMnSn using neutron scattering. We provide direct evidence for the spin-reorientation transition and unveil the coexistence of two Tb modes at 200 K. To account for these results, we put forward a model based on SU(N) spin-wave theory, in which there is a temperature evolution of the ground state Tb 
orbitals, driven by the crystalline electric field, single-ion anisotropy, and exchange interactions between Tb and Mn ions. Our findings shed light on the complex magnetism of TbMnSn, despite its relatively simple ground state magnetic structure, and provide insights into the mechanisms for tuning magnetic topological materials.
小山 真一; 池内 宏知; 三次 岳志; 前田 宏治; 佐々木 新治; 大西 貴士; Tsai, T.-H.; 高野 公秀; 深谷 洋行; 中村 聡志; et al.
廃炉・汚染水・処理水対策事業事務局ホームページ(インターネット), 216 Pages, 2023/11
令和3年度及び4年度に原子力機構が補助事業者となって実施した令和3年度開始「廃炉・汚染水対策事業費補助金に係る補助事業(燃料デブリの性状把握のための分析・推定技術の開発(燃料デブリの分析精度向上、熱挙動の推定及び簡易分析のための技術開発))」の成果概要を最終報告として取りまとめた。本報告資料は、廃炉・汚染水・処理水対策事業事務局ウェブサイトにて公開される。
Soler, J. M.*; Kek
linen, P.*; Pulkkanen, V.-M.*; Moreno, L.*; Iraola, A.*; Trinchero, P.*; Hokr, M.*; 
ha, J.*; Havlov
, V.*; Trpko
ov, D.*; et al.
Nuclear Technology, 209(11), p.1765 - 1784, 2023/11
被引用回数：4 パーセンタイル：71.02(Nuclear Science & Technology)The REPRO-TDE test was performed at a depth of about 400 m in the ONKALO underground research facility in Finland. Synthetic groundwater containing radionuclide tracers (HTO, Cl-36, Na-22, Ba-133, Cs-134) was circulated for about four years in a packed-off interval of the injection borehole. Tracer activities were additionally monitored in two observation boreholes. The test was the subject of a modelling exercise by the SKB GWFTS Task Force. Eleven teams participated in the exercise, using different model concepts and approaches. Predictive model calculations were based on laboratory-based information concerning porosities, diffusion coefficients and sorption partition coefficients. After the experimental results were made available, the teams were able to revise their models to reproduce the observations. General conclusions from these back-analysis calculations include the need for reduced effective diffusion coefficients for Cl-36 compared to those applicable to HTO (anion exclusion), the need to implement weaker sorption for Na-22, compared to results from laboratory batch-sorption experiments, and the observation of large differences between the theoretical initial concentrations for the strongly-sorbing Ba-133 and Cs-134 and the first measured values a few hours after tracer injection. Different teams applied different concepts, concerning mainly the implementation of isotropic vs. anisotropic diffusion, or the possible existence of Borehole Disturbed Zones around the different boreholes. The role of microstructure was also addressed in two of the models.
平 義隆*; 遠藤 駿典; 河村 しほり*; 南部 太郎*; 奥泉 舞桜*; 静間 俊行*; Omer, M.; Zen, H.*; 岡野 泰彬*; 北口 雅暁*
Physical Review A, 107(6), p.063503_1 - 063503_10, 2023/06
被引用回数：5 パーセンタイル：64.27(Optics)偏光レーザーと電子による逆コンプトン散乱は偏光ガンマ線を生成する手法の一つであり、100%偏光のレーザーを用いることで100%の偏光ガンマ線を得ることができる。しかしながら、偏光具合はガンマ線の散乱角度に依存して変化する。本研究ではMeVのエネルギーのガンマ線の円偏光度を測定することが可能である磁化鉄を用いて、ガンマ線の円偏光度の空間分布を実験的に測定した。ガンマ線の磁化鉄の透過率の非対称性が確認され、中心軸付近において円偏光しているガンマ線が、散乱角度が大きくなると円偏光から直線偏光に変化することが確認された。
大澤 崇人; 長澤 俊作*; 二宮 和彦*; 高橋 忠幸*; 中村 智樹*; 和田 大雅*; 谷口 秋洋*; 梅垣 いづみ*; 久保 謙哉*; 寺田 健太郎*; et al.
ACS Earth and Space Chemistry (Internet), 7(4), p.699 - 711, 2023/04
被引用回数：7 パーセンタイル：75.48(Chemistry, Multidisciplinary)小惑星試料中の炭素をはじめとする主要元素の濃度は、地球上の生命の誕生や太陽系の進化について非常に重要な情報を与えてくれる。ミュオンX線を用いた元素分析は、固体物質の元素組成を決定する最も優れた分析方法の一つであり、特にバルク試料中の軽元素濃度を非破壊で測定できる唯一の方法である。我々は、探査機「はやぶさ2」が小惑星リュウグウから回収した貴重な微小試料中の炭素などの主要元素の濃度を測定するために、ミュオンX線を用いた新しい分析システムを開発した。この分析システムは、ステンレス製の分析チャンバー、クリーンな環境で小惑星サンプルを操作するためのアクリル製のグローブボックス、分析チャンバーを囲むように配置されたGe半導体検出器から構成されている。測定に重要なバックグラウンドレベルを含め、分析装置の性能は初期から後期まで大幅に向上した。フィージビリティスタディの結果、最新型のミュオンX線分析装置は、「はやぶさ2」のサンプルモデル中の炭素濃度を6日間の測定で10%以下の不確かさで決定できることがわかった。
C宮澤 健; 菊池 裕太*; 安堂 正己*; Yu, J.-H.*; 藪内 聖皓*; 野澤 貴史*; 谷川 博康*; 野上 修平*; 長谷川 晃*
Journal of Nuclear Materials, 575, p.154239_1 - 154239_11, 2023/03
被引用回数：4 パーセンタイル：71.02(Materials Science, Multidisciplinary)This study examined the effects of alloying elements such as Re and Ta on the microstructural evolution of recrystallized W under proton and self-ion irradiations at 800C. Although the number density of voids increased with increasing proton-induced damage level, the void density in W-Re and W-Ta alloys were lower than that of pure W. Herein, the addition of Re and Ta to W suppresses the void formation process. In the proton-irradiated W-3%Re, a lot of dislocation loops were observed at 0.05 dpa which is the stage of nucleation. The evolution process up to 0.2 dpa was characterized by loop growth via the absorption of clusters and point defects. The dislocation loops then coalesce and grow large, and the dislocation lines become tangled at 1 dpa. At 0.05 dpa, the dislocation loops in pure W have already evolved into the tangled dislocations. Solute Re may inhibit the mobility of small dislocation loops and SIA clusters. In W-3%Ta irradiated at 0.05 and 0.2 dpa, the coalescence process of the elongated dislocation loops was observed. Solute Ta may inhibit the mobility of SIA clusters. Although no voids and rafts were observed in self-ion irradiated W-3%Re to 0.2 dpa, not only dislocation loops but also voids and rafts were observed in pure W to 0.2 dpa. The solute Re would suppress the raft formation and then the void formation under self-ion irradiation.
阿久澤 禎*; Kim, S.-Y.*; 久保田 真彦*; Wu, H.*; 渡部 創; 佐野 雄一; 竹内 正行; 新井 剛*
Journal of Radioanalytical and Nuclear Chemistry, 331(12), p.5851 - 5858, 2022/12
被引用回数：5 パーセンタイル：60.29(Chemistry, Analytical)In this work, we have examined Ln(III) and MA(III) separation conditions by the extraction chromatography using HONTA adsorbent to decide the Ln(III)/MA(III) separation process fow. From the research results, we found the simulated element of Am(III) for HONTA adsorbent and the conditions to use it. In addition, Ln(III) and Am(III) (simulated element) separation experiments were carried out using the HONTA adsorbent packed column, we have determined the column separation conditions for Am(III) such as order of fow solution and fow rate.
atoms (J-PARC E03, E07 and future)山本 剛史; 藤田 真奈美; 後神 利志*; 原田 健志*; 早川 修平*; 細見 健二; 市川 裕大; 石川 勇二*; 鎌田 健人*; 叶内 萌香*; et al.
EPJ Web of Conferences, 271, p.03001_1 - 03001_5, 2022/11
X-ray spectroscopy of hadronic atoms give us various information on the strong interaction between hadrons and nuclei. At J-PARC, we are aiming for the world-first detection of the X rays from atoms with a doubly strange hyperon, . Recently, two experiments, J-PARC E07 and J-PARC E03, have been performed for the detection of X rays from atoms. Overview and status of these measurements will be presented. We will also discuss future plan of X-ray spectroscopy on -atoms, which can be performed together with high resolution hyper nuclear spectroscopy using newly constructed S-2S spectrometer. Preparation status will be shown in this contribution.
atomic X-rays藤田 真奈美; 細見 健二; 石川 勇二*; 叶内 萌香*; 小池 武志*; 小椋 裕*; 田村 裕和; 谷田 聖; 鵜養 美冬*; 山本 剛史
Nuclear Instruments and Methods in Physics Research A, 1042, p.167439_1 - 167439_9, 2022/11
被引用回数：3 パーセンタイル：31.55(Instruments & Instrumentation) atomic X-ray spectroscopy is a powerful method of studying the N interaction, for which very limited experimental data are currently available. For this reason, we constructed a germanium (Ge) detector array referred to as Hyperball-X and conducted the first-ever atomic X-ray measurements in 2016 and 2017 at J-PARC. We developed a novel method for in-beam energy calibration of Ge detectors. Three rays (202 keV, 307 keV, and 511 keV) from 
Lu in LSO scintillation counters and 
Na source were used as reference. The 
and 
coincidence detection using the Ge detectors and LSO counters allows for continuous in-beam calibration with this new calibration method, and the calibration uncertainty is reduced to less than 100 eV for energies ranging from 202 to 511 keV.
Fe
O
solid solutions under high-pressure and high-temperature conditions山中 高光*; 平尾 直久*; 中本 有紀*; 三河内 岳*; 服部 高典; 小松 一生*; Mao, H.-K.*
Physics and Chemistry of Minerals, 49(10), p.41_1 - 41_14, 2022/10
被引用回数：3 パーセンタイル：7.21(Materials Science, Multidisciplinary)MnFeO固溶体の磁性と結晶構造を高温高圧下で中性子回折と放射光メスバウアー分光によって調べた。Mn
FeOスピネルのフェリ磁性-常磁性転移は100
C、正方晶-立方晶転移は180Cで起こり、これら2つの転移は直接関連していないことが分かった。構造相転移の転移温度は圧力とともに減少する。メスバウアー分光と中性子回折から、四面体サイトでのFe
の占有率が圧力とともに増加することがわかり、MnFeO相は逆スピネルに近づくことが示唆された。磁気構造解析により、MnFeOとMnFeOの常磁性とフェリ磁性の構造を明らかにした。これらのスピネルはそれぞれ18.4GPaと14.0GPaで斜方高圧相に変化し、Mn含有量の増加とともに転移圧力が低下することがわかった。
松田 晶平; 中島 信昭*; 横山 啓一; 谷口 誠治*; Chosrowjan, H.*; 染川 智弘*; 八ッ橋 知幸*
Chemical Physics Letters, 802, p.139759_1 - 139759_6, 2022/09
被引用回数：1 パーセンタイル：6.45(Chemistry, Physical)
ブロック元素の-遷移波長での共鳴多光子励起によって標的元素の酸化数のみを選択的に制御する技術は、希少金属の高純度な精製方法への応用が期待できる。この共鳴多光子過程を経る酸化還元の効率については、一光子目と二光子目それぞれの量子収率と吸収断面積が重要な因子である。そこで本研究では三価ユウロピウム(Eu
)から二価ユウロピウム(Eu
)への還元効率のレーザーフルエンス依存性を精密に調べることでそれらを評価した。その結果、励起波長394nmでのEuの二光子吸収過程における一光子目の量子収率の値、二光子目の量子収率と吸収断面積の積の値を見積もることができた。また、従来よりも広いフルエンス領域を調べたことで飽和が観測され、必要なレーザー出力の上限が推定できた。
近藤 恭弘; 北村 遼; 不破 康裕; 森下 卓俊; 守屋 克洋; 高柳 智弘; 大谷 将士*; Cicek, E.*; 恵郷 博文*; 深尾 祥紀*; et al.
Proceedings of 31st International Linear Accelerator Conference (LINAC 2022) (Internet), p.636 - 641, 2022/09
J-PARCにおいて、現代の素粒子物理学で最も重要な課題の一つである、ミューオン異常磁気モーメント、電気双極子モーメントを精密測定する実験のためのミューオンリニアック計画が進行中である。J-PARCミューオン施設からのミューオンはいったん室温まで冷却され、212MeVまで加速される。横エミッタンスは1.5
mm mradであり、運動量分散は1%である。高速で規格化した粒子の速度で0.01から0.94におよぶ広い範囲で効率よく加速するため、4種類の加速構造が用いられる。計画は建設段階に移行しつつあり、初段の高周波四重極リニアックによるミューオン再加速はすでに2017年に実証済である。次段の交差櫛形Hモードドリフトチューブリニアックのプロトタイプによる大電力試験が完了し、ディスクアンドワッシャ型結合セルリニアックの第一モジュールの製作が進行中である。さらに円盤装荷型加速管の設計もほぼ終了した。本論文ではこれらミューオンリニアックの最近の進捗について述べる。
