Temperature effect on the absorption spectrum of the hydrated electron paired with a lithium cation in deuterated water

Lin, M.; Kumagai, Yuta; Lampre, I.*; Coudert, F.*; Muroya, Yusa*; Boutin, A.*; Mostafavi, M.*; Katsumura, Yosuke

Journal of Physical Chemistry A, 111(18), p.3548 - 3553, 2007/05

https://doi.org/10.1021/jp070615j

Temperature effect on the absorption spectrum of the hydrated electron paired with a metallic cation in deuterated water

Lin, M.; Kumagai, Yuta; Muroya, Yusa*; Katsumura, Yosuke; Lampre, I.*; Coudert, F.*; Boutin, A.*; Mostafavi, M.*

no journal, , 

In this work, we measure the absorption spectra of hydrated electron in DO solutions containing different concentrations of Li and Mg cations at various temperatures by pulse radiolysis techniques, and perform quantum classical molecular dynamics (QCMD) simulations to explain the shift of the absorption spectra due to the combined effects of temperature and salt concentration.